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New ceramic materials for hydrogen storage

15 April 2014

Engineers at the University of California, San Diego, have created new ceramic materials that could be used to store hydrogen safely and efficiently. The researchers have created for the first time compounds made from mixtures of calcium hexaboride, strontium and barium hexaboride. They also have demonstrated that the compounds could be manufactured using a simple, low-cost manufacturing method known as combustion synthesis.

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The researchers have created for the first time compounds made from mixtures of calcium hexaboride, strontium and barium hexaboride. The resulting ceramics are essentially crystalline structures in a cage of boron. To store hydrogen, the researchers would swap the calcium, strontium and boron with hydrogen atoms within the cage. Credit: Olivia Graeve/Jacobs School of Engineering at UC San Diego. Click to enlarge.

The resulting ceramics are essentially crystalline structures in a cage of boron. To store hydrogen, the researchers would swap the calcium, strontium and boron with hydrogen atoms within the cage.

The work is at the proof of concept stage and is part of a $1.2-million project funded by the National Science Foundation, a collaboration between UC San Diego, Alfred University in upstate New York and the University of Nevada, Reno.

The manufacturing process for the ceramics is faster and simpler than traditional methods used to manufacture these types of materials. The researchers presented their work in March 2014 at the third International Symposium on Nanoscience and Nanomaterials in Mexico.

Engineers mixed boron with metal nitrates and organic fuels, such as urea, in a box furnace at temperatures below 400 ˚C. The nitrates and organic fuels ignite, generating heat that then drives the reaction without the need for an external source of power. This method is known as combustion synthesis.

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