[Due to the increasing size of the archives, each topic page now contains only the prior 365 days of content. Access to older stories is now solely through the Monthly Archive pages or the site search function.]
Vertimass licenses ORNL ethanol-to-hydrocarbon conversion technology; overcoming the blend wall with drop-in fuels
March 07, 2014
Vertimass LLC, a California-based start-up company, has licensed an Oak Ridge National Laboratory (ORNL) technology that directly converts ethanol under moderate conditions at one atmosphere without the use of hydrogen into a hydrocarbon blend-stock for use in transportation fuels.
The technology developed by ORNL’s Chaitanya Narula, Brian Davison and Associate Laboratory Director Martin Keller uses an inexpensive zeolite catalyst to transform ethanol into a blend-stock consisting of a mixture of C3 – C16 hydrocarbons containing paraffin, iso-parrafins, olefins, and aromatic compounds with a calculated motor octane number of 95. Fractional collection of the fuel product allows for the different fractions to be used as blend-stock for gasoline, diesel, or jet fuel.
Fleet testing shows UPM renewable diesel from wood biomass performs as well as petroleum diesel
March 03, 2014
The first fleet tests of UPM’s BioVerno renewable diesel have shown that the fuel works in cars just as well as any conventional petroleum diesel. The fleet tests, conducted by the VTT Technical Research Center of Finland, were started in May last year and ran until early 2014. (Earlier post.)
The UPM BioVerno diesel fleet tests focused on investigating UPM’s renewable diesel in terms of fuel functionality in engine and fuel consumption. The tests were conducted with a fuel blend including 20% UPM BioVerno and 80% fossil diesel. With this blend fuel consumption matched the consumption of fossil diesel.
Neste Oil and DONG Energy partner on renewable diesel and jet fuels from ag residues via microbial oil
February 28, 2014
Neste Oil, the world’s largest producer of premium-quality renewable fuels, is working with DONG Energy, one of the leading energy groups in Northern Europe, to develop an integrated process to produce renewable diesel and aviation fuel derived from agricultural residues.
DONG Energy’s Inbicon technology will be used in the first part of the process to pre-treat biomass and produce cellulosic sugars that can then be converted into microbial oil with Neste Oil’s technology (earlier post). Microbial oil can be used as a feedstock for Neste’s NExBTL process for premium-quality renewable fuels such as renewable diesel and renewable aviation fuel.
DOE to issue funding opportunity for bioenergy technologies; outliers to current multi-year program plan
February 13, 2014
The US Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) intends to issue, on behalf of the Bioenergy Technologies Office (BETO), a Funding Opportunity Announcement (DE-FOA-0000974) entitled “Bioenergy Technologies Incubator”.
BETO’s mission is to engage in R&D and demonstration at increasing scale activities to transform renewable biomass resources into commercially viable, high-performance biofuels, and bioproducts and biopower that enable biofuel production. To accomplish this mission, BETO develops a multi-year program plan (MYPP) to identify the technical challenges and barriers that need to be overcome. These technical challenges and barriers form the basis for BETO to issue funding opportunities announcements (FOAs) for financial assistance awards in these specific areas.
Navigant Research forecasts 58% growth in global biofuels consumption by 2022; biodiesel and drop-in fuels gain market share
February 05, 2014
In a new report, “Biofuels for Transportation Markets”, Navigant Research forecasts that global demand for biofuels in the road transportation sector will grow from representing almost 6% of the liquid fuels market in 2013 to roughly 8% by 2022. Of that 8%, 8% will consist of advanced drop-in fuels, according to the research firm. Navigant forecasts that global biofuels consumption in the road transportation sector will grow from more than 32.4 billion gallons per year (BGPY) in 2013 to more than 51.1 BGPY in 2022—an increase of 58%.
Overall, Navigant forecasts that global retail sales of all liquid fuels for the road transportation sector will grow from more than $2.6 trillion in 2013 to more than $4.5 trillion in 2022 (73% growth).
