Green Car Congress  
Go to GCC Discussions forum About GCC Contact  RSS Subscribe Twitter headlines

« Trade groups file petition with EPA to mandate ongoing availability of E10 fuel | Main | BASF subsidiary to acquire 15% stake in South Stream Russian gas pipeline company; €2B investment in the project »

Print this post

First gas flows to Pearl GTL

23 March 2011

Pearlgtl
Construction at the massive Pearl GTL project, Qatar, 2010. Click to enlarge.

Qatar Petroleum and Shell announced the first flow of dedicated offshore gas into the Pearl gas-to-liquids (GTL) plant located in Ras Laffan Industrial City in the State of Qatar. (Earlier post.) Pearl GTL is the largest energy project ever launched in the State of Qatar, in terms of total investments. It consists of two offshore platforms 60 kilometers (37 miles) off the Qatar coast, connected by pipeline to the largest GTL plant ever built, located in Ras Laffan Industrial City.

Pearl GTL will add almost 8% to Shell’s production worldwide, making it the company’s main engine for growth for 2012. It is expected to ship its first product in 2011 and reach full production in 2012.

Once fully operational, Pearl will produce 1.6 billion cubic feet of gas per day from the North Field, which will be processed to generate 120,000 barrels per day of condensate and natural gas liquids and 140,000 barrels per day of gas to liquids (GTL) products such as cleaner-burning diesel-type fuel (gasoil, about 50,000 barrels per day); GTL kerosene for aviation fuel; base oils (about 30,000 barrels per day) for advanced lubricants; naphtha used to make plastics; and paraffin for detergents.

Shell, which is the operator of the Pearl GTL plant developed under a Production and Sharing Agreement with QP, has opened natural gas wells offshore allowing the first sour gas to flow through a subsea pipeline into the giant GTL plant onshore. Sections of the Pearl GTL plant will be started up progressively over the coming months. The Pearl GTL project was launched in July 2006 and the first stone was laid by His Highness Sheikh Tamim bin Hamad Al-Thani, the Heir Apparent in February 2007.

Two underwater 76–centimeter (30-inch) diameter pipelines are carrying the natural gas to a gas separation plant onshore that extracts natural gas liquids: ethane for industrial processes; liquefied petroleum gas (LPG) for domestic heating and cooking; and condensates as a feedstock for refineries. The separation process also removes contaminants like metals and sulphur. The sulfur is turned into pellets and shipped to the nearest market to make hydrosulfuric acid, fertilizer or other valuable products.

The pure methane that remains will then flow to the GTL section of the plant, where it will be converted in a three-stage process into a range of gas-to-liquids products using Shell proprietary technology:

  • Making syngas. In the gasifier at around 2,200-2,650°F (1,400-1,600°C) methane and oxygen from an air separation plant are converted into a mixture of hydrogen and carbon monoxide known as synthesis gas, or syngas. The reaction produces heat, which is recovered to produce steam for power.

  • Making liquid waxy hydrocarbons. The synthesis gas enters one of 24 reactors. Each reactor holds a large number of tubes containing a Shell proprietary cobalt synthesis catalyst. The catalyst serves to speed up the chemical reaction in which the synthesis gas is converted into long-chained waxy hydrocarbons and water.

    The total surface area of the microscopic holes in the catalyst granules is more than eighteen times the surface area of Qatar. Placed end-to-end the tubes would stretch from Qatar to Japan. The synthesis process generates heat, which is also used to produce steam that in turn powers the GTL plant via steam turbines. All water in the GTL process is purified and reused in the utilities system of the plant to generate steam.

    Shell’s catalyst company, CRI/Criterion, spent around four years using dedicated facilities in Europe in full-time production to provide the thousands of tonnes of catalysts needed for the start of production at Pearl GTL.

  • Making GTL (gas to liquids) products. Using another Shell proprietary catalyst, the long hydrocarbon molecules from the GTL reactor are contacted with hydrogen and cut (cracked) into a range of smaller molecules of different length and shape. Distillation separates out the products with different boiling points.

March 23, 2011 in Gas-to-Liquids (GTL) | Permalink | Comments (6) | TrackBack (0)

TrackBack

TrackBack URL for this entry:
http://www.typepad.com/services/trackback/6a00d8341c4fbe53ef014e86eaa3b6970d

Listed below are links to weblogs that reference First gas flows to Pearl GTL:

Comments

This would make more sense in Alaska rather than building the $20 billion natural gas pipeline that is proposed, they would convert natural gas to gasoline and tanker it to the Pacific coast.

This is more proof that the energy return from liquid fuels is declining fast. GTL made in Malaysia 'throws away' about 40% of the possible energy of the gas so I guess Qatar is similar. Wouldn't it be simpler if we just converted to NGVs?

I think we'll always need liquid fuels for aviation, PHEV range extenders and gas/liquid bi-fuel vehicles. However the percentage of liquids per distance travelled must decline as they get more expensive. Think of the alternative uses for the gas wasted in making GTL just so we can drive SUVs and fly to places we could take the train instead.

There is a lot of "stranded" gas in the world. It is remote and not considered worth the effort to bring to market so they just flare (burn) it off.

The world burns off more stranded gas than the U.S. consumes. If that gas can be converted to liquid fuels and brought to market, the air would be cleaner and OPEC would not have the huge power that they have on supply and hence prices.

Correction...the world flares over 100 billion therms and the U.S. uses more than 200 billion. The world flares about the same amount used by Germany and France combined.

That could still make about 50 billion gallons of synthetic gasoline which would be sold quickly around the world, taking pressure off of oil prices.

Instead of NG as primary source they could as well use any waste. I guess that will be the next step.

Stranded gas is usually not up to the 100,000 BTUs per 100 standard cubic feet that pipeline natural gas is. It is maybe 1/3 that energy content, but still able to be used by the synthetic fuels process.

Verify your Comment

Previewing your Comment

This is only a preview. Your comment has not yet been posted.

Working...
Your comment could not be posted. Error type:
Your comment has been posted. Post another comment

The letters and numbers you entered did not match the image. Please try again.

As a final step before posting your comment, enter the letters and numbers you see in the image below. This prevents automated programs from posting comments.

Having trouble reading this image? View an alternate.

Working...

Post a comment

Green Car Congress © 2013 BioAge Group, LLC. All Rights Reserved. | Home | BioAge Group