[Due to the increasing size of the archives, each topic page now contains only the prior 365 days of content. Access to older stories is now solely through the Monthly Archive pages or the site search function.]
DOE Bioenergy Technologies Office updates Multi-Year Program Plan; focus on wet wastes
April 05, 2015
The US Department of Energy (DOE) Bioenergy Technologies Office (BETO) released its newly updated and detailed Multi-Year Program Plan (MYPP). The MYPP sets forth the goals and structure of the Office, and identifies the research, development, demonstration, market transformation, and crosscutting activities on which the Office is planning to focus over the next five years.
The latest version of the MYPP presents a merged conversion R&D section; the renaming of the demonstration and market transformation area; and emerging work in wet waste-to-energy feedstocks. BETO says that wet wastes represent an underused feedstock and an emerging pathway to advanced biofuels that has the potential to greatly contribute to BETO’s near-term and long-term advanced biofuel and bioproduct goals.
NASA-led analysis characterizes the impact of jet fuel composition on emitted aerosols
April 03, 2015
Using data gathered during four different, comprehensive ground tests conducted over the past decade, researchers from NASA and their colleagues have statistically analyzed the impact of jet fuel properties on aerosols emitted by the NASA Douglas DC-8 CFM56-2-C1 engines burning 15 different aviation fuels. The analysis, reported in a paper in the ACS journal Energy & Fuels, linked changes in aerosol emissions to fuel compositional changes.
Among the results was the finding that reducing both fuel sulfur content and naphthalenes to near-zero levels would result in roughly a 10-fold decrease in aerosol number emitted per kilogram of fuel burned. The study can inform future efforts to model aircraft emissions changes as the aviation fleet gradually begins to transition toward low-aromatic, low-sulfur alternative jet fuels from bio-based or Fischer–Tropsch production pathways.
New UK Energy & Fuels 2050 transportation roadmap highlights important role of drop-in fuels and power-to-gas
March 23, 2015
Professor Neville Jackson, Ricardo’s chief technology and innovation officer, presented the results of a research project carried out by the Automotive Council UK to establish a long-term (to 2050) transition from current gasoline and diesel fuels to a majority renewable energy portfolio. Inputs to the new Energy & Fuels Roadmap included recent UK & EU studies on automotive technologies, as well as roadmaps for passenger cars, commercial vehicles and internal combustion engines previously published by the Automotive Cuncil.
The research, presented at last week’s Open Forum organized by the Society of Motor Manufacturers and Traders (SMMT) in London, aimed to create a high level consensus view for the future of transport energy in the UK. Chaired by Professor Jackson of Ricardo, the research team that produced the report was made up of representatives drawn from a wide range of industry stakeholder organizations including BP, Shell, Jaguar LandRover, Caterpillar, the Energy Technologies Institute, the Low Carbon Vehicle Partnership, E4tech, Element Energy and Associated British Foods.
Navy researchers produce 100% bio-derived high-density renewable diesel and jet by blending sesquiterpanes with synthetic paraffinic kerosene
March 06, 2015
A team at the Naval Air Warfare Center Weapons Division (NAWCWD) at China Lake has produced 100% bio-derived high-density renewable diesel and jet fuels by blending multicyclic sesquiterpanes with a synthetic paraffinic kerosene (5-methylundecane). The resulting renewable fuels have densities and net heats of combustion higher than petroleum-based fuels while maintaining cetane numbers high enough (between 45 and 57) for use in conventional diesel engines.
The team said that its results show that full-performance and even ultra-performance fuels can be generated by combining bio-derived sesquiterpanes and paraffins. All components can be generated from biomass sugars by a combination of fermentation and chemical catalysis which may allow for their production at industrially relevant scale, they noted. An open access paper on the work has been accepted for publication in the ACS journal Energy & Fuels.
Neste Oil now the world’s largest producer of renewable fuels from waste and residues
March 05, 2015
Over the last few years, Neste Oil has become the world’s largest producer of renewable fuels from waste and residues. In 2014, the company produced nearly 1.3 million tonnes (1.6 billion liters, 423 million gallons US) of renewable fuel from waste and residues. In practical terms, this is enough to power for two years all the 650,000 diesel-powered passenger cars in Finland with NEXBTL renewable diesel manufactured from waste and residues.
Examples of Neste Oil’s waste and residue-based raw materials include animal and fish fats; used cooking oil; and various residues generated during vegetable oil refining such as palm fatty acid distillate (PFAD) and technical corn oil. These raw materials accounted for 62% of Neste Oil’s renewable inputs in 2014 (52% in 2013, 35% in 2012).
DOE BETO awards $10M to 7 advanced biofuels projects
February 21, 2015
The US Department of Energy’s (DOE) Bioenergy Technologies Office (BETO) has selected seven projects to receive up to $10 million to support innovative technologies and solutions to help advance the development of advanced biofuels, including bugaboo and drop-in hydrocarbons.
The Bioenergy Technologies Office is working to produce cost-competitive ($3/gallon of gasoline equivalent) advanced biofuels from non-food biomass resources that reduce greenhouse gas emissions by 50% or more versus petroleum-based alternatives. These newly selected projects are intended to support this effort.
California ARB issues feedstock-only pathway for camelina-based fuels under LCFS; zero ILUC emissions results in very low CI fuels
February 05, 2015
The California Air Resources Board has issued Sustainable Oils Inc., a wholly owned subsidiary of Global Clean Energy Holdings, a feedstock-only pathway for the production of camelina-based fuels under the Low Carbon Fuel Standard (LCFS). The feedstock-only CI (carbon intensity) is 7.58 gCO2e/MJ.
A feedstock-only pathway allows a fuel producer interested in producing either biodiesel or renewable diesel from a camelina feedstock using Sustainable Oils’ proprietary seed varieties to combine the CI of this pathway for the production of a camelina oil feedstock with the carbon intensity components of the fuel producer’s specific fuel production and transportation processes. The feedstock-only pathway includes only the CI components for farming, agricultural chemicals, camelina transportation, and oil extraction.
