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New prelithiation technique for silicon monoxide anodes for high-performance batteries; compatible with current roll-to-roll manufacturing

4 January 2016

Researchers from the Korea Advanced Institute of Science and Technology (KAIST), with colleagues from the Korea Institute of Energy Research (KIER), Qatar University and major battery manufacturer LG Chem have developed a technique for the delicately controlled prelithiation of SiOx anodes for high-performance Li-ion batteries.

The result, paired with a an emerging nickel-rich layered cathode, Li[Ni0.8Co0.15Al0.05]O2is high Columbic efficiencies (CE) and a full cell energy density 1.5-times as high as that of a graphite-LiCoO2 cell in terms of the active material weight. A paper on their work is published in the ACS journal Nano Letters.

Master.img-005
Comparison of the gravimetric energy densities for various full-cells. LMO, LCO, LFP, NMC, and NCA indicate LiMn2O4; LiCoO2; LiFePO4; Li- [CoNiMn]O2; and Li[Ni0.8Co0.15Al0.05]O2, respectively. Credit: ACS, Kim et al. Click to enlarge.

Although silicon is a very attractive anode material because of its higher energy density, its huge volume change over repeated charge−discharge cycles impairs the cycle life through pulverization of active particles, film delamination, and unstable solid−electrolyte interphase (SEI) formation.

As an alternative approach to avoid the known drawbacks, silicon monoxide (SiOx, x ≈ 1) phase has been recently adopted because its SiOy (y near 2) background matrix can buffer the volume expansion of inner Si nanodomains. On the basis of this structural advantage, some SiOx electrodes demonstrated very stable cycling performance.

Nonetheless, most of these phases suffer from inferior performance in a crucial parameter, namely initial Coulombic efficiency (ICE). This shortcoming originates primarily from Li ion trapping in the matrix and SEI layer formation during the first lithiation. Hence, in an overall performance viewpoint, while facilitating the long-term cycling performance, the background matrix, in turn, sacrifices the ICE. The compromised ICE would impose a great hurdle in constructing full-cells in practical applications because poor ICE necessitates an excess amount of cathode active material solely for the first cycle, leading to a lessened total energy density. For reference, current commercial LIBs involving graphite anodes usually have ICEs higher than 85% at low C-rates (∼0.1C).

In an attempt to catch these two challenging rabbits (cycle life and ICE), the current study has developed delicately controlled prelithiation for SiOx anodes.

—Kim et al.

Attaining the optimal degree of lithiation is very critical for stable full-cell operations, the team noted. Insufficient lithiation leaves Li trapping sites and does not improve the ICE enough, but overlithiation removes the possibility of accepting Li ions during the actual alloying reaction in the first charge.

To hit the sweet spot, the team prelithiated the pristine electrode via an electrical short with Li metal foil in the presence of an optimized circuit resistance while simultaneously monitoring the voltage between both electrodes.

Master.img-001
(a) Graphical illustration of prelithiation process of c-SiOx electrode and (b) its scalable roll-to-roll process scheme. Credit: ACS, Kim et al. Click to enlarge.

The procedure is compatible with the existing roll-to-roll manufacturing line and could be immediately applicable to the current state-of-the-art LIB anodes containing SiOx, they concluded.

Resources

  • Hye Jin Kim, Sunghun Choi, Seung Jong Lee, Myung Won Seo, Jae Goo Lee, Erhan Deniz, Yong Ju Lee, Eun Kyung Kim, and Jang Wook Choi (2015) “Controlled Prelithiation of Silicon Monoxide for High Performance Lithium-Ion Rechargeable Full Cells” Nano Letters doi: XXX10.1021/acs.nanolett.5b03776XX

January 4, 2016 in Batteries | Permalink | Comments (2)

Comments

This R&D work confirms my view that LG Chem is very well placed for providing mass produced energy dense batteries for long range BEV-s. Perhaps LG Chem could well be the leading manufacturer in 2016?

If you need to produce one million cells per day with consistent quality, you need advanced manufacturing techniques.

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