DOE to award up to $12M for technologies to produce renewable carbon fiber from biomass
February 04, 2014
The US Department of Energy (DOE) will award (DE-FOA-0000996) up to $12 million in funding to advance the development of a cost-competitive pathway to produce high-performance carbon fiber for vehicle lightweighting from renewable non-food biomass. Reducing a vehicle’s weight by just 10% can improve fuel economy by 6% to 8%.
Carbon fiber composites are lightweight, yet strong, materials that can greatly improve vehicle fuel efficiency when incorporated into structural and non-structural components. Carbon fibers are polymers that are typically made from petroleum and natural gas feedstocks (propylene and ammonia, respectively) that react to form acrylonitrile (ACN) which is then polymerized and spun into polyacrylonitrile (PAN).
UC Davis process produces gasoline-range hydrocarbons from biomass-derived levulinic acid; field-to-tank yield of >60% claimed
|GC-MS chromatogram of the liquid products obtained after hydrodeoxygenation of angelica lactone dimer. Source: Mascal et al. SI. Click to enlarge.|
Researchers at the University of California, Davis have developed a process for the production of branched C7–C10 hydrocarbons in the gasoline volatility range from biomass-derived levulinic acid with good yield, operating under relatively mild conditions, with short reaction times.
Considering that levulinic acid is available with more than 80% conversion from raw biomass, a field-to-tank yield of drop-in, cellulosic gasoline of more than 60% is possible, the researchers claimed. A paper on their work is published in the journal Angewandte Chemie International Edition; UC Davis has filed provisional patents on the process, and is making it available for licensing.
AVA Biochem begins commercial-scale production of 5-HMF from biomass using HTC
February 03, 2014
AVA Biochem in Muttenz (Switzerland) has begun commercial-scale production of 5-(hydroxymethyl)furfural (5-MHF) from biomass at its Biochem-1 facility using a modified version of a hydrothermal carbonization (HTC) process developed by the Karlsruhe Institute of Technology (KIT). 5-HMF is a platform chemical that can serve as a precursor for various fuels and plastics. (Earlier post.)
In the first phase, AVA Biochem will produce up to 20 tonnes of biomass-derived 5-HMF per year. Various levels of purity—up to 99.9%—are now available for delivery.
Boeing, UAE partners make progress with oilseed halophytes as feedstock for renewable jet fuel; desert plants fed by seawater
January 23, 2014
Boeing and research partners in the United Arab Emirates have made breakthroughs in sustainable aviation biofuel development, finding that desert plants fed by seawater (the oilseed-producing halophyte Salicornia bigelovii) can produce biofuel more efficiently than other well-known feedstocks. (Earlier post.) The Sustainable Bioenergy Research Consortium (SBRC), affiliated with the Masdar Institute of Science and Technology in Abu Dhabi, will test these findings in a project that could support biofuel crop production in arid countries, such as the UAE.
S. bigelovii is a leafless, C3, succulent annual salt marsh plant that produces an oilseed on seawater irrigation in coastal desert environments; the oil from the seeds is suitable for biofuel production. Yields on seawater are similar to conventional oilseeds under ideal conditions. SBRC research also found that the entire shrublike plant (i.e., its lignocellulosic biomass as well as the the oil) can be turned into biofuel effectively.
Global Bioenergies to collaborate with Audi on development of drop-in bio-isooctane
January 21, 2014
Global Bioenergies (GBE), a leading developer of one-step fermentation processes for the direct and cost-efficient transformation of renewable resources into light olefins (earlier post), has signed a collaboration agreement with Audi on the development of bio-isooctane—a high-performance drop-in biofuel for gasoline engines—derived from bio-isobutene. In 2011, GBE had announced an agreement “with a major German car manufacturer” regarding an undisclosed application of GEB’s technology. (Earlier post.)