Researchers devise method to produce jet-range hydrocarbons as co-product of production of algal biodiesel; role of alkenones
January 22, 2015
|Isochrysis extraction and fractionation scheme with yields given in parentheses for the different products obtained from each step. Credit: ACS, O’Neil et al. Click to enlarge.|
Researchers from Western Washington University and Woods Hole Oceanographic Institution have developed a method to produce jet-fuel range hydrocarbons as a co-product of the production of algal biodiesel from the biomass of the industrially grown marine microalgae Isochrysis. A paper on their work is published in the ACS journal Energy & Fuels.
Certain species of algae—including Isochrysis—synthesize a unique class of lipids: long-chain (35-40 carbons) alkenones. The structure of alkenones is characterized by a very long liner carbon chain with trans double bonds and a methyl or ethyl ketone. The researchers developed a method for the isolation of pure alkenones from Isochrysis biomass in parallel with biodiesel production.
Thai researchers find waste chicken fat a good low-cost feedstock for renewable diesel
January 19, 2015
In a study investigating the effect of the water and free fatty acid (FFA) content in waste chicken fat from poultry processing plants on the production of renewable diesel (not biodiesel), researchers in Thailand have found that both higher FFA and water content improved the biohydrogenated diesel (BHD) yield.
In their paper, published in the ACS journal Energy & Fuels, they reported that the presence of water accelerated the breakdown of the triglyceride molecules into FFAs, while the presence of more FFAs also increased yield. Therefore, they concluded, waste chicken fat from food industries containing a high degree of FFAs and water content can be used as a low-cost feedstock for renewable diesel production without requiring a pretreatment process.
Purdue process converts lignin in intact biomass to hydrocarbons for chemicals and fuels
December 18, 2014
A team of researchers from Purdue University’s Center for Direct Catalytic Conversion of Biomass to Biofuels, or C3Bio, has developed a process that uses a bimetallic Zn/Pd/C catalyst to convert lignin in intact lignocellulosic biomass directly into two methoxyphenol products (phenols are a class of aromatic hydrocarbon compounds used in perfumes and flavorings) leaving behind the carbohydrates as a solid residue.
Lignin-derived methoxyphenols can be further deoxygenated to propylcyclohexane—a cycloalkane. Cycloalkanes are important components of not only traditional vehicle fuels such as gasoline and diesel, but also jet fuels, such as Jet-A/Jet-A1/JP-8.
Vertimass selected for negotiation for up to $2M from DOE for conversion of ethanol into gasoline, diesel and jet blendstocks; expanding the ethanol market (updated)
December 05, 2014
|Ethanol conversion to hydrocarbons as a function of temp. at a LHSV of 2.93 h−1. Source: US 20140100404 A1. Click to enlarge.|
Vertimass LLC has been selected for negotiation of an award to receive up to $2 million from the Bioenergy Technologies Office (BETO) within the US Department of Energy’s Office of Energy Efficiency and Renewable Energy (earlier post) to support the commercialization of catalyst technology that converts ethanol into gasoline, diesel and jet fuel blend stocks, while retaining compatibility with the current transportation fuel infrastructure. (Earlier post.)
The technology—developed by Oak Ridge National Laboratory’s (ORNL) Chaitanya Narula, Brian Davison and Associate Laboratory Director Martin Keller and licensed exclusively by Vertimass—is expected to allow expansion of the ethanol market beyond current constraints. Existing US ethanol production plants currently have a capacity of approximately 14 billion gallons per year, a level that saturates current use as 10% blends with gasoline. However, the new Vertimass catalyst breaks that barrier by producing a hydrocarbon blend stock compatible in higher-level blends.
Boeing conducts world’s first flight with 15% blend of NExBTL renewable diesel as aviation biofuel
December 04, 2014
Boeing has completed the world’s first flight using “green diesel,” a renewable, drop-in hydrocarbon biofuel that is widely available and used in ground transportation. The company powered its ecoDemonstrator 787 flight test airplane with a blend of 15% NExBTL renewable diesel from Neste Oil and 85% petroleum jet fuel in the left engine. (Neste Oil can also produce a NExBTL synthetic paraffinic kerosene as a discrete, and already approved, commercial aviation fuel.)
Boeing previously found that renewable diesel is chemically similar to HEFA (hydro-processed esters and fatty acids) aviation biofuel approved in 2011. With a renewable diesel production capacity of 800 million gallons (3 billion liters) in the US, Europe and Asia, the on-road fuel could rapidly supply as much as 1% of global jet fuel demand. With a wholesale cost of about $3 per gallon, inclusive of US government incentives, green diesel approaches price parity with petroleum jet fuel.
DOE JBEI team boosts methyl ketone production from E. coli 160-fold; advanced biofuel or blendstock
December 02, 2014
In 2012, researchers at the US Department of Energy’s Joint BioEnergy Institute (JBEI) engineered Escherichia coli (E. coli) bacteria to overproduce from glucose saturated and monounsaturated aliphatic methyl ketones in the C11 to C15 (diesel) range from glucose. In subsequent tests, these methyl ketones yielded high cetane numbers, making them promising candidates for the production of advanced biofuels or blendstocks. (Earlier post.)
Now, after further genetic modifications of the bacteria, they have managed to boost the E.coli’s methyl ketone production 160-fold. A paper describing this work is published in the journal Metabolic Engineering.
Lifecycle analysis of Amyris renewable jet from sugar cane finds “substantial potential” to mitigate GHG emissions, but a wide range of potential outcomes
November 25, 2014
|Monte Carlo results for the net life cycle emissions of the renewable jet fuel from sugar cane. Credit: ACS, Moreira et al.. Click to enlarge.|
Brazilian researchers evaluating the lifecycle GHG emissions of a renewable jet fuel produced from sugar cane in Brazil using Amyris’ proprietary technology platform (earlier post) found that the farnesane-based renewable fuel presents “a substantial potential” to mitigate the GHG emissions of the aviation sector. Their paper is published in the ACS journal Environmental Science & Technology.
