[Due to the increasing size of the archives, each topic page now contains only the prior 365 days of content. Access to older stories is now solely through the Monthly Archive pages or the site search function.]
TU Bergakademie Freiberg launches OTTO-R project with VW Group, Shell, OMV as partners; P2X for green gasoline
January 24, 2017
Researchers at the Technische Universität Bergakademie Freiberg, with partners from the automotive industry (Audi, VW) and the petroleum industry (Shell, OMV) have launched the €1.46-million OTTO-R project for the production of gasoline from “green” methanol produced from CO2, water and renewable electricity.
The new OTTO-R synthesis process is based on the Syngas-To-Fuel-Process (STF) developed by Chemieanlagenbau Chemnitz GmbH (CAC) at the Institute for Energy Process Engineering and Chemical Engineering (IEC). STF first converts natural gas-based synthesis gas to methanol in an isothermal reactor; the methanol is then transformed into high-octane gasoline via the intermediate methanol. Residual methanol and light hydrocarbons are separated downstream and recycled into the process.
MIT team engineers yeast to boost lipid production for biofuels
January 20, 2017
MIT engineers have genetically engineered strains of the oleaginous yeast Yarrowia lipolytica to boost the production of lipids by about 25% compared to previously engineered yeast strains. Their approach could enable commercialization of microbial carbohydrate-based lipid production, supporting the renewable production of high-energy fuels such as diesel.
A paper on their work is published in the journal Nature Biotechnology; the MIT team, led by Gregory Stephanopoulos, the Willard Henry Dow Professor of Chemical Engineering and Biotechnology at MIT, is now working on additional improvements to the lipids yield.
Port of Seattle, Boeing and Alaska Airlines release aviation biofuel infrastructure findings
January 17, 2017
The Port of Seattle, Boeing and Alaska Airlines released a first-of-its-kind study that identifies the best infrastructure options for delivering aviation biofuel to Seattle-Tacoma International Airport. In pursuit of its goal to power every flight at Sea-Tac with sustainable aviation biofuel, Sea-Tac is among the first airports in North America to work with aviation, energy and research partners to systematically evaluate all aspects to developing a commercial-scale program from scratch.
The objective of the study was to identify the best approach to deliver up to 50 million gallons (and to double to 100 million after 2025) of aviation biofuel per year into the fuel hydrant delivery system at Sea-Tac International Airport. A total of 29 sites across the state were identified and screened. The sites were located in King, Pierce, Whatcom, Skagit, Grays Harbor and Franklin Counties, Washington.
DOE Co-Optima initiative publishes report reviewing first 12 months; progress on fuels and engines
January 16, 2017
The US Department of Energy’s (DOE’s) Co-Optima initiative—a broad, joint effort to co-optimize the development of efficient engines and low greenhouse-gas fuels for on-road vehicles with the goal of reducing petroleum consumption by 30% by 2030 beyond what is already targeted (earlier post)—has published a year-in-review report for FY 2016—the initiative’s first 12 months.
Co-Optima’s premise is that current fuels constrain engine design—and thus engine efficiency. The researchers suggest that there are engine architectures that can provide higher thermodynamic efficiencies than available from modern internal combustion engines; however, new fuels are required to maximize efficiency and operability across a wide speed/load range. The report details the technical progress in a selection of projects across the initiative’s two main thrusts: spark ignition (SI) and advanced compression ignition (ACI).
Neste launches Neste MY Renewable Diesel made 100% from waste and residues in Finland; initial customers
Neste recently launched a renewable diesel made entirely from waste and residues under the brand name Neste MY Renewable Diesel at select service stations in the Helsinki region today, 9 January 2017. The product enables up to 90% lower greenhouse gas emissions throughout the life cycle of the fuel compared to conventional fossil diesel.
Production of Neste MY Renewable Diesel is based on Neste’s proprietary NEXBTL technology which can be used for producing premium-quality renewable diesel and other renewable products from almost any waste fat or vegetable oil. The feedstock selection available for Neste’s renewable diesel has been successfully expanded to more than 10 raw materials. The company is engaged in continuous development work to further expand the raw material base.
DOE BETO releases new strategic plan; biofuels to constitute 25% of US transportation fuels by 2040
December 31, 2016
The US Department of Energy’s Bioenergy Technologies Office (BETO) released its new strategic plan, titled Strategic Plan for a Thriving and Sustainable Bioeconomy. The strategic plan—with a vision for 2040—lays out BETO’s mission to accomplish its vision in a dynamic setting that realizes changes in the energy landscape, advances in technology, growing environmental awareness, and public expectations.
The strategic plan sets the foundation for the development of BETO’s multi-year program plans, annual operating plans, and technology program areas. It also takes a crosscutting approach to identify opportunities to adapt and align BETO activities and project portfolios with those in both the public and private sectors. The plan centers around four key opportunities: enhancing the bioenergy value proposition; mobilizing US biomass resources; cultivating end-use markets and customers; and expanding stakeholder engagement and collaboration.
DOE awards LanzaTech $4M for low-carbon jet & diesel demo plant; 3M gpy; Audi evaluating fuel properties
December 30, 2016
LanzaTech has been selected by the Department of Energy’s Bioenergy Technologies Office (BETO) to receive a $4-million award to design and plan a demonstration-scale facility using industrial off gases to produce 3 million gallons/year of low-carbon jet and diesel fuels. The LanzaTech award was one of six totaling $12.9 million. (Earlier post.)
The LanzaTech facility will recycle industrial waste gases from steel manufacturing to produce a low cost ethanol intermediate: “Lanzanol.” Both Lanzanol and cellulosic ethanol will then be converted to jet fuel via the Alcohol-to-Jet" (ATJ) process developed by LanzaTech and the Pacific Northwest National Laboratory (PNNL). (Earlier post.)
DOE awarding $12.9M to 6 pilot- and demonstration-scale projects for manufacturing biofuels, bioproducts, and biopower
December 29, 2016
The US Department of Energy (DOE) has selected six projects—entitled, “Project Definition for Pilot- and Demonstration-Scale Manufacturing of Biofuels, Bioproducts, and Biopower”—-for up to $12.9 million in federal funding. These projects, required to share the cost at a minimum of 50%, will develop and execute plans for the manufacturing of advanced or cellulosic biofuels, bioproducts, refinery-compatible intermediates, and/or biopower in a domestic pilot- or demonstration-scale integrated biorefinery.