Under the agreement, GBE will supply Audi with isooctane derived from isobutene produced at its new pre-commercial pilot system at the Fraunhofer CBP in Leuna. (Earlier post.) During the two-year collaboration, this agreement also foresees the possibility for Audi to acquire shares of Global Bioenergies corresponding to less than 2% of its capital.
California Energy Commission to award up to $24M for new biofuel projects
January 17, 2014
The California Energy Commission announced the availability of up to $24 million in grant funds for the development of new, or the modification of existing, California-based biofuel production facilities that can sustainably produce low-carbon transportation fuels. (PON-13-609) Eligible biofuels are diesel substitutes, gasoline substitutes, and biomethane as defined in the solicitation.
The allocation of funds by fuel category is: Diesel Substitutes – $9.0 million; Gasoline Substitutes – $9.0 million; and Biomethane – $6.0 million. The Energy Commission will conduct two rounds of scoring. The first round of scoring will fund at least $4.027 million in passing projects; remaining funds will be applied to the second round of scoring.
UW-Madison team develops high-yield non-enzymatic process for production of sugars from biomass using GVL
Researchers at the University of Wisconsin-Madison, led by Dr. James Dumesic, have developed a process for for the non-enzymatic production of sugars from biomass using γ-valerolactone (GVL) itself derived from biomass. A paper on their work, which was funded by the National Science Foundation and the US Department of Energy’s Great Lakes Bioenergy Research Center (GLBRC), is published in the journal Science.
Using a solvent mixture of biomass-derived GVL, water, and dilute acid (0.05 weight percent H2SO4), they produced soluble carbohydrates from corn stover, hardwood, and softwood at high yields (70 to 90%) at laboratory scale. The sugars can then be chemically or biologically upgraded into biofuels. With support from the Wisconsin Alumni Research Foundation (WARF), the team will begin scaling up the process later this year.
DEINOVE produces ethanol at 9% titer with its optimized Deinococcus bacteria
January 16, 2014
DEINOVE, a technology company that designs, develops and markets a new generation of industrial processes based on optimized Deinococci bacteria, has produced ethanol at a titer of 9% via its fermentation of biomass sugars in 20L pre-industrial fermentors. In September 2012, the company had reported that its optimized strain of Deinococcus generated ethanol from wheat-based biomass with a titer of 3%. (Earlier post.)
The 9% content v/v (volume/volume)—equal to 7.2% wt/v (weight/volume)—exceeds the 5% alcohol content wt/v considered to be the threshold for industrial exploitation of a process for 2nd generation biofuels, the company said. The obtained performance is gradually approaching the maximum theoretical yield, the company added. The use of Deinoccoccus offers several benefits:
Study cautions on sole focus on energy crop biomass yield; perennial grasslands deliver greater ecosystems services than corn
January 14, 2014
A study by a team from the DOE’s Great Lakes Bioenergy Center has concluded that focusing on the yield of an energy crop alone can come at the expense of many other environmental benefits. The study, published as an open access paper in the Proceedings of the National Academy of Sciences (PNAS), found that switchgrass and prairie plantings harbored significantly greater plant, methanotrophic bacteria, arthropod, and bird diversity than corn.
Although the corn biomass yield was higher, all other ecosystem services, including methane consumption, pest suppression, pollination, and conservation of grassland birds, were higher in perennial grasslands.
KiOR halts cellulosic fuels production at Columbus in Q1 to optimize production; need for R&D to boost yield and cut costs
January 13, 2014
In a conference call on Friday, KiOR President and CEO Fred Cannon said that the company will halt production of cellulosic gasoline, diesel and fuel oil at its plant in Columbus, Mississippi in order to implement a number of optimization projects it identified as necessary—based on its experience in 2013—to optimize production to enhance yield, throughput and operability and to minimize cost.
In December 2013, Cannon had said that KiOR would operate the Columbus plant “on a limited campaign basis only” to verify the impact of improvements. (Earlier post.) In the Friday call, he said that the company would only operate the Columbus facility during Q1 “only to the extent we want to test and prove optimization projects.” The current execution plan for 2014 is to focus exclusively on bringing the plant to its nameplate basis, and further to develop yield and process efficiency through R&D.