In their base case, the researchers calculated a “rather optimistic” GHG footprint of 8.5g CO2eq/MJ; lifecycle emissions of fossil jet fuel usually lie within the 80−95g CO2eq/MJ range. However, they noted, the estimation is highly uncertain, with a number of factors—especially related to electricity exports, sugar cane farming itself, and agrochemicals production and use—significantly affect the outcome. The results of the Monte Carlo analysis indicate life cycle emissions of 21 ± 11 g CO2eq/MJ (mean ± SD), with substantial influence from the LUC factor.
DOE Bioenergy Technologies Office updates 5-year program plan; commercially viable hydrocarbon biofuel technologies by 2017; <$3/GGE
November 23, 2014
|BETO high-level schedule. Click to enlarge.|
The US Department of Energy (DOE) Bioenergy Technologies Office (BTO) has updated its Multi-Year Program Plan (MYPP), which delineates the goals and structure of the office. BTO is one of the 10 technology development offices within the Office of Energy Efficiency and Renewable Energy (EERE) at DOE.
The MYPP identifies the research, development, demonstration, and deployment (RDD&D) activities the Office will focus on over the next five years and explains why these activities are important. The MYPP is intended for use as an operational guide to help BETO manage and coordinate its activities, as well as a resource to help communicate its mission and goals to stakeholders and the public.
EPA delays issuing 2014 RVO standards for RFS until sometime in 2015
November 21, 2014
The US Environmental Protection Agency (EPA) will not finalize the 2014 applicable percentage standards (the 2014 Renewable Volume Obligations, RVOs) under the Renewable Fuel Standard (RFS) program until sometime next year. In a notice to be published in the Federal Register, the agency said that it intends to take action on the 2014 standards rule in 2015 prior to or in conjunction with action on the 2015 standards rule.
Because of the delay in issuing the 2014 RFS standards, EPA is moving the compliance demonstration deadline for the 2013 RFS standards to 2015. EPA will make modifications to the Moderated Transaction System (EMTS) to ensure that Renewable Identification Numbers (RINs) generated in 2012 are valid for demonstrating compliance with the 2013 applicable standards.
Purdue team demonstrates proof-of-concept of H2Bioil process; liquid fuel range hydrocarbons from biomass
November 17, 2014
|H2Bioil concept. Venkatakrishnan et al. Click to enlarge.|
Researchers at Purdue University report a proof-of-concept of a their novel consecutive two-step process (H2Bioil) for the production of liquid fuel range hydrocarbons (C4+) with undetectable oxygen content from cellulose and an intact biomass (poplar). (Earlier post.)
Purdue University filed a patent application on the H2Bioil concept, which is based on fast-hydropyrolysis and downstream vapor-phase catalytic hydrodeoxygenation (HDO), in 2008. The process adds hydrogen into the biomass-processing reactor and is made possible by development of a new catalyst and the innovative reactor design. Findings are described in a research paper published online in the RSC journal Green Chemistry.
Researchers in China produce highest octane gasoline fuel reported from biomass
November 11, 2014
Researchers in China have generated gasoline fuel with a research octane number of 95.4 from biomass-derived γ-valerolactone (GVL)—the highest octane number reported for biomass-derived gasoline fuel—using an ionic liquid catalyst. A paper on their work is published in the RSC journal Green Chemistry.
In the study, they converted biomass-derived γ-valerolactone into gasoline by the decarboxylation of valerolactone to produce butenes and the subsequent alkylation of the produced butenes with butane using [CF3CH2OH2][CF3CH2OBF3] as an efficient catalyst. The obtained gasoline was rich in trimethylpentane (isooctane), with the RON of 95.4.
California Energy Commission to award up to $3M for advanced biofuel projects
October 28, 2014
The California Energy Commission’s Alternative and Renewable Fuel and Vehicle Technology Program (ARFVTP) announced (PON-14-602) the availability of up to $3 million in grant funds for biofuels projects that are in the early/pre-commercial technology development stage. This solicitation is emphasizing transformative technology solutions to significant biofuels industry problems that increase yields, productivity, or cost effectiveness of biofuel production; and/or that target a significant unmet need in California’s biofuels industry.
The ARFVTP has an annual budget of approximately $100 million and provides financial support for projects that increase the use of alternative and renewable fuels and advanced vehicle technologies.
Neste Oil seeking California LCFS approval for gutter oil to renewable diesel pathway
October 26, 2014
Among four new California Low Carbon Fuel Standard (LCFS) fuel pathway applications is a used cooking oil (gutter oil) to renewable diesel (NExBTL) pathway from Neste Oil at its Singapore plant. (Boeing and COMAC are opening a demonstration facility in China to convert gutter oil to renewable aviation fuel. Earlier post.)
Neste Oil Singapore Pte Ltd. produces approximately 250 million gallons annually of drop-in renewable diesel (RD)—i.e., not biodiesel—using a hydrogenation process and multiple oil and fat feedstocks. Neste has also filed applications for renewable diesel pathways for California (all from its Singapore plant) using Southeast Asian rendered fish oil (earlier post); New Zealand tallow (earlier post); North American tallow (earlier post), and Australian tallow (earlier post). Of the five RD pathways proposed so far, the gutter oil pathway has the lowest carbon intensity.
New WSU palladium-iron catalyst could improve drop-in biofuels production from pyrolysis oils
October 17, 2014
|The addition of palladium (Pd) prevents deactivation (addition of oxygen, red spheres) of an iron catalyst in the reaction that removes oxygen from biofuel feedstock. Credit: ACS, Hensley et al.. Click to enlarge.|
Washington State University researchers have developed a new palladium-iron hydrodeoxygenation catalyst (Pd/Fe2O3) that could lead to making drop-in biofuels cheaply and more efficiently. Their work is described in two papers in the October issue of the journal ACS Catalysis and is featured on the cover.