The projects will be evaluated in two phases. Award recipients will design and plan their facilities in Phase 1. In order to continue to Phase 2, projects will be evaluated on Phase 1 progress, as well as the ability to secure the required 50% cost share funding for Phase 2. DOE anticipates Phase 2 awards to be made in fiscal year 2018 to construct and operate the pilot- or demonstration-scale facility. Projects could receive additional federal funds of up to $15 million for pilot-scale facilities or $45 million for demonstration-scale facilities.
Global Bioenergies plans to acquire Dutch start-up Syngip; gaseous carbon feedstocks for renewable isobutene process
December 21, 2016
Global Bioenergies, the developer of a process to convert renewable resources into light olefin hydrocarbons via fermentation (with an initial focus on isobutene) (earlier post), signed a contribution agreement with the shareholders of Syngip B.V. to transfer all Syngip shares to Global Bioenergies S.A. Syngip is a third-generation industrial biotech start-up created in 2014 in the Netherlands that has developed a process to convert gaseous carbon sources such as CO2, CO, and industrial emissions such as syngas, into various valuable chemical compounds.
Syngip has identified a specific micro-organism capable of growing using these gaseous carbon sources as its sole feedstock, and has developed genetic tools to allow the implementation of artificial metabolic pathways into it. Its recent work has been directed to the implementation of metabolic pathways leading to light olefins: major petrochemical molecules, which include isobutene.
Global Bioenergies reports first production of green isobutene at demo plant
December 15, 2016
Global Bioenergies is now entering the final phase of demonstrating its technology for converting renewable carbon into hydrocarbons. The first trials on the demo plant in Leuna were successfully completed, within schedule, in the fall of 2016 and Global Bioenergies announced first production of green isobutene via fermentation. (Earlier post.)
With a nameplate capacity of 100 tons/year, the demo plant will allow the conversion of various resources (industrial-grade sugar from beets and cane, glucose syrup from cereals, second-generation sugars extracted from wheat straw, bagasse, wood chips…), into high-purity isobutene.
LANL team develops simple catalyst system to upgrade acetone to range of chemicals and fuels
December 12, 2016
Researchers at Los Alamos National Laboratory (LANL) have developed a simple inexpensive catalyst system (Amberlyst 15 and Ni/SiO2–Al2O3) to upgrade bio-derived acetone to provide C6, C9, and C12 aliphatic ketones, along with C9, C12, and C15 aromatic compounds. Stepwise hydrodeoxygenation of the produced ketones can yield branched alcohols, alkenes, and alkanes. A paper on their work is published in the journal ChemSusChem.
Predicted and measured fuel properties of a selection of these produced molecules showed that certain compounds are candidates as drop-in fuel replacements for spark- and compression-ignition engines.
WSU Tri-Cities researchers receive $50K NSF grant to test market potential for lignin pathway for biojet
December 03, 2016
Researchers at Washington State University Tri-Cities have been awarded a $50,000 National Science Foundation I-Corps grant to explore the commercialization potential of their new pathway for biojet from biomass waste. The WSU process, described in a 2015 paper in the RSC journal Green Chemistry, uses hydrodeoxygenation (HDO) of dilute alkali extracted corn stover lignin catalyzed by a noble metal catalyst (Ru/Al2O3) and acidic zeolite (H+-Y) to produce lignin-substructure-based hydrocarbons (C7-C18), primarily C12-C18 cyclic structure hydrocarbons in the jet fuel range. (Earlier post.)
Current biorefineries undervalue lignin’s potential, largely because selective conversion of lignin has proven to be challenging. Processes that have been successful at breaking the lignin bonds have typically resulted in shorter chain monomers as opposed to the longer chain hydrocarbons needed for fuel. In contrast, the output of the WSU processis a mix of hydrocarbons that are long-chain and can be made into nearly the right mix for jet fuel.
GAO study concludes Renewable Fuel Standard will miss advanced biofuel program targets; EPA generally concurs
November 29, 2016
A new study from the US Government Accountability Office (GAO) concludes that the Renewable Fuel Standard program will miss its advanced biofuel targets due to the the high costs of creating advanced biofuel; the relatively low price of fossil fuel; the timing and cost to bring new tech to commercial-scale production; regulatory uncertainty; and other issues as challenges to increased production.
GAO was asked by Congress to review issues related to advanced biofuels R&D. The report describes (1) how the federal government has supported advanced biofuels R&D in recent years and where its efforts have been targeted; and (2) expert views on the extent to which advanced biofuels are technologically understood and the factors that will affect the speed and volume of production. GAO interviewed DOD, DOE, EPA, NSF, and USDA officials and worked with the National Academy of Sciences to convene a meeting of experts from industry, academia, and research organizations. EPA generally agreed with the conclusions of the report, the GAO said.
EPA finalizes increase in renewable fuel volumes for 2017; 6% total increase to 19.28B gallons
November 23, 2016
The US Environmental Protection Agency (EPA) finalized increases in renewable fuel volume requirements across all categories of biofuels under the Renewable Fuel Standard (RFS) program. In a required annual rulemaking, the action finalizes the volume requirements and associated percentage standards for cellulosic biofuel, advanced biofuel, and total renewable fuel for 2017, and for biomass-based diesel for 2018.
The final volumes represent continued growth over historic levels. The final standards meet or exceed the volume targets specified by Congress for total renewable fuel, biomass-based diesel, and advanced biofuel. Total renewable fuel volumes grow 6% (1.2 billion gallons) from 2016 to 2017 to 19.28 billion gallons.
Argonne LCA finds renewable diesel from algae fractionation has 63-68% lower GHG than petroleum diesel
October 22, 2016
A new analysis from Argonne National Laboratory, funded by the US Department of Energy’s Bioenergy Technologies Office (BETO), shows the potential of an algae fractionation process to produce renewable diesel fuel with 63%–68% lower greenhouse gas (GHG) emissions than conventional diesel. The study is published in the journal Algal Research.
In some algal biofuel production methods, lipids are extracted from algae and converted to renewable diesel, while the non-lipid components of the algae are converted to biogas. The biogas is used for renewable heat and electricity to power the conversion process of the lipids to renewable diesel.