NREL/UGA study finds microbial enzyme digests cellulose ~2x fast as current leading commercial cellulase; implications for biofuels cost
January 04, 2014
Researchers at the Energy Department’s National Renewable Energy Laboratory (NREL) and the University of Georgia have discovered that an enzyme from a microorganism first found in the Valley of Geysers on the Kamchatka Peninsula in Russia in 1990 can digest cellulose almost twice as fast as Cel7A, the current leading component cellulase enzyme on the market.
The high-performance enzyme CelA was discovered 15 years ago, but until this recent work, all that was known about this complex protein was its general architecture and that it had the ability to degrade cellulose. If it continues to perform well in larger tests, it could help drive down the price of making lignocellulosic fuels, from ethanol to other biofuels that can be dropped into existing infrastructure. A paper reporting this finding appears in the journal Science.
ARPA-E piloting crowdsourced energy challenge in biofuels
January 02, 2014
The US Department of Energy’s (DOE’s) Advanced Research Projects Agency - Energy (ARPA-E) is piloting a crowdsourced energy challenge, focused on ARPA-E’s PETRO (Plants Engineered To Replace Oil) program, which aims to increase the viability of biofuels by investing in research to double the energy-capture-per-unit area from that of corn ethanol. (Earlier post.)
The challenge asks “solvers” to present a detailed description and scientific rationale for a simple, rapid, and minimally invasive method to determine the energy content of plant material. Winners could receive up to $30,000.
MSU-Ford team evaluates 12 biofuel compounds for effects on cold flow properties of diesel and jet blends
|Cloud point temperatures of a high aromatic diesel (HAD) in mixtures with various biofuel compounds. Lown et al. Click to enlarge.|
Researchers from Michigan State University and Ford Motor Company's Research and Advanced Engineering Group recently tested 12 potential biofuel compounds containing oxygen in different functional groups in mixtures with three diesel fuels and one jet fuel to determine the effects of the functional groups on low-temperature fuel properties.
Groups evaluated included diesters, esters, ketones and ethers; alkanes were used for comparison. Fuels included a standard #2 US diesel (USD); a European standard diesel (ESD); and a high aromatic diesel (HAD), as well as JP-8 donated by the US Air Force.
Field trials with genetically modified poplars shows potential for efficient conversion to sugars but with impact on biomass yield
December 31, 2013
|Ethanol yield (g/L) for the Belgian and French field trials. Van Acker et al. Click to enlarge.|
The results of field trials with genetically modified poplar trees in Belgium and France shows that the wood of the modified poplar trees—down-regulated for cinnamoyl-CoA reductase (CCR), an enzyme in the lignin biosynthetic pathway—improved saccharification yield—i.e., it can be more efficiently converted into sugars for producing bio-based products such as bio-plastics and bio-ethanol.
However, the study, published as an open access paper in Proceedings of the National Academy of Sciences (PNAS), also found that strong down-regulation of CCR also affected biomass yield. The team, from Belgium, France and the US, led by researchers from VIB and Ghent University, concluded that CCR down-regulation may become a successful strategy to improve biomass processing if the yield penalty can be overcome.
KiOR expects to produce 920K gallons of cellulosic biofuels by year end; short-term focus on economics
December 24, 2013
Cellulosic gasoline and diesel company KiOR, Inc. expects that, given current and anticipated operations through the remainder of the year, its Columbus, Mississippi facility will produce approximately 410,000 gallons of renewable fuel during the fourth quarter of 2013, bringing full year production total from the facility to approximately 920,000 gallons. (Earlier post.) The ratio between gasoline, diesel and fuel oil expected to be produced during the year is approximately 35% gasoline, 40% diesel, and 25% fuel oil.
