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Argonne Investigating Butanol/Diesel Blends in Light-Duty Vehicles
15 August 2008
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| Steady-state NOx versus filter smoke number at 35 mph for ULSD, Bu20 and Bu40. Click to enlarge. |
Butanol can be used as a blending agent in diesel to displace petroleum and reduce emissions of particulate matter without significantly increasing NOx or significantly lowering the cetane number, according to the results of a preliminary study by researchers at Argonne National Laboratory.
With properties superior to that of ethanol, butanol (C4H9OH) is generally being considered as a gasoline blend component. Test results presented by BP and DuPont at SAE World Congress 2007 showed that bio-derived 1-butanol (also called n-butanol) performs similarly to unleaded gasoline on key parameters, and that biobutanol formulations meet key characteristics of a “good” spark ignition fuel, including high energy density, controlled volatility, sufficient octane and low levels of impurities. (Earlier post.)
Butanol, however, can potentially also be blended with diesel for compression ignition engines without causing significant penalties. Blending butanol with diesel may also improve cold flow properties and extend oxidative stability. Although the potential exists to positively impact engine-out emissions through the use of butanol/diesel blends, limited research has been done to this point on the effect and operation of butanol in compression ignition (diesel) engines.
Butanol exists as different isomers based on the location of the OH group and carbon chain structure. Argonne used n-butanol, which has a straight-chain structure with the alcohol at the terminal carbon, in this project.
The butanol contains 21.5 mass-% oxygen, and its net heat of combustion on a mass basis is 23% lower than ULSD. On a volume basis, the net heat of combustion is 26.6% lower. The cetane number is 40% lower than ULSD: ~25, rather than 42. (The butanol cetane of 25 is significantly higher than that of ethanol, which is ~8.)
While 100% n-butanol would not operate properly in an engine designed and calibrated for diesel fuel, Argonne found that low to medium blends of 1-butanol and ULSD provide acceptable cetane along with the potential advantage of oxygen in the fuel.
| Butanol/Diesel Fuel Data | ||||
|---|---|---|---|---|
| Property | Neat fuels | Blends | ||
| ULSD | n-Butanol | Bu20 | Bu40 | |
| Composition (C, H, O) (mass-%) | 87, 13, 0 | 65, 13.5, 21.5 | 82.6, 13.1, 4.3 | 78.2, 13.2, 8.6 |
| Lower heating value (MJ/kg) | 43.04 | 33.1 | 41 | 39 |
| Density (kg/m3) | 850 | 810 | 842 | 834 |
| Energy density (MJ/L) | 36.6 | 26.8 | 34.5 | 32.5 |
| Cetane number | 42 | ~25 | 38.6 | 35.2 |
In a preliminary study, the Argonne team used Bu20 (20% butanol) and Bu40 (40% butanol) blends of ultra low sulfur diesel (ULSD) in a 1999 Mercedes Benz Euro-3 C220 turbodiesel. Cold- and hot-start urban (UDDS) and highway (HWFET) drive cycle tests were conducted with the two butanol blends and compared to the pure ULSD fuel. In addition, 35 and 55 mph steady-state tests were run under varying road loads for the blends.
Broadly, the study found that on the urban drive cycle, both total hydrocarbon (THC) and carbon monoxide (CO) emissions increased as larger quantities of butanol were added to the diesel fuel. THC increased significantly as the percentage of butanol increased for cold-start UDDS drive cycle and only modestly for the hot-start UDDS cycle. Oxides of nitrogen (NOx) were not significantly affected by the 20% butanol blend and decreased with the 40% butanol blend.
Drivability of the vehicle decreased noticeably for the 40% butanol blend, especially for the cold-start urban drive cycle. Fuel consumption increased as the blend ratio of butanol increased, due primarily to the lower energy density of butanol compared to diesel. The largest reduction in fuel economy, approximately 30%, was observed during the cold-start UDDS drive cycle with the 40% butanol blend. The team found a significant difference in fuel economy when comparing the cold-start UDDS fuel economy and the hot-start UDDS, due to the effect of a warm versus cold engine in the Bu20 blend.