The first WSU paper (Hong et.al) describes the synthesis of a series of Pd/Fe2O3 catalysts and their performance for the hydrodeoxygenation of m-cresol—a phenolic compounds used as a model compound in the HDO research, as it can be derived from pyrolysis of lignin. The second (Hensley et al.) reports on a combined experimental and theoretical approach to understand the potential function of the surface Pd in the reduction of Pd/Fe2O3.
Solazyme and Amyris receive Presidential Green Chemistry Challenge awards
October 16, 2014
The US Environmental Protection Agency (EPA) has announced the 5 winners of the 2014 Presidential Green Chemistry Challenge Awards, including biotechnology companies Amyris and Solazyme, Inc. Solazyme received the award for Greener Synthetic Pathways for its tailored oils produced from microalgal fermentation. Amyris received the Small Business award for its renewable hydrocarbon farnesane for use as diesel and jet fuel.
Amyris has engineered yeast to make the hydrocarbon farnesene via fermentation instead of ethanol. Farnesene is a building block hydrocarbon that can be converted into a renewable, drop-in replacement for petroleum diesel without certain drawbacks of first-generation biofuels. A recent lifecycle analysis estimated an 82% reduction in GHG emissions for farnesane, compared with the EPA baseline fossil diesel—including indirect effects.
Neste Oil de-emphasizing microbial oil R&D for renewable diesel; seeking other uses for cellulosic biomass
October 07, 2014
Neste Oil, the producer of NExBTL renewable diesel, is realigning its long-term R&D and switching from an emphasis on research into the production of microbial oil as a feedstock for NExBTL renewable diesel and renewable jet fuel (earlier post) to other areas of technology for using cellulosic forestry and agricultural waste, due in part to feedstock cost issues.
Despite the decision to de-emphasize microbial oil, Neste Oil emphasized that cellulosic waste will continue to play an important role in its research strategy, adding that it remains committed to its goal of further extending its feedstock base and making greater use of waste and residues in this area in particular.
USDA provides $91M loan guarantee to Cool Planet for biogasoline blendstock plant; biomass pyrolysis and catalytic conversion
October 05, 2014
|Gas chromatography comparison of Conoco fuel and a Conoco-CoolPlanet blend. Cool Planet’s biogasoline blendstock is 100% compatible with pump gasoline. Source: Cool Planet. Click to enlarge.|
USDA has reached an agreement with Silicon Valley Bank to provide a $91-million Biorefinery Assistance Program loan guarantee to Cool Planet to help the company finish construction on an advanced biofuel plant at the Port of Alexandria in Louisiana. (Earlier post.)
Cool Planet has devised a biomass-to-liquids thermochemical conversion process that simultaneously produces liquid fuels and sequesterable biochar useful as a soil amendment. The Cool Planet plant will produce approximately 8 million to 10 million gallons of high-octane, renewable gasoline blendstocks (reformate), as well the biochar, all made from sustainable wood residues.
Southwest Airlines signs purchase agreement with Red Rock Biofuels for renewable jet fuel from forest residues; ~3M gallons per year
September 24, 2014
Southwest Airlines has signed an agreement with Red Rock Biofuels LLC (RRB) to purchase low carbon renewable jet fuel, made using forest residues that will help reduce the risk of destructive wildfires in the Western United States. The airline’s agreement with RRB covers the purchase of approximately three million gallons per year. The blended product will be used at Southwest’s Bay Area operations with first delivery expected in 2016.
RRB’s first plant will convert approximately 140,000 dry tons of woody biomass feedstock into at least 12 million gallons per year of renewable jet, diesel, and naphtha fuels. The company recently received a $70-million grant under phase 2 of the US Defense Production Act Title III Advanced Drop-in Biofuels project for construction of the facility, which will also produce mil-spec fuels. (Earlier post.)
Departments of the Navy, Energy and Agriculture award $210M in contracts for 3 drop-in fuel biorefineries; more than 100M gallons/year
September 20, 2014
The US Departments of Navy, Energy, and Agriculture have awarded contracts worth a combined $210 million to three companies—Emerald Biofuels, Fulcrum BioEnergy and Red Rock Biofuels—to construct and commission biorefineries capable of producing drop-in biofuels. In total, these projects are intended to produce more than 100 million gallons of military-grade fuel beginning in 2016 and 2017 at a price competitive with their petroleum counterparts.
The awards were made through the Department of Defense’s (DOD) Defense Production Act (DPA) of 1950, which was passed at the beginning of the Korean War to empower the President, among other things, with an array of authorities to shape national defense preparedness programs and to take appropriate steps to maintain and enhance the domestic industrial base. DPA has been re-authorized multiple times since then.
California Energy Commission awards $5M grant to AltAir Fuels to expand renewable diesel production; $3M to GFP Ethanol for sorghum feedstock
September 11, 2014
The California Energy Commission approved $8 million in grants to two biofuel companies stemming from a solicitation issued earlier this year (PON-13-609: Pilot-Scale and Commercial-Scale Advanced Biofuels Production Facilities).
AltAir Fuels LLC (earlier post) will receive $5 million to expand production of renewable diesel fuels at its Paramount facility in Los Angeles County from 30 million gallons per year to 40 million gallons per year, and allow for processing of additional feedstocks. This facility will also co-produce renewable jet at commercial scale and a byproduct chemical and gasoline component. GFP Ethanol is receiving $3 million to support the development of sorghum as a feedstock for lower carbon intensity ethanol.