New three-step process for conversion of vegetable oils into cycloparaffinic and aromatic biofuels in jet fuel range
October 17, 2016
A team from the University of Science & Technology of China in Hefei has developed a three-step process for the conversion of vegetable oils (triglycerides) into cycloparaffinic and aromatic biofuels in jet fuel range.
This process cracks vegetable oils into light aromatics over the zeolite catalyst (HZSM-5(80)), followed by the aromatic alkylation of the resulting light aromatics using the ionic liquid [bmim]Cl-2AlCl3, followed by the hydrogenation of the aromatics over a Pd/AC catalyst. As reported in a paper in the journal Fuel, the process produced 86.2 wt% of C8–C15 aromatics after alkylation, yielding 84.3 wt% monocyclic cycloparaffins after hydrogenation.
NREL and partners build pilot plant to co-process biomass streams with petroleum
October 14, 2016
The National Renewable Energy Laboratory (NREL), together with leading petroleum refining technologies supplier W.R. Grace, and leading pilot plant designer Zeton Inc., built a unique pilot-scale facility that can produce biomass-derived fuel intermediates with existing petroleum refinery infrastructure. This pilot plant, constructed in part with funding from the Bioenergy Technologies Office, combines biomass pyrolysis together with fluid catalytic cracking—one of the most important conversion processes used in petroleum refineries—to demonstrate the potential to co-process biomass-derived streams with petroleum, at an industrially-relevant pilot scale.
There are 110 domestic fluid catalytic cracking units currently operating in the United States. Using them to co-produce biofuel could enable production of more than 8 billion gallons of bio-derived fuels, without construction of separate biorefineries. This would significantly contribute to the Renewable Fuel Standard mandate set by the Energy Independence and Security Act of 2007 to produce 21 billion gallons of advanced renewable transportation fuels by 2022.
Gevo produces first cellulosic renewable jet fuel specified for use on commercial airline flights
October 12, 2016
Gevo, Inc. has completed production of the world’s first cellulosic renewable jet fuel that is specified for commercial flights. Gevo successfully adapted its patented technologies to convert cellulosic sugars derived from wood waste into renewable isobutanol, which was then further converted into Gevo’s Alcohol-to-Jet fuel (ATJ) fuel. (Earlier post.)
This ATJ meets the ASTM D7566 specification allowing it to be used for commercial flights. The revisions to the ASTM D7566 specification, which occurred earlier this year, includes ATJ derived from renewable isobutanol, regardless of the carbohydrate feedstock (i.e. cellulosics, corn, sugar cane, molasses, etc.). (Earlier post.)
China researchers devise process to convert biomass to gasoline via one-step DME synthesis: DTG
October 10, 2016
Researchers from the Qingdao Institute of Bioenergy and Bioprocess Technology have proposed a new process for the conversion of biomass to gasoline via a one-step DME synthesis (DTG: Dimethyl ether to gasoline). In a paper in the journal Fuel, they report a per-pass conversion of CO and the production capacity of gasoline of up to 45% and 4.4 kg/h, respectively.
Their homemade catalysts exhibited favorable activity, selectivity and stability during all the operations. The gasoline obtained from the pilot plant had a high octane number (RON>93). Although further studies are needed on mass and energy balances to ensure the most economical and optimal heat integration strategy, the practical experience of this work is sufficiently promising to merit further investigations, the team suggested.
NREL lowers biofuel costs through catalyst regeneration and vapor-phase upgrading; R-Cubed
October 06, 2016
This past June, researchers at the National Renewable Energy Laboratory (NREL), in partnership with Particulate Solids Research, Inc. and Springs Fabrication, installed a recirculating regenerating riser reactor (R-Cubed) in the pilot-scale Thermochemical Process Development Unit (TCPDU). Funded by the DOE Bioenergy Technologies Office (BETO), this unique unit represents the next generation of thermochemical biomass conversion technology and adds additional capabilities to NREL’s state-of-the-art Thermochemical Users Facility.
The R-Cubed system will now allow for catalytic upgrading of biomass pyrolysis vapors—a process that can significantly improve the efficiency and reduce the costs associated with upgrading bio-oil to a finished fuel product—at an industrially-relevant pilot scale.
EPA proposing updates to Renewable Fuel Standard
October 05, 2016
EPA is proposing updates to the Renewable Fuels Standard (RFS) regulations and related fuels regulations to better align the standards with the current state of the renewable fuels market and to promote the use of ethanol and non-ethanol biofuels.
Several of the proposed changes to the Renewable Fuel Standard program would align regulations with recent developments in the marketplace resulting in increased production of cellulosic, advanced and other biofuels, EPA said.
Global Bioenergies joins Preem, Sekab and forestry in bio-isooctane project in Sweden
September 28, 2016
In April this year, Preem, Sekab and Sveaskog entered into a collaboration to develop a gasoline fuel based entirely on forest resources with support from the Swedish Energy Agency. The consortium has now selected the bio-isobutene process developed by the French industrial biotech Global Bioenergies for the conversion of wood-derived sugars into a high-performance gasoline.
The consortium will study various plant scenarios t convert forestry products and residues profitably into bio-isooctane, a 100-octane rating, high-performance bio-based gasoline derived from bio-isobutene. The value chain will rely on Sveaskog’s forestry activities, Sekab’s CelluAPP biomass to sugar conversion process, Global Bioenergies wood-sugars to isobutene process and Preem’s gasoline production processes, blending and retailing activities.
Cummins Euro 6 engines compatibile with HVO renewable diesel & other paraffinic fuels; fuels at “point of commercial maturity”
September 22, 2016
Cummins Inc. announced Euro 6 (VI) engine compatibility for use with Hydrotreated Vegetable Oil (HVO) renewable diesel and other EN 15940 paraffinic fuels, representing a significant step forward to reduce the carbon footprint of Cummins-powered bus, truck and coach fleets operating in Europe.
Compared with conventional fossil-based diesel, HVO offers the potential to reduce greenhouse gas (GHG) emissions by 40 to 90 percent over the total life cycle of the fuel, dependent on the level of sustainable feedstock used in the production process.
Navy tests 100-percent CHCJ advanced biofuel in EA-18G
September 20, 2016
The US Navy has completed flight testing of a 100% advanced biofuel in the EA-18G “Green Growler” at Naval Air Station Patuxent River, Maryland. The US Navy is a leader in incorporating alternative fuel into operational supplies, in order to increase mission capability and flexibility.