For the highway drive cycle, THC and CO emissions were not significantly impacted but NOx showed a slight increase as the butanol blend ratio increased. The lowest fuel economy reduction (~9%) occurred for the HWFET drive cycle.
For the steady-state tests, they found a reduction in filter smoke number with increasing butanol quantity—an 80% reduction in filter smoke number was observed for the 40% butanol blend.
The results showed that butanol/diesel blends up to 20% butanol can be successfully operated in a diesel engine calibrated for 100% diesel fuel. In addition, the results showed the significant impact butanol can have on vehicle emissions, especially particulate matter, without significantly increasing NOx. A 40% blend of butanol with ULSD may be able to be operated satisfactorily with ECU recalibration and thus realize the full potential of the higher blends of butanol, not only from an emissions standpoint but from a petroleum diesel fuel displacement blending agent as well. The potential exists to blend butanol with various base fuels, such as biodiesel and Fischer-Tropsch to produce blends with unique and favorable characteristics.
—Miers et al. (2008)
Argonne presented a snapshot of results of the butanol/diesel study at the recent Diesel Engine-Efficiency and Emissions Research (DEER 2008) conference, and will present a full paper on the work at the upcoming SAE Powertrains, Fuels and Lubricants Meeting, October 2008, in Chicago, IL.
Resources
Scott A. Miers, Steven McConnell, Thomas Wallner, Henry K. Ng, Richard W. Carlson, Jack LeFeber (2008) Drive Cycle Analysis of Butanol/Diesel Blends In a Light-Duty Vehicle (SAE 2008-01-2381 not yet published)
Khaled R. Asfar and Thaer H. Al-Rabadi (2003) Fuel Blends in Compression Ignition Engines (AIAA 2003-6027)
August 15, 2008 in Biobutanol, Diesel | Permalink | Comments (12) | TrackBack (0)
Comments
Posted by: reed | August 15, 2008 at 03:14 PM
Butanol seems to be a very good substitute for gasoline, and now this shows that a substantial portion of diesel can be replaced by it.
It is now time that high compression engines develop a new ignition system. One of the first engines used a flame to ignite the fuel. Injecting already burning fuel or super-heated fuel is an obvious extension. The INNAS NOAX allows for super-high compression, and, perhaps, low pressure injection followed by super high pressure HCCI operation will eliminate worries about cetane ratings. The NOAX could even have a special mix period or cycle. Power take off could be from a turbine as it was in the Pescara machines.
It might be more efficient and cheaper in the long run to use hybrid trucks with Capstone turbines, and worries about octane and cetane disappear as do NOX and particulates. For higher efficiency a combined cycle can be used. ..HG..
Posted by: Henry Gibson | August 15, 2008 at 04:22 PM
I can't see that it makes much difference what we burn in ICEs. They can be manufactured and/or adjusted to run on many fuels.
And even pure diesels can be fitted to be pretty clean.
To me the question is: Which fuel(s) or mixtures will be best in terms of supply and infrastructure. Wonderful fuels we can't obtain in volume or can't afford won't prove very useful.
However I am impressed by the small but steady improvements in ICE technology that engineers continue to wring out.
To second Henry, turbines might be worth another look.
Posted by: K | August 15, 2008 at 05:36 PM
This R&D is an example of how unfocused that fuel research has become. The US fuels research program needs a clear directed vision of a national future fuels policy.
Posted by: Axil | August 15, 2008 at 08:19 PM
FWIW combined cycle turbines would do well for long haul trucks. Incredible power density, ability to run multiple fuels without worries about exotic emissions, and very low maintenance. The downsides to turbines in this case is thermal efficiency and elasticity. A series hybrid drive train would compensate for the elasticity problem. Combined cycle would help thermal efficiency but it would kill power density.