Solar fuels company Joule looks to partner with Scatec Solar to bring photovoltaic power to Joule production plants
September 05, 2014
Joule, the developer of a direct, single-step, continuous process for the production of solar hydrocarbon fuels (earlier post), has entered into a memorandum of understanding (MoU) with Scatec Solar ASA, a leading, independent solar power producer. In the MoU the parties have agreed to initiate a process to reach specific terms for a partnership, to support the roll-out of Joule production plants featuring photovoltaic power.
The terms of the MoU anticipate that Scatec Solar ASA will become preferred supplier and operator of photovoltaic power installations for Joule plants, with an initial deployment goal of up to 25,000 acres (~10,000 hectares) and a power requirement of 2 gigawatts. A deployment of this scale would generate up to 625 million gallons (~15 million barrels) of ethanol or 375 million gallons (~9 million barrels) of diesel per year, while consuming about 4 million tonnes of industrial waste CO2 annually in the process.
USDA closes on $105M loan guarantee to Fulcrum for biorefinery converting municipal waste to renewable jet fuel; first USDA loan for biojet
September 04, 2014
The US Department of Agriculture (USDA) has closed on a $105-million Biorefinery Assistance Program loan guarantee through Bank of America, N.A. to Fulcrum Sierra Biofuels, LLC to build a biorefinery to produce jet fuel from municipal solid waste (MSW) via a proprietary two-stage thermochemical process. (Earlier post.)
USDA Rural Development’s loan guarantee represents less than half of the $266 million project cost. The plant is expected to produce 11 million gallons of fuel annually. This is the first loan guarantee USDA has made for the production of bio jet fuel.
Researchers successfully engineer E. coli to produce renewable propane; proof-of-concept
September 03, 2014
Researchers from the University of Turku in Finland, Imperial College London and University College London have devised a synthetic metabolic pathway for producing renewable propane from engineered E. coli bacteria. Propane, which has an existing global market for applications including engine fuels and heating, is currently produced as a by-product during natural gas processing and petroleum refining. A paper on their work is published in Nature Communications.
The new pathway is based on a thioesterase specific for butyryl-acyl carrier protein (ACP), which allows native fatty acid biosynthesis of the Escherichia coli host to be redirected towards a synthetic alkane pathway. Although the initial yields were low, the team was able to identify and to add essential biochemical components in order to boost the biosynthesis reaction, enabling a the E. coli strain to increase propane yield, although the amounts are still far too low for commercialization.
PNNL study uncovers role of water in forming impurity in bio-oil upgrading; insight into fundamentals of biofuel catalysis
August 21, 2014
In working to elucidate the chemistry of hydrodeoxygenation (HDO) for the catalytic upgrading of pyrolytic bio-oil to fuel-grade products, researchers at Pacific Northwest National Laboratory (PNNL) have discovered that water in the conversion process helps form an impurity which, in turn, slows down key chemical reactions. Results of the study, which was reported in the Journal of the American Chemical Society, can help improve processes that produce biofuels from plants.
The study examines the conversion of bio-oil, produced from biomass such as wood chips or grasses, into transportation fuels. Researchers used density functional theory (DFT)-based ab initio molecular dynamics calculations to provide a detailed atomic-level understanding of how the hydrogenation reactions are influenced by the presence of water and also by the nature of the hydrogenating metal. The results of the study apply not only to water but to related liquids in bio-oil such as alcohols and certain acids.
New palladium oxalate hydrodeoxygenation catalyst for production of drop-in paraffinic biofuels
August 17, 2014
Researchers in Malaysia and Oman have developed a novel palladium oxalate catalyst supported on zeolite A (PdOx/ Zeol) with increased acidity for the hydrodeoxygenation and isomerization of bio-feedstocks into paraffinic (drop-in) biofuels. In a paper in the ACS journal Energy & Fuel, they report the hydrodeoxygenation (HDO) of stearic acid (SA) (one of the most common saturated fatty acids found in nature following palmitic acid) into paraffinic biofuel.
Their best observed conditions for the process were 360 °C, 20 bar, 100 mL/min, and 25 mg to achieve 92% biofuel production from 35 g SA. The biofuel product distribution showed 71% n-C18H38, 18% iso-C18H38, and 3% C17H36.
Emissions study suggests E10 + renewable hydrocarbons a high bioenergy alternative for conventional cars
August 14, 2014
Researchers from VTT Technical Research Center of Finland and Neste Oil analyzed the exhaust emissions from three different spark ignition engine technologies—multipoint fuel injection (MPFI); direct-injection spark-ignition (DISI); and flex-fuel (FFV)—using different biofuels—low- and high-concentration ethanol blends; isobutanol; and biohydrocarbons. They report their findings in a paper in the ACS journal Environmental Science & Technology.
Among their conclusions was that the combination of ethanol or isobutanol with renewable hydrocarbon components (i.e., drop-in biohydrocarbons) could offer an option to achieve a high-bioenergy-content gasoline that is compatible with conventional gasoline-fueled cars (i.e., those limited to a 10% ethanol blend) without a significant change in emissions.
Virent receives EPA fuel registration for BioForm biogasoline blends up to 45%
August 13, 2014
|Gas chromatographs (samples stacked for clarity) of Virent’s BioFormate biogasoline reformate vs. conventional petroleum reformate. Source: Virent. Click to enlarge.|
Virent has received fuel registration from the US Environmental Protection Agency (EPA) for its BioForm drop-in biogasoline in blends of up to 45%. (Earlier post.) As a registered fuel, Virent’s biogasoline can now be used in on-highway motor vehicles.
Virent BioForm Gasoline blended with conventional gasoline underwent testing at Southwest Research Institute (SWRI) with the results demonstrating that the emissions from the blended fuel were well below the maximum permitted by current regulations. The fuel was manufactured by Virent at its demonstration plant in Madison, Wisconsin, which is capable of producing up to 10,000 gallons of biofuels and biochemicals per year. The EPA testing work was funded by Virent partner Royal Dutch Shell.