The catalytic hydrothermal conversion-to-jet (CHCJ) process 100% alternative fuel performed as expected during a ground test 30 August at NAWCAD’s Aircraft Test and Evaluation Facility (ATEF), followed by the first test flight 1 September, said Rick Kamin, energy and fuels lead for Naval Air Systems Command (NAVAIR). Kamin also leads the alternative fuel test and qualification program for the Navy.
JetBlue enters 10-year renewable HEFA SPK jet fuel purchase agreement with SG Preston; 33M gallons of 30% blend per year
September 19, 2016
JetBlue announced a ten-year renewable jet fuel purchase agreement with SG Preston, a bioenergy company. The airline will purchase renewable jet fuel made from rapidly renewable, bio-based feedstocks that do not compete with food production. This marks one of the largest renewable jet fuel purchase agreements yet, and the largest, long-term, binding commitment by any airline globally for HEFA (hydro-processed esters and fatty acids) SPK (synthetic paraffinic kerosene) -based renewable jet fuel.
To launch the strategic relationship with SG Preston, JetBlue plans to purchase more than 33 million gallons of blended jet fuel per year for at least 10 years. The fuel will consist of 30% renewable jet fuel blended with 70% traditional Jet-A fuel.
Strategic consortium to commercialize Virent’s BioForming Technology for low carbon fuels and bio-paraxylene
September 15, 2016
Renewable fuels and chemicals company Virent has established a strategic consortium with Tesoro, Toray, Johnson Matthey and The Coca-Cola Company focused on completing the development and scale up of Virent’s BioForming technology to produce low carbon bio-based fuels and bio-paraxylene (a key raw material for the production of 100% bio-polyester).
The consortium members will work together to finalize technical developments and commercial arrangements, with the objective of delivering a commercial facility to produce cost effective, bio-based fuels and bio-paraxylene. Earlier this month, Virent and petroleum refiner and marketer Tesoro reached an agreement for Tesoro to become Virent’s new strategic owner. (Earlier post.)
LanzaTech produces 1,500 gallons of alcohol-to-jet fuel from waste gases for Virgin Atlantic
September 14, 2016
In a milestone for the low-carbon fuel project, LanzaTech has produced 1,500 gallons of jet fuel from waste industrial gases from steel mills via a fermentation process for Virgin Atlantic. Virgin Atlantic and LanzaTech have been working together on the project since 2011. HSBC joined the partnership in 2014.
The “Lanzanol” was produced in China at the RSB (Roundtable of Sustainable Biomaterials) certified Shougang demonstration facility. The innovative alcohol-to-jet (ATJ) process was developed in collaboration with Pacific Northwest National Lab (PNNL) with support from the US Department of Energy (DOE) and with the help of funding from HSBC.
Tesoro to acquire renewable fuels company Virent
September 07, 2016
Renewable fuels and chemicals company Virent and petroleum refiner and marketer Tesoro have reached an agreement for Tesoro to become Virent’s new strategic owner. The acquisition will support the scale-up and commercialization of Virent’s BioForming technology for the production of low carbon bio-based fuels and chemicals. (Earlier post.)
The companies initiated a strategic relationship in January 2016 (earlier post), and have worked together to establish a forward plan to scale-up the technology and reduce deployment risks to meet the increasing demands for high quality, renewable fuels and chemicals.
Researchers generate methane from CO2 in one light-driven step using engineered bacteria
August 25, 2016
Using an engineered strain of the phototropic bacterium Rhodopseudomonas palustris as a biocatalyst, a team from the University of Washington, Utah State University and Virginia Polytechnic Institute and State University have reduced carbon dioxide to methane in one enzymatic step.
The work demonstrates the feasibility of using microbes to generate hydrocarbons (i.e., CH4 in this case) from CO2 in one enzymatic step using light energy. A paper on their work is published in Proceedings of the National Academy of Sciences (PNAS).
China team develops pathway for producing renewable aviation-range hydrocarbons and aromatics from oleic acid without added H2
Researchers from Zhejiang University; SINOPEC’s Fushun Research Institute of Petroleum and Petrochemicals; Nanjing Tech University; and Xinjiang Technical Institute of Physics and Chemistry have developed an “atom-economic” approach to produce renewable drop-in aviation-range hydrocarbons and aromatics from oleic acid (C18H34O2, a fatty acid that occurs naturally in various animal and vegetable fats and oils) without an added hydrogen donor. A paper on their work is published in the ACS journal Energy & Fuels.
The conversion of oleic acid in the process was 100%, and the yield of heptadecane (C17H36, the main product) can reach 71% after 80 min at 350 °C. The process also produced an aromatics yield of 19%; aromatics are a critical component of aviation fuels due to their ability to maintain the swelling of fuel system elastomers. The results, said the researchers, indicate that their process is a complicated reaction system including in situ hydrogen transfer, aromatization, decarboxylation, and cracking.
PNNL-Lanzatech team hits milestone on waste-gas-to-ethanol-to-jet project
August 23, 2016
With funding from Bioenergy Technologies Office (BETO), Pacific Northwest National Laboratory (PNNL) has been working with industry-partner LanzaTech to convert alcohols derived from captured carbon monoxide, a byproduct in the production of steel, into synthetic paraffinic kerosene, a non-fossil-based jet fuel. The technology not only provides a viable source of sustainable jet fuel but also reduces the amount of greenhouse gasses emitted into the atmosphere.
The team recently reached a significant milestone on the project, producing over five gallons of synthetic paraffinic kerosene in a lab environment. Five gallons is the quantity needed for “fit-for-purpose” testing.
Study shows renewable diesel from crude tall oil is a high quality drop-in fuel for off-road engines
August 20, 2016
A team from the University of Vaasa (Finland) and UPM-Kymmene Corporation has examined how the blends of fossil and renewable diesel produced from crude tall oil (CTO) affect the performance and exhaust emissions of the modern common-rail off-road diesel engine.
The study, published in the journal Fuel, used four different fuel blends of low-sulfur fossil diesel fuel oil and CTO renewable fuel, UPM BioVerno (HB): HB10, HB20, HB50, and HB100. UPM BioVerno renewable diesel is produced from wood-based tall oil. (Earlier post.)
