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### University of Washington team develops new robust approach to solving battery models

## 15 August 2015

A team at the University of Washington (Seattle) led by Dr. Venkat Subramanian has developed an approach that helps solve battery models without knowing the exact initial conditions and without having to use a Newton Raphson iteration (a method for finding successively better approximations of a real-valued function) or a nonlinear solver. Source code and details are available at the Modeling, Analysis and Process-control Laboratory for Electrochemical Systems (MAPLE) Lab at the university. A paper on the approach is newly published in the journal *Computers & Chemical Engineering.*

The approach enables solving lithium-ion and other battery/electrochemical storage models accurately in a robust manner in a cheap microcontroller with minimum memory requirements. A disclosure has been filed with the University of Washington to apply for a provisional patent for battery models and Battery Management System for transportation, storage and other applications. In particular, use of this single step avoids initialization issues/(no need to initialize separately) for parameter estimation, state estimation or optimal control of battery models.

When modeling physical phenomena, the representative system of equations often includes a combination of ordinary differential equations (ODEs), partial differential equations (PDEs), and algebraic equations (AEs). These phenomena often use PDEs as governing equations of the system that vary in both space and time. When discretizing these PDEs spatially, the system becomes a set of ODEs and AEs. The resulting set of equations is known as a system of differential algebraic equations (DAEs). In physical systems, ODEs will typically represent most of the governing equations, while AEs act as constraints applied to the system ensuring that the solution accurately reflects the physical possibilities (e.g. conservation laws, boundary conditions, etc.). Systems of DAEs have been used to model real-world environments across a range of problems including large industrial processes, predator-prey eco-systems, electric power systems, and electrochemical environments. Computing solutions for systems of DAEs is important across a variety of fields. These systems combine algebraic states that act as constraints (nonlinear) on a set of ODEs, making the system more difficult to solve.

… In this paper, we show how explicit ODE solvers (such as Maple’s rkf45, a fourth-fifth order Runge–Kutta solver) can be used to solve nonlinear DAEs starting from inconsistent algebraic states.—Lawderet al.

Dr. Subramanian points out that a major difficulty solvers have with battery models is the unknown values for certain battery states such as state of charge (SOC), state of health (SOH), or individual electrode potential at the start of a simulation. When trying to solve a system of differential algebraic equations (DAEs), which are present in most electrochemically based battery models, normal solvers will fail if the initial conditions for all the state variables are inconsistent. This causes issues in Battery Management Systems (BMS).

The MAPLE approach corrects all of the algebraic variables to a set of consistent conditions. Additionally, once the consistent values are found, the proposed approach uses the same solver for the simulation of the model. This means there is only one solver call for both initialization and simulation.

The MAPLE team applied this approach successfully to a nickel electrode model, single particle model, porous electrode model for lithium-ion batteries and many other DAE systems.

Dr. Subramanian claims that the proposed approach is the most robust approach for solving index -1 DAEs as of today.

If there is a better approach for robustness and efficiency, we would like to know of the same. In addition, if the proposed approach fails for any index-1 DAE or battery model, we would like to be alerted about the same.—Dr. Venkat Subramanian

The United States Department of Energy (DOE) supported the MAPLE work though the Advanced Research Projects Agency – Energy (ARPA-E), award #DE-AR0000275.

**Resources**

Matthew T. Lawder, Venkatasailanathan Ramadesigan, Bharatkumar Suthar, Venkat R. Subramanian (2015) “Extending explicit and linearly implicit ODE solvers for index-1 DAEs,”

*Computers & Chemical Engineering*, Volume 82, Pages 283-292 doi: 10.1016/j.compchemeng.2015.07.002.

August 15, 2015 in Batteries | Permalink | Comments (1)

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So does this mean batteries will be able to predict the amount of charge left in any given battery better, or that we will be able to model battery types better ?

Posted by: mahonj | August 15, 2015 at 10:27 AM