Boeing partners with South African Airways to convert Solaris energy tobacco into jet fuel
August 07, 2014
|Solaris energy tobacco is optimized for seed production for energy applications, not leaf production. Click to enlarge.|
Boeing, South African Airways (SAA) and SkyNRG are collaborating to make sustainable aviation biofuel from Solaris, a new hybrid tobacco plant optimized for seed production for energy applications. This initiative broadens cooperation between Boeing and SAA to develop renewable jet fuel in ways that support South Africa’s goals for public health as well as economic and rural development.
Solaris is a new, non-GMO, high-seed tobacco variety protected by patents, the rights to which are held by Sunchem Holdings in Italy, which is partnering with US-based Tyton BioEnergy Systems on its testing and deployment. Solaris maximizes the production of flowers and seeds to the detriment of the leaves production, and biomass for biogas production. The plant is extremely robust, and is able to grow in various climates and soils. One hectare of Solaris can deliver an average seed yield of 4 to 10 tonnes with multiple harvests per year (depending on climate conditions). The seed contains around 40% oil.
UC Riverside team develops new high efficiency method for conversion of biomass to biofuels
August 04, 2014
|Overview of the process. Cai et al. (2014) Click to enlarge.|
A team of researchers, led by Professor Charles E. Wyman, the Ford Motor Company Chair in Environmental Engineering at the University of California, Riverside’s Bourns College of Engineering, has developed a versatile, relatively non-toxic, and efficient way to convert lignocellulosic biomass into biofuels and chemicals.
The method couples the use of a metal halide selective catalyst with a highly tunable co-solvent—renewable tetrahydrofuran (THF)—to enhance co-production of the fuel precursors furfural and 5-HMF from biomass in a single-phase reaction strategy capable of integrating biomass deconstruction with catalytic dehydration of sugars. Those fuel precursors can then be converted into ethanol, chemicals or drop-in fuels.
Ethanol producer to integrate renewable diesel production from corn distiller oil
July 25, 2014
Ethanol producer East Kansas Agri-Energy LLC (EKAE) intends to integrate renewable diesel production at its ethanol plant in Garnett, Kansas. Renewable diesel will be made from the corn distillers oil (CDO) already produced at the plant along with other feedstocks purchased on the market. WB Services is the technology provider for the catalytic renewable diesel process.
Construction on the new facility will begin soon and will be complete in about 12 to 14 months. The plant will be able to produce three million gallons of hydrocarbon fuel per year, with the ability to double that capacity in the future. The plant currently produces some 40 million gallons of ethanol; 200,000 tons of the livestock feed distillers grains; and 5 million pounds of corn oil each year from more than 16 million bushels of locally-sourced corn.
California Energy Commission selects 11 advanced biofuels projects for $43.6M in awards
The California Energy Commission (CEC) has selected 11 biofuel projects projects—including gasoline substitutes, diesel substitutes and biomethane projects—for $43,633,421 in awards under a grant solicitation released in January for the development of new, or the modification of, existing California-based biofuel production facilities that can sustainably produce low carbon transportation fuels.
The grant solicitation had announced a total of $24 million available for projects funded by the solicitation; however, the Energy Commission, at its sole discretion, reserves the right to increase or reduce the amount of funds available.
Researchers synthesize diesel- and jet-range cycloalkanes from lignocellulosic platform compounds
July 18, 2014
Researchers at the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, have synthesized, for the first time, a mixture of C9−C15 branched alkanes and cycloalkanes with relatively higher density from 2-Methylfuran (2-MF) and cyclopentanone (CPO)—selective hydrogenation products of furfural, which can be produced in industrial scale with lignocellulose.
Most work done so far with lignocellulose-based platform compounds has concentrated on the production of diesel (C9−C21) or jet fuel (C8−C16) range straight-chain alkanes and/or branched-chain alkanes, the team notes in their paper in the ACS journal Energy & Fuels. Although those alkanes have good thermal stability and excellent combustion efficiency, their lower densities require blending with conventional jet fuel (a mixture of straight-chain alkanes, branched-chain alkanes, and cyclic hydrocarbons) to meet the specifications of aviation fuel.
New one-pot process for conversion of cellulose to n-hexane, a gasoline component
June 26, 2014
|One-pot process for conversion of cellulose to hexane, a gasoline component. Credit: ACS, Liu et al. Click to enlarge.|
Researchers at Tohoku University in Japan have developed a one-pot process to convert cellulose to n-hexane in the presence of hydrogen gas. According to the US Environmental Protection Agency (EPA), unleaded gasoline contains about 11.6% n-hexane.
In a paper in the journal ACS Sustainable Chemistry & Engineering, the Tohuku team reports achieving a yield of n-hexane of 83% from ball-milled cellulose and 78% from microcrystalline cellulose. Even using a high weight ratio of cellulose to water (1:1), a 71% yield of n-hexane could be obtained from ball-milled cellulose.
LowCVP reports indicate pathways for meeting renewable energy targets in transportation, decarbonizing fuel to 2030 and beyond
June 18, 2014
|Illustrative impact of the fuel roadmap. Source: LowCVP, Element Energy. Click to enlarge.|
The UK’s LowCVP has published twin reports which set out how the UK could meet its 2020 targets defined in the EU’s Renewable Energy Directive, and proceed on a pathway to decarbonize road transport fuel in the period to 2030 and beyond.
The LowCVP—the stakeholder body which brings government, industry and other stakeholders together to focus on the challenges of decarbonizing road transport—commissioned energy consultancy Element Energy to analyze the UK’s options for meeting the Renewable Energy Directive’s (RED) 2020 transport target which states that at least 10% of the final energy consumption in transport must come from renewable sources. This and the parallel Fuels Roadmap report benefitted from wide industry consultation and explicitly set out to align with existing powertrain roadmaps (including those published by the Automotive Council and the LowCVP).