China researchers develop new pathway for jet-range bio-cycloalkanes from acetone and hydrogen
August 12, 2016
Researchers from the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, have developed a new route for the synthesis of jet-fuel range C10 and C12 cycloalkanes using diacetone alcohol (the self-aldol condensation product of acetone under mild conditions)—which can be derived from lignocellulosic biomass—and hydrogen. A paper on their work is published in the RSC journal Green Chemistry.
The branched cycloalkanes are synthesized with high carbon yield (~76%), have high density (0.83 g mL-1) and a low freezing point (216.5 K). As a potential application, they can be used as additives to conventional bio-jet fuel comprising C8-C16 chain alkanes.
US Navy completes sea trial with ARA’s 100% drop-in renewable diesel fuel
August 09, 2016
A Navy ship has, for the first time, operated on a 100% drop-in renewable diesel fuel. Naval Surface Warfare Center, Port Hueneme Division’s (NSWC PHD) Self Defense Test Ship (SDTS) completed final-phase testing of a 100% drop-in renewable diesel fuel as part of the Navy’s MILSPEC qualification program. ReadiDiesel was developed by Applied Research Associates (ARA) and Chevron Lummus Global, as a drop-in replacement for petroleum F-76 marine diesel. ReadiDiesel is a 100% renewable biofuel. (Earlier post.)
The SDTS took on approximately 18,000 gallons of ReadiDiesel in San Diego, California. The objective of this particular test was twofold: first, to demonstrate that ReadiDiesel is a drop-in replacement for petroleum-sourced F-76 marine diesel, meaning that it requires no blending with petroleum-derived fuels, equipment modifications or operational modifications by the crew; and second, to ensure that this renewable fuel performs equally to, or better than, existing petroleum-derived fuels.
DOE awarding up to $11.3M to 3 projects under MEGA-BIO for biomass-to-hydrocarbon fuels, products
August 03, 2016
The US Department of Energy (DOE) will award up to $11.3 million to three projects under MEGA-BIO: Bioproducts to Enable Biofuels (earlier post) that support the development of biomass-to-hydrocarbon biofuels conversion pathways that can produce variable amounts of fuels and/or products based on external factors, such as market demand.
Producing high-value bioproducts alongside cost-competitive biofuels has the potential to support a positive return on investment for a biorefinery. This funding is intended to develop new strategies for biorefineries to diversify revenue streams, including chemicals and products manufacturing, resulting in long-term economic benefits to the United States. Projects selected for funding are:
US releases Federal alternative jet fuels R&D strategy
July 29, 2016
The Obama Administration has released the Federal Alternative Jet Fuels Research and Development (R&D) Strategy (FAJFS), which maps out a unified federal plan to advance R&D as well as science and technology solutions to support deployment of alternative jet fuels (AJFs) in both civil and military aviation.
The strategy provides a prioritized list of R&D goals and objectives addressing specific scientific, technical, analytical, and logistics challenges that hinder the development, production, and wide-scale economic deployment of AJFs. In releasing the FAJFS, the federal government hopes to accelerate the development of the AJF industry by minimizing technical uncertainty to encourage further private sector interest, facilitate the development and approval of new AJF pathways, and reduce the cost of AJF production in the United States.
American Refining Group taking 1/3 stake in Amyris/Cosan Novvi JV; accelerating commercialization of renewable base oil and lubricants
July 19, 2016
American Refining Group (ARG) is taking a 33.3% stake in Novvi LLC, a joint venture of Amyris and Brazil-based Cosan S.A. formed in 2011 to produce renewable base oils and lubricants from Amyris’ Biofene—Amyris’s brand of a renewable, long-chain, branched hydrocarbon molecule called farnesene (trans-ß-farnesene). (Earlier post.) Both Amyris and Cosan will continue to hold share ownership stakes in Novvi, together with ARG.
Biofene is the basis for a wide range of products varying from specialty products such as cosmetics, perfumes, detergents and industrial lubricants, to transportation fuels such as diesel and jet fuel.
Lux: biojet fuel to account for 56% of targeted 2050 CO2 emissions reductions in aviation
Biojet fuels will be key to achieving the aviation industry’s pledge to cut CO2 emissions to 0.2 billion tons (GT) in 2050—half the 2005 figure—as opposed to the staggering 2.1 GT projected by current growth rates, according to a new report from Lux Research, “Biojet Fuel Technology Roadmap.”
Lux forecasts that biojet fuel innovations, led globally by Honeywell UOP and Boeing, will account for 56% of the targeted CO2 emissions reductions, while a third of the requisite cuts will come from new aircraft technology, and optimization of operations and infrastructure.
Los Alamos team develops robust route to convert starch and sugar to C10 and C11 hydrocarbons; “potato-to-pump”
July 18, 2016
Researchers at Los Alamos National Laboratory have developed a route to convert oligosaccharides, such as starch, cellulose, and hemicelluloses to C10 and C11 hydrocarbons by using depolymerization followed by chain extension.
In a paper published in the journal ChemSusChem, they report on the robustness of the approach by performing a simple starch extraction from a Russet potato and subjecting it to their process. (They noted that the use of the potato was simply illustrative, and that the use of food crops for fuel production should be avoided.)
Boeing, South African Airways and Mango celebrate Africa’s 1st commercial flights with sustainable aviation biofuel from tobacco
July 15, 2016
Boeing, South African Airways (SAA) and low-cost carrier Mango celebrated Africa’s first passenger flights with sustainable aviation biofuel. The flights coincided with Boeing’s 100th anniversary and centennial celebrations worldwide.
The SAA and Mango flights carried 300 passengers from Johannesburg to Cape Town on Boeing 737-800s using a blend of 30% aviation biofuel produced from Sunchem’s nicotine-free tobacco plant Solaris, refined by AltAir Fuels and supplied by SkyNRG. (Earlier post.)
Global Bioenergies, IBN-One and Lantmännen Aspen partner on renewable isooctane for specialty fuel applications
July 11, 2016
Global Bioenergies, IBN-One and Lantmännen Aspen, world market leader in alkylate gasoline for two- and four-stroke small engines, have entered into a partnership on renewable isooctane (earlier post) for specialty fuel applications.
