New Berkeley Lab spectroscopy technique for in situ measurement of charge dynamics in an operating battery electrode
5 December 2013
|This schematic depicts the new soft X-ray spectroscopy technique. Windows etched into a foil covering allow soft X-rays to measure charge dynamics in an operating electrode. Click to enlarge.|
Researchers at Berkeley Lab and its Advanced Light Source have developed a new soft X-ray spectroscopy technique that can measure the migration of ions and electrons in an integrated, operating battery electrode. Taking advantage of the elemental, chemical and surface sensitivities of soft X-rays, they reported, in an open access paper in Nature Communications, distinct lithium-ion and electron dynamics in Li(Co1/3Ni1/3Mn1/3)O2 and LiFePO4 cathodes in polymer electrolytes.
The contrast between the two systems and a relaxation effect in LiFePO4 is attributed to a phase transformation mechanism, and the mesoscale morphology and charge conductivity of the electrodes. These discoveries demonstrate feasibility and power of in situ soft X-ray spectroscopy for studying integrated and dynamic effects in batteries, they suggested.
Over the past several years, scientists have developed several ways to study the changes in a working electrode. These include techniques based on hard X-rays, electron microscopy, neutron scattering, and nuclear magnetic resonance imaging. But most of these methods track structural changes. They don’t track electron and ion dynamics directly, which is very important in the push to understand and optimize battery performance.
Improving energy storage technology has become a critical and formidable challenge for modern sustainable energy applications, especially for electric vehicles. Lithium-ion battery (LIB) technology provides a high-efficiency solution for energy storage. However, significant improvements in cost, safety, capacity and power density are needed for current LIBs to meet the requirements for transportation applications. A practical LIB electrode is a complex system consisting of active materials, electrolyte, binder, additives and current collectors. LIBs operate with ion and electron migration through such integrated matrix, leading to evolving chemical and physical states in electrodes throughout electrochemical cycles. Although ex situ techniques have provided much valuable information for understanding individual components in equilibrium states, the dynamics of LIB, as one integrated multicomponent system, can only be characterized through in situ experiments. Tremendous efforts have been made to develop various in situ techniques based on hard X-ray, electron microscopy, neutron scattering and nuclear magnetic resonance for battery research. In particular, because of its penetration depth, hard X-ray techniques such as diffraction, and absorption spectroscopy have received early and wide use for in situ studies of batteries.
Compared with hard X-ray and other techniques, soft X-ray spectroscopy is a more direct and efficient experimental probe of the electronic states near the Fermi level. In battery materials, these key electronic states in the vicinity of Fermi level fundamentally regulate the properties pertaining to battery performance, such as electron conductivity, ion diffusion, open-circuit voltage, safety, structural stability and phase transformation.
… In this work, we have developed an in situ system for sXAS studies of LIBs. Two different electrode systems are deliberately selected and compared. The surface sensitivity of soft X-ray techniques is utilized for position-dependent studies of charge transportation during battery operations. Combining battery fabrication, morphology characterization, and in situ and ex situ sXAS techniques, we are able to unveil the charge dynamics in battery electrodes that are regulated by charge transport, mesoscale morphology and phase transformation. Additionally, the contrast between different electrode systems and the comparison between in situ and ex situ results provide soft X-ray fingerprints of metastable phases during the electrochemical process.—Liu et al.
The new technique relies on the Advanced Light Source, a Department of Energy national user facility located at Berkeley Lab that generates intense light for scientific research. The facility emits soft X-rays, which are very good at interacting with electrons. Because of this, soft X-ray spectroscopy is an ideal probe for studying battery characteristics such as electron and ion diffusion.
However, soft X-rays are so-named because they don’t penetrate very far, only about 100 nanometers, which isn’t far enough to study an electrode covered by a metal foil.
To overcome this, the spectroscopists at the Advanced Light Source worked with battery experts in the Environmental Energy Technologies Division. The team employed a laser system to etch a special detection window on the top foil layer. This allows soft X-rays to penetrate into an electrode for measurement.
This research was performed at beamline 8.0.1 at the Advanced Light Source, with battery cells assembled at the Environmental Energy Technologies Division. It was funded in part by the Energy Department’s Office of Energy Efficiency and Renewable Energy and Berkeley Lab’s Laboratory Directed Research and Development Program.
The Advanced Light Source is a third-generation synchrotron light source producing light in the x-ray region of the spectrum that is a billion times brighter than the sun.
Xiaosong Liu, Dongdong Wang, Gao Liu, Venkat Srinivasan, Zhi Liu, Zahid Hussain & Wanli Yang (2013) “Distinct charge dynamics in battery electrodes revealed by in situ and operando soft X-ray spectroscopy,” Nature Communications 4, Article number: 2568 doi: 10.1038/ncomms3568
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