Total and Amyris preparing to market jet fuel with 10% farnesane; direct sugar to hydrocarbons product
June 16, 2014
|The D7566 committee is running a number of task forces on alternative fuels; the use of farnesane is one of those (red outline). Source: CAAFI. Click to enlarge.|
With the release of the newly revised ASTM D7566-14 standard for jet fuel, Amyris and Total have begun to prepare to market a drop-in jet fuel that contains up to 10% blends of renewable farnesane. (Earlier post.)
The revised standard, developed by ASTM Committee on Petroleum Products, Liquid Fuels, and Lubricants, now includes the use of renewable farnesane as a blending component in jet fuels for commercial aviation. This latest version of ASTM D7566, Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons, will allow a biomass-based renewable jet fuel, as developed by Amyris and Total, to support the commercial airliners’ goal of reducing greenhouse gas emissions.
International team sequences Eucalyptus genome; potential for improving biofuel and biomaterial production
June 14, 2014
An international team of researchers has sequenced the genome of the eucalyptus tree (Eucalyptus grandis) and published the analysis in an open access paper in the journal Nature. With its prodigious growth habit, the eucalyptus tree, one of the world’s most widely planted hardwood trees, has the potential to enhance sustainable biofuels and biomaterials production, and to provide a stable year-round source of biomass that doesn’t compete with food crops.
The researchers reported the sequencing and assembly of more than 94% of the 640-megabase genome of Eucalyptus grandis. Of 36,376 predicted protein-coding genes, 34% occur in tandem duplications, the largest proportion thus far in plant genomes. Eucalyptus also shows the highest diversity of genes for specialized metabolites such as terpenes, which can be substituted catalytically for jet fuel.
Navy fuel solicitation targeting minimum 10% drop-in biofuels component in F-76 and JP-5; at least 39M gallons biofuels
June 11, 2014
The US Navy has posted a Farm-to-Fleet Inland/East/Gulf Coast Solicitation (SP060014R0061) seeking a minimum of about 39 million gallons of drop-in drop-in JP-5 and F-76 biofuels from currently approved pathways—i.e., Hydroprocessed Esters and Fatty Acid (HEFA) or Fischer Tropsch (FT)—for April 2015-March 2016 fuel deliveries.
Under this solicitation, the Navy has a goal that 10% of its total military specification JP-5 aviation turbine fuel and F-76 naval distillate fuel requirements consist of biofuels.
Ames Lab creates multifunctional nanoparticles for cheaper, cleaner renewable diesel
May 13, 2014
Researchers at the US Department of Energy’s Ames Laboratory have developed bi-functional nanoparticles that perform two processing functions at once for the production of renewable diesel via the hydrogenation of oils from renewable feedstocks such as algae.
Iron nanoparticles supported on mesoporous silica nanoparticles (Fe-MSN) catalyze the hydrotreatment of fatty acids with high selectivity for hydrodeoxygenation over decarbonylation and hydrocracking. The selectivity is also affected by the pretreatment of Fe-MSN; the more reduced the catalyst the higher the yield of hydrodeoxygenation product. Fe-MSN catalyzes the conversion of crude microalgal oil into diesel-range hydrocarbons.
Study finds that optimized integrated catalytic processing of biomass could produce renewable jet fuel with selling price as low as $2.88/gallon
May 09, 2014
|Integrated processing of hardwood to renewable jet and chemicals. Click to enlarge.|
A team from seven US universities and the Korea Institue of Science and Technology, led by George Huber, Professor of Chemical and Biological Engineering at the University of Wisconsin-Madison, has developed an integrated catalytic process for the conversion of whole biomass into drop-in aviation fuels with maximal carbon yields.
The researchers expect that in its current state, the proposed technology could deliver jet fuel-range liquid hydrocarbons for a minimum selling price of $4.75 per gallon—assuming nth commercial plant that produces 38 million gallons liquid fuels per year with a net present value of the 20 year biorefinery set to zero. Future improvements in this technology, including replacing precious metal catalysts by base metal catalysts and improving the recyclability of water streams, could reduce this cost to $2.88 per gallon.
DOE seeking stakeholder input on 8 strategic biofuels pathways
May 04, 2014
The US Department of Energy (DOE) has issued a request for information (DE-FOA-0001124) seeking stakeholder input regarding the 8 representative biofuel technology pathways that the Office of Energy Efficiency and Renewable Energy’s (EERE) Bioenergy Technologies Office (BETO) has selected to guide its Research and Development (R&D) strategy in the near-term.
DOE is also seeking input on other pre-commercial pathways that it should consider in the near- to long-term.
EIA: US biomass-based diesel imports increased to record levels in 2013; from net exporter to net importer
May 02, 2014
|Monthly US biodiesel and renewable diesel imports. Source: EIA. Click to enlarge.|
Total US imports of biomass-based diesel fuel—biodiesel and renewable diesel—reached 525 million gallons in 2013, compared to 61 million gallons in 2012, according to the US Energy Information Administration (EIA). As a result, the United States switched from being a net exporter of biomass-based diesel in 2012 to a net importer in 2013 by a wide margin.
Two principal factors drove the increase in US biodiesel imports, EIA said: growth in domestic biodiesel demand to satisfy renewable fuels targets, and increased access to biodiesel from other countries.
Byogy and Avianca launch initiative to accelerate approval of Alcohol-to-Jet (ATJ) fuel
April 25, 2014
|Byogy’s four-step process for the conversion of ethanol to renewable jet fuel. Click to enlarge.|
Byogy Renewables and airline partner Avianca Brasil (earlier post) have launched an initiative to support advanced testing to accelerate the approval by ASTM of Byogy’s alcohol-to-jet (ATJ) fuel. (Earlier post.) The Avianca/Byogy Team will perform advanced Flight Testing using the CFM-56 powered A319 to acquire test data and support an Environmental Impact Study to drive ASTM adoption of Byogy’s ATJ fuel.