Aspen is part of the Swedish Lantmännen group, an agricultural cooperative and Northern Europe’s leader in agriculture, machinery, bioenergy and food products with annual revenues of €3.4 billion (US$3.8 billion). In particular, Lantmännen Aspen’s commercial activities include specialty fuels for usage in two- and four-stroke small engines—e.g. chainsaws and lawn mowers—where the operator, machine and environment benefit from a cleaner fuel quality regarding harmful substances compared to regular gasoline.
Scripps research ship fueled by 100% NEXBTL renewable diesel for 1 year; emissions analysis
June 14, 2016
In 2014, Scripps Institution of Oceanography received a grant from the US Department of Transportation to test the use of biofuel on the research vessel Robert Gordon Sproul for more than a year. Spearheaded by Scripps Associate Director Bruce Appelgate and co-led by Scripps atmospheric scientist Lynn Russell, the biofuel project investigated the viability of using hydrotreated renewable diesel fuel (HRD) on a long-term basis.
The Scripps researchers originally wanted to test renewable biodiesel produced from algae, but no manufacturers made algal biodiesel in the volume needed. Appelgate was able to take advantage of a newly-established reliable supply chain for another type of biodiesel, a hydrogenation-derived renewable diesel (HDRD) —purchased from Neste Oil Corporation: NEXBTL Renewable Diesel.
New catalyst system for converting castor-oil-derived ricinoleic acid methyl ester into jet fuel; up to 90% carbon selectivity
June 13, 2016
Researchers at Beijing University of Chemical Technology have developed a catalytic process for the selective conversion of ricinoleic acid methyl ester—derived from castor oil—into jet fuel. A paper on their work is published in the RSC journal Green Chemistry.
A common challenge in bio-jet fuel production is the high cost due to the feedstock and processing technology. Although hydro-processing of lipid and fatty acid is well-known, the yield of jet fuel from typical lipid based oil with mainly C18 fatty acid is quite low (about 35–40%). The major reason for the low overall yield is the necessity of a hydrocracking step for converting the C18 or C16 alkane into jet fuel range paraffin (C9–C15), the researchers explained. A key improving lipid-to-jet production technology is thus to avoid the un-selective cracking.
New 3-step process for conversion of kraft lignin from black liquor into green diesel
June 01, 2016
Researchers in Sweden and Spain have devised a three-step process for the conversion of precipitated kraft lignin from black liquor into green diesel. Their paper appears in the journal ChemSusChem.
The kraft process converts wood into wood pulp for paper production. The process produces a toxic byproduct referred to as black liquor—a primarily liquid mixture of pulping residues (such as lignin and hemicellulose) and inorganic chemicals from the Kraft process (sodium hydroxide and sodium sulfide, for example). For every ton of pulp produced, the kraft pulping process produces about 10 tons of weak black liquor or about 1.5 tons of black liquor dry solids.
Clariant to scale-up catalysts for Gevo’s Ethanol-to-Olefins (ETO) technology; renewable diesel and hydrogen
May 19, 2016
Gevo, Inc. has entered into an agreement with Clariant Corp., one of the world’s leading specialty chemical companies, to develop catalysts to enable Gevo’s Ethanol-to-Olefins (ETO) technology.
Gevo’s ETO technology, which uses ethanol as a feedstock, produces tailored mixes of propylene, isobutylene and hydrogen, which are valuable as standalone molecules, or as feedstocks to produce other products such as diesel fuel and commodity plastics, that would be drop-in replacements for their fossil-based equivalents. ETO is a chemical process, not a biological process as is Gevo’s conversion of biomass to isobutanol.
China team directly synthesizes gasoline- and diesel-range alkanes from acetone from biomass
May 17, 2016
Researchers in China have directly synthesized gasoline- and diesel-range C6-C15 branched alkanes in high carbon yield (~80%) via the self-condensation of acetone and the subsequent hydrodeoxygenation over a dual-bed catalyst system. A paper on their work appears in the RSC journal Green Chemistry.
Acetone is a by-product in the production of bio-butanol via the acetone-butanol-ethanol (ABE) fermentation of lignocellulose. In a typical ABE fermentation, butanol, acetone and ethanol are produced at a weight ratio of 6:3:1.4 Acetone can also be produced by ketonization of acetic acid—a low-cost lignocellulosic platform compound which is obtained as a by-product in furfural production or from the fermentation of lignocellulose.
DOE awards up to $10M to 6 projects for non-food biomass and algal biofuels and biochemicals
May 16, 2016
The US Department of Energy is awarding up to $10 million in funding for six projects that will support the Bioenergy Technologies Office’s (BETO) work to develop renewable and cost-competitive biofuels and biochemicals from non-food biomass feedstocks by reducing the technical risk associated with potentially breakthrough approaches and technologies for investors.
The projects selected include the following:
DOE to award up to $90M for integrated biorefinery projects
May 07, 2016
“Project Development for Pilot and Demonstration Scale Manufacturing of Biofuels, Bioproducts, and Biopower” is a funding opportunity that will support efforts to improve and demonstrate processes that break down complex biomass feedstocks and convert them to gasoline, diesel and jet fuel, as well as plastics and chemicals.
U Mich study explores performance of renewable diesel, FT diesel and ULSD in PCCI combustion
May 03, 2016
A team at the University of Michigan has investigated the performance of three different fuels—ultralow sulfur diesel (ULSD), diesel fuel produced via a low temperature Fischer–Tropsch process (LTFT), and a renewable diesel (RD), which is a hydrotreated camelina oil under partially premixed compression ignition (PCCI) combustion. Their paper is published in the ACS journal Energy & Fuels.
Partially premixed compression ignition (PCCI) combustion is an advanced, low-temperature combustion mode that creates a partially premixed charge inside the cylinder before ignition occurs. PCCI prolongs the time period for mixing of the fuel–air mixture by separating the end of injection and start of combustion. As a result, NOx and particulate matter (PM) emissions can be reduced simultaneously relative to those of conventional diesel combustion.
Roland Berger study outlines integrated vehicle and fuels roadmap for further abating transport GHG emissions 2030+ at lowest societal cost
April 30, 2016
A new study by consultancy Roland Berger defines an integrated roadmap for European road transport decarbonization to 2030 and beyond; the current regulatory framework for vehicle emissions, carbon intensity of fuels and use of renewable fuels covers only up to 2020/2021.