As an aside, thermal efficiency is only a useful metric to a point: if your TE falls from ~45% to ~30% but your fuel cost drops 50% along with maintenance costs then you are still ahead. The advantage of switching over to a series hybrid drivetrain is that if we ever get the EESU right we can just take out the range extender and drop in an EESU with an adequate range. The electric traction motors are already in place.
Posted by: GreenPlease | August 15, 2008 at 10:23 PM
The specs don't appear to be as good as
LPG boosted diesel
with both increased power and lower fuel cost. A friend had the conversion done (not cheap) on a Nissan Patrol diesel then went on a two month trip with faultless economical performance. The next step might be CNG boosted diesel.
Instead of dying quietly it looks like the internal combustion piston engine keeps reinventing itself.
Posted by: Aussie | August 15, 2008 at 10:51 PM
Why doesn't someone do some testing with supplemental hydrogen. It does a good job of reducing polutants due to the more complete buring of the fuel mixture and supplemental hydrogen systems are much less expensive than LPG or CNG and there is no cost for the hydrogen.
Posted by: gyroguy | August 16, 2008 at 08:24 AM
the U of M is doing supplimental H2 with diesel, not sure of the results.
Why would it reduce pollutants due to "more complete burning"?
Diesel and most SI engines operate with a 99.999 % combustion efficiency. There are many other reasons for emissions.
Posted by: | August 16, 2008 at 09:13 AM
@anon
That is to say 99+% efficiency through the course of an entire stroke. Ideally, you want to get as much of the burn completed at or near TDC as possible.
Posted by: GreenPlease | August 17, 2008 at 07:37 AM
Butanol has some good characteristics as a fuel for spark-ignited engines. For those who are interested, see www. butanol. com.
The problem is producing it. The bacteria that produce butanol need sugar as the raw material input, and where are you going to get your sugar? You could use cornstarch, but look at how many people are complaining about corn-based ethanol robbing the world's hungry of food.
That leaves cellulose, which is everywhere you see trees, bushes, and other plants. But then, one runs into the same problems that exist with celluslosic ethanol: How to break down cellulose into simple sugars. Many researchers are working on this problem, but we are only beginning to see large-scale cellulosic ethanol production.
I read Green Car Congress whenever I can access the site, in part to see what are the latest developments in this area.
Posted by: Akovnat | August 17, 2008 at 09:37 AM
The U.S. fuels direction seems sound to me. There is a lot of ongoing work in a lot of areas which maximizes probability of finalizing on winning choices. The government's job at this point is to help identify and develop widespread pilot programs for a wide variety of energy solutions.
What we are seeing is a half dozen or so alcohol-based solutions from waste or cellulosic feedstocks. We are also seeing the potential for algal oil-based diesel/jetfuels. We have the electrification of transport decreasing demand for all liquid fuels. Battery technology is following an exponent curve, shrinking pack size and increasing in e-density.
For the grid, we have an immediate solution to coal-fired power via conversion to abundant NG. As more and more solar and wind arrive the present day grid gets cleaner, and with badly needed restructuring, more efficient.
Meanwhile, an emphasis on low cost, low temp electrolysis, CHP gensets/FCs will rapidly build out the Residential Power Unit replacements for outdated grid elements. DoE and industry need to support this development - in spite of political influences to the contrary. There are millions of new jobs and economic growth in the offing.
Finally, national security rests not only on sustainable domestic fuel sources, but on de-coupling from heavily centralized distribution systems that, unfortunately, make easy targets.
Posted by: gr | August 17, 2008 at 02:19 PM
Where to get sugar for Butanol? Try Hawaii, it grows like a weed here. Hawaii used to produce a million tons a year. Hawaii is also the perfect market for butanol with the highest petroleum prices and the most vulnerable supply line. The State government at least claims to support biofuel research. Then there is the perfect place to build a pilot plant, The National Energy Lab at Kona.
Posted by: Ken S Obenski | October 22, 2008 at 09:29 PM
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