Byogy’s proprietary ATJ process converts ethanol to a full replacement renewable jet fuel that does not require blending, and also demonstrates performance characteristics better than jet fuel produced from oil. Byogy’s jet fuel is not an additive, but instead, a full replacement standalone fuel, and hence can be used at any blend ratio up to 100%, the company says.
Navy researchers produce high-performance renewable fuels by combining heterogeneous catalysis with biosynthesis
April 18, 2014
A team from the Naval Air Warfare Center, Weapons Division (NAWCWD) at China Lake, with colleagues from the National Institute of Standards and Technology (NIST), have demonstrated that renewable high density fuels with net heats of combustion ranging from ~133,000 to 141,000 Btu gal-1—up to 13% higher than commercial jet fuel (~125,000 Btu)—can be generated by combining heterogeneous catalysis with multicyclic sesquiterpenes produced by engineered organisms. A paper on their work is published in the RSC journal Physical Chemistry Chemical Physics.
This advance has the potential to produce a range of higher-density biofuels to improve the range of aircraft, ships, and ground vehicles without altering engine configurations, they suggested.
BA and Solena Fuels to build GreenSky landfill-waste-to-jet-fuel plant in Thurrock; completion in 2017
April 16, 2014
British Airways and its partner Solena Fuels announced that the UK GreenSky facility to convert landfill waste into jet fuel (earlier post) will be built in Thames Enterprise Park, part of the site of the former Coryton oil refinery in Thurrock, Essex. The site has excellent transport links and existing fuel storage facilities. One thousand construction workers will be hired to build the facility which is due to be completed in 2017, creating up to 150 permanent jobs.
The plant will convert approximately 575,000 tonnes of post-recycled waste, normally destined for landfill or incineration into 120,000 tonnes of clean burning liquid fuels using Solena’s Integrated Biomass-Gas to Liquid (IBGTL) technology. British Airways has committed to purchasing, at market competitive prices, the jet fuel produced by the plant for the next 11 years which equates to about $550 million at today’s prices. It is also providing construction capital and becoming a minority share holder in GreenSky.
DOE issues draft loan solicitation for up to $4B for renewable energy and energy efficiency projects; drop-in biofuels a key area
The US Department of Energy (DOE) issued a draft loan guarantee solicitation for renewable energy and energy efficiency projects located in the US that avoid, reduce, or sequester greenhouse gases. The Renewable Energy and Efficient Energy Projects Loan Guarantee solicitation is intended to support technologies that will have a catalytic effect on commercial deployment of future projects, are replicable, and are market ready.
When finalized, the solicitation is expected to make as much as $4 billion in loan guarantees available to help commercialize technologies that may be unable to obtain full commercial financing.
DOE announces $10M for upgrading technologies for production of renewable drop-in fuels
The US Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) announced up to $10 million in funding to advance the development, improvement and demonstration of integrated biological or chemical upgrading technology for the production of substitutes for petroleum‐based feedstocks, products and fuels. (DE-FOA-0001085).
The DOE’s Bioenergy Technologies Office (BETO) has funded research on biochemical conversion processes since 2007, with particular focus on the development of improved cellulases and fermentative organisms for ethanol production from cellulosic feedstocks. EERE is seeking to diversify the BETO portfolio to include a variety of chemical and biological upgrading technologies for the production of a suite of hydrocarbon fuels, fuel intermediates and chemicals (beyond ethanol) to be produced in an integrated fashion from biologically or chemically derived intermediate feed streams, such as but not limited to cellulosic sugars, lignocellulose derivatives, lignin, cellulosic alcohols, bio‐solids and biogases.
ARB posts 5 new LCFS pathways; two renewable diesel
April 15, 2014
California Air Resources Board (ARB) staff has posted five new and one revised Low Carbon Fuel Standard (LCFS) fuel pathway applications to the LCFS public comment website. The new pathways include two renewable diesel pathways; two biodiesel pathways, and one corn ethanol pathway. The revised package is for corn oil biodiesel.
The renewable diesel proposals both come from Diamond Green Diesel (DGD) in Louisiana, using used cooking oil (UCO) as a feedstock; the proposals differ in the mode of shipment to California: one by rail, one by ship.
Navy researchers test direct sugar-to-hydrocarbon fuel (farnesene) in multiple engines
April 09, 2014
A team from the US Naval Academy and the US Navy have tested a Direct Sugar to Hydrocarbon (DSH) biosynthetic fuel in multiple diesel engines. Their results, reported in a paper presented at the SAE World Congress in Detroit, show that DSH meets all three of their proposed combustion acceptance metrics.
Further, they determined that a 50/50 blend of DSH and F76 (the Navy standard distillate primary fuel for propulsion and power generation) is fit for use in compression ignition engines and an acceptable candidate blend to continue with full-scale diesel engine qualification testing.
US Navy demos recovery of CO2 and production of H2 from seawater, with conversion to liquid fuel; “Fuel from Seawater”
April 08, 2014
Researchers at the US Naval Research Laboratory (NRL), Materials Science and Technology Division have demonstrated novel NRL technologies developed for the recovery of CO2 and hydrogen from seawater and their subsequent conversion to liquid fuels. Flying a radio-controlled replica of the historic WWII P-51 Mustang red-tail aircraft (of the legendary Tuskegee Airmen), NRL researchers Dr. Jeffrey Baldwin, Dr. Dennis Hardy, Dr. Heather Willauer, and Dr. David Drab used a novel liquid hydrocarbon fuel to power the aircraft’s unmodified two-stroke internal combustion engine.
The test provides a proof-of-concept for an NRL-developed process to extract CO2 and produce hydrogen gas from seawater, subsequently catalytically converting the CO2 and H2 into fuel by a gas-to-liquids process. The potential longer term payoff for the Navy is the ability to produce fuel at or near the point of use when it is needed, thereby reducing the logistics tail on fuel delivery, enhancing combat capabilities, and providing greater energy security by fixing fuel cost and its availability.