The study was commissioned by a coalition of fuel suppliers and automotive companies with a view to identifying a roadmap to 2030+ to identify GHG abatement options at the lowest cost to society. The coalition comprises BMW, Daimler, Honda, NEOT/St1, Neste, OMV, Shell, Toyota and Volkswagen. Among the key findings of the study were:
New $30M ARPA-E program to produce renewable liquid fuels from renewable energy, air and water
April 26, 2016
The US Department of Energy’s Advanced Research Projects Agency-Energy (ARPA-E) announced up to $30 million in funding for a new program for technologies that use renewable energy to convert air and water into cost-competitive liquid fuels. (DE-FOA-0001562)
ARPA-E’s Renewable Energy to Fuels through Utilization of Energy-dense Liquids (REFUEL) program seeks to develop technologies that use renewable energy to convert air and water into Carbon Neutral Liquid Fuels (CNLF). The program is focused in two areas: (1) the synthesis of CNLFs using intermittent renewable energy sources and water and air (N2 and CO2) as the only chemical input streams; and (2) the conversion of CNLFs delivered to the end point to another form of energy (e.g. hydrogen or electricity).
DOE to issue funding opportunity to develop plans for drop-in bio-hydrocarbon biorefinery
April 16, 2016
The US Department of Energy’s Office of Energy Efficiency and Renewable Energy (EERE) intends (DE-FOA-0001581) to issue, on behalf of the Bioenergy Technologies Office, a Funding Opportunity Announcement (DE-FOA-0001232) entitled “Project Definition for Pilot and Demonstration Scale Manufacturing of Biofuels, Bioproducts, and Biopower (PD2B3)”. The FOA will be issued on or about 2 May.
This FOA supports technology development plans for the manufacture of drop-in hydrocarbon biofuels, bioproducts, or biopower in a pilot- or demonstration-scale integrated biorefinery. Plans for facilities that use cellulosic biomass, algal biomass, or biosolids feedstocks will be considered under this funding opportunity.
JBEI team engineers E. coli for one-pot production of bio-jet fuel precursor from ionic-liquid-pretreated biomass
April 13, 2016
A team led by researchers at the DOE’s Joint BioEnergy Institute (JBEI) in Emeryville, CA, has engineered E. coli bacteria for the one-pot production of the monoterpene bio-jet fuel precursor D-limonene from ionic-liquid-pretreated cellulose and switchgrass. A paper on their work is published in the RSC journal Green Chemistry.
The ionic liquid 1-ethyl-3-methylimidazolium acetate is highly effective in deconstructing lignocellulose, but leaves behind residual reagents that are toxic to standard saccharification enzymes and the microbial production host. The JBEI researchers discovered a strain of E. coli that is tolerant to that ionic liquid due to a specific mutation. They engineered this strain to express a D-limonene production pathway.
Texas A&M-led team identifies synthetic hydrocarbon pathway in green alga B. braunii
April 07, 2016
The green microalga Botryococcus braunii is considered a promising biofuel feedstock producer due to its prodigious accumulation of hydrocarbon oils that can be converted into fuels. Now, a team led by researchers from Texas A&M AgriLife Research has identified the first committed step in the biosynthesis of hydrocarbon oil in B. braunii and has described a new enzyme which carries out this reaction.
The study, published as an open-access paper in the current issue of the journal Nature Communications, could enable scientists to use the enzyme in a plant to make large amounts of fuel-grade oil, according to Dr. Tim Devarenne, AgriLife Research biochemist in College Station and lead scientist on the team.
New energy-efficient process for direct conversion of biomass without pretreatment to liquid hydrocarbon fuels
April 01, 2016
A team from The University of Manchester and East China University has developed a process for the direct hydrodeoxygenation of raw woods into liquid alkanes with mass yields up to 28.1 wt% over a multifunctional Pt/NbOPO4 catalyst in cyclohexane.
The superior performance of the catalyst allows simultaneous conversion of cellulose, hemicellulose and, more significantly, lignin fractions in wood sawdust into hexane, pentane and alkylcyclohexanes, respectively. An open-access paper on their work is published in the journal Nature Communications.
New renewable hydrocarbon fuel pathway uses platform molecule acetoin produced by biomass fermentation
March 30, 2016
Researchers at Nanjing Tech University in China have developed a new pathway for the production of liquid hydrocarbon fuels from lignocellulose. The new Nanjing Tech process uses acetoin—a novel C4 platform molecule derived from new ABE (acetoin–butanol–ethanol)-type fermentation via metabolic engineering—as a bio-based building block for the production of the liquid hydrocarbon fuels.
In a paper published in the RSC journal Green Chemistry, the Nanjing Tech team reported producing a series of diesel or jet fuel range C9–C14 straight, branched, or cyclic alkanes in excellent yields by means of C–C coupling followed by hydrodeoxygenation reactions.
ASTM ballot greenlights approval of ATJ-SPK biojet from alcohol; Gevo 1st commercial test flight with Alaska Airlines
March 29, 2016
Renewable isobutanol company Gevo announced that the ASTM International Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants and Subcommittee D02.J on Aviation Fuel passed a concurrent ballot this week approving the revision of ASTM D7566 (Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons) to include alcohol-to-jet synthetic paraffinic kerosene (ATJ-SPK) (the “D02.J Ballot”). (Earlier post.)
This approval prepares the way for the use of Gevo ATJ—as well as ATJ-SPK fuels produced by other manufacturers—in commercial operations. As previously announced, Alaska Airlines is now poised to fly the first commercial test flight using Gevo’s renewable ATJ-SPJ fuel. (Earlier post.) Gevo is preparing the shipment of ATJ to Alaska Airlines for this first flight. Alaska Airlines will work with the Federal Aviation Administration to schedule the flight using Gevo’s ATJ.
NREL updates Survey of Advanced Biofuel Producers in the United States
March 17, 2016
The National Renewable Energy Laboratory (NREL) updated its annual survey of US non-starch ethanol and renewable hydrocarbon biofuels producers. The 2015 Survey of Non-Starch Ethanol and Renewable Hydrocarbon Biofuels Producers provides an inventory of the domestic advanced biofuels production industry as of the end of calendar year 2015, documenting important changes (e.g., biorefinery development, production capacity, feedstock use, and technology pathways) that have occurred since the publication of the original 2013 survey.
During 2015, NREL surveyed 114 companies that were reported to be pursuing commercial-scale biofuel production capacity. Companies were classified as either non-starch (cellulosic or algae-derived) ethanol producers or renewable hydrocarbon producers. The questionnaire included topics such as facility stage of development, facility scale, feedstock, and biofuel products. The NREL team supplemented missing survey data elements (when possible) with publicly available data obtained directly from company websites, press releases, and public filings.
United Airlines begins commercial-scale use of renewable jet fuel; 15M gallons over 3-year period
March 12, 2016
United Airlines has become the first US airline to begin use of commercial-scale volumes of sustainable aviation biofuel for regularly scheduled flights, beginning with the departure of United Flight 708 from Los Angeles International Airport (LAX). The launch marks a milestone in the commercial aviation industry by moving beyond demonstration flights and test programs to the use of advanced biofuels for United’s ongoing revenue operations.
United has agreed to purchase up to 15 million gallons of sustainable biofuel from AltAir Paramount over a three-year period. The biofuel will be mixed with traditional jet fuel at a 30/70 blend ratio: 30% biofuel, 70% traditional fuel. The airline has begun using the biofuel in its daily operations at LAX, storing and delivering it in the same way as traditional fuel.
Government of Alberta awarding $10M to SBI Bioenergy for production of drop-in hydrocarbon fuels; funds from carbon levy
March 10, 2016
Using revenue from the price Alberta’s large emitters pay for releasing greenhouse gases, the Climate Change and Emissions Management Corporation (CCEMC) has earmarked a $10-million contribution for Alberta-based SBI BioEnergy to support a $20-million facility for the demonstration-scale production of drop-in, renewable diesel, jet and gasoline fuels from plant oils and waste fats.
With this investment, SBI will be able to produce 10 million liters (2.6 million gallons US) of renewable diesel fuel annually. This support works in concert with Alberta’s Renewable Fuels Standard which requires commercial fuel producers to blend renewable products into their fuels. SBI’s facility strengthens Alberta’s expanding industrial bio-product sector and gives Alberta farmers a new market for off-grade canola.
New highly selective catalytic process for conversion of vegetable oils to diesel-range alkanes under mild conditions
March 08, 2016
A team led by researchers from the University of Oxford has developed a simple but highly selective catalytic process for the direct hydrodeoxygenation of vegetable oils (triglycerides) into diesel-range alkanes under mild conditions over a Pd/NbOPO4 catalyst. As reported in their paper in the RSC journal Chemical Communications The mass yields of diesel-range alkanes from palm oil and soybean oil can approach to quantitative values.
A number of approaches are being developed and commercialized to convert vegetable oils into diesel fuels. The current primary commercial pathway is the production of first-generation biodiesel—the transesterification of triglycerides with methanol to form fatty acid methyl ester (FAME), with glycerol as the by-product.
New route to renewable diesel and jet from biomass-derived platform compounds
February 29, 2016
Researchers in China have developed a new route to the production of renewable diesel and jet fuel-range branched alkanes by combining the hydroxyalkylation/alkylation (HAA) of 2-methylfuran (MF)—a biomass-derived platform compound—with angelica lactone—another biomass-derived compound—and subsequent hydrodeoxygenation.
Under solvent-free conditions, the researchers obtained 81.3% yield of HAA products; after the HDO of the hydrogenated HAA products over 5 wt% Pd/C catalyst, they achieved 81.0% carbon yield of diesel or jet fuel-range alkanes. Compared to a 2-MF–levulinic acid (or ester) route proposed in their earlier work, the new 2-MF–angelica lactone route offers higher HAA reactivity.
Mercedes-Benz Trucks approves HVO renewable diesel for its medium- and heavy-duty engines; neat or blended
February 22, 2016
With immediate effect, Mercedes-Benz Trucks is granting approval for the use of Hydrotreated Vegetable Oil (HVO) renewable diesel for the in-line six-cylinder engine variants of the Mercedes-Benz OM 470, OM 471 (first generation) and OM 936 as well as the in-line four-cylinder variants of the OM 934 meeting the Euro VI emissions standard. The engines are designed as standard to make use of the new HVO fuel. The approval applies to all engine variants whatever their output category.
HVO is a renewable diesel produced from waste materials such as waste fat, used cooking oil and also oil from crop plants. The HVO raw material is sourced from controlled and certified cultivation facilities and as such does not compete with foodstuff production. A leading example is Neste’s NEXBTL.
Process for production of jet-range hydrocarbons from crude Jatropha oil using hydrogen produced in-situ from formic acid
February 16, 2016
A team at the Korea Institute of Energy Research has developed a catalytic process for the production of jet-range oxygen-free hydrocarbons from crude Jatropha oil, using hydrogen produced in-situ from formic acid.
In a fixed bed reaction using a mixture of crude Jatropha oil and formic acid, normal hydrocarbon in the range of C10–C18 (mostly C15 and C17) was the main product—about 97% in the liquid product—and the degree of deoxygenation was about 99.5%. A paper on their work is published in the journal Fuel.
DOE to award up to $11.3M for biomass-to-hydrocarbon biofuels pathways; MEGA-BIO
February 09, 2016
The US Department of Energy (DOE) will provide up to $11.3 million in funding to develop flexible biomass-to-hydrocarbon biofuels conversion pathways that can be modified to produce advanced fuels and/or products based on external factors, such as market demand. (DE-FOA-0001433: MEGA-BIO: Bioproducts To Enable Biofuels.)
These pathways can consist of a route to a platform chemical that could be converted to products or renewable hydrocarbon fuels or a route that co-produces chemicals and renewable hydrocarbon fuels.
UCR team advances direct production of chemical and fuel precursors in yeast
January 28, 2016
A team led by a researcher at the University of California, Riverside has adapted the CRISPR-Cas9 gene editing system for use in a yeast strain that can produce useful lipids and polymers. The development will lead to new precursors for biofuels, specialty polymers, adhesives and fragrances.
Published recently in an open-access paper in the journal ACS Synthetic Biology, the research involves the oleaginous (oil-producing) yeast Yarrowia lipolytica, which is known for converting sugars to lipids and hydrocarbons that are difficult to make synthetically. Until now, Y. lipolytica has been hard to manipulate at the genetic level, but the application of CRISPR-Cas9 will change that, allowing scientists to tap into its bio-manufacturing potential.