In August, the US Environmental Protection Agency (EPA) finalized the 2013 percentage standards for four fuel categories that are part of the Renewable Fuel Standard (RFS) program. With the final 2013 overall volumes and standards requiring 16.55 billion gallons of renewable fuels to be blended into the US fuel supply (a 9.74% blend), EPA projected 6 million gallons (0.004%) of cellulosic biofuels. Of that, EPA projected the bulk to come from the KiOR Columbus plant (5-6 million gallons of renewable gasoline and diesel).
ICCT suggests minor changes to Fed tax policy to cut higher investment risk of 2nd-gen biofuels and advance the industry
December 22, 2013
Minor changes to an existing Federal tax incentive for second-generation biofuels (i.e., biofuel made from cellulose, algae, duckweed, or cyanobacteria) could mitigate the current elevated risk of investing in the industry that is retarding its advance, according to a new paper by a team from the International Council on Clean Transportation (ICCT) and Johns Hopkins University. Some of the ICCT recommendations are mirrored in the recently released Baucus draft proposal for tax reform (earlier post), notes Dr. Chris Malins of the ICCT, one of the study’s co-authors.
Previous studies have attempted to explain the slow commercialization of cellulosic and algal biofuels qualitatively, however few have presented financial analysis across the sector, the authors observe. Using publicly available financial data, they applied investment analysis tools (the capital assets pricing model, CAPM) that are generally not applied to this space in order to develop a more rigorous understanding of the investment risk in the industry.
Ford brings cellulose fiber reinforced thermoplastic to 2014 Lincoln MKX
December 20, 2013
|Early version of CRP-based armrest piece under development. Source: Weyerhaeuser. Click to enlarge.|
A three-year collaboration between Lincoln, Weyerhaeuser and auto parts supplier Johnson Controls has resulted in the creation of a tree-based, renewable alternative to fiberglass for use in auto parts. (Earlier post.) The 2014 Lincoln MKX features the use of Cellulose Reinforced Polypropylene (called “THRIVE” composites by Weyerhaeuser) in the floor console armrest substrate—a structural piece located within the center console armrest.
Pieces made from CRP are roughly 6% lighter, and decrease the reliance on less-environmentally friendly fiberglass parts. The use of Cellulose Reinforced Polypropylene in the MKX, while relatively small, marks an advancement that has the potential to play a more impactful role in the future, suggested Dr. Ellen Lee, plastics research technical expert for Ford Motor Company. Ford engineers are using the company’s development and deployment of soy-based foam as an model—i.e., starting out small, then improving the material and widening the application.
BASF to partner with Renmatix for the production of industrial sugars from biomass; bio-based precursors for chemicals and fuels
December 18, 2013
BASF and US-based supercritical hydrolysis company Renmatix Inc. signed a non-exclusive joint development agreement to scale up the Renmatix Plantrose process for the production of industrial sugars based on lignocellulosic biomass. The parties have also agreed to key financial terms for future commercial licenses, which BASF can exercise at its discretion. The collaboration follows BASF’s $30 million investment in Renmatix in January 2012. (Earlier post.)
The Plantrose technology developed by Renmatix enables industrial sugar to be produced, at competitive costs, from a variety of non-edible biomass (lignocellulose) sources. The proprietary process breaks down lignocellulosic sources (e.g. wood, agricultural-residues or straw) into industrial sugars using supercritical water (water at high temperature and pressure).
USDA and DOE award $8.1M to 7 biomass genomics research projects for biofuel and bioenergy
December 12, 2013
The Department of Energy’s Office of Science, Office of Biological and Environmental Research (DOE-BER), and the US Department of Agriculture National Institute of Food and Agriculture’s Agriculture and Food Research Initiative (USDA-NIFA) are jointly awarding $8.1 million in research grants to 7 projects using genomics to develop non-food feedstocks that can be used for bioenergy. The awards continue a commitment by the two agencies begun in 2006 to conduct fundamental research in biomass genomics that will establish a scientific foundation to facilitate and accelerate the use of woody plant tissue for bioenergy and biofuel. (Earlier post.)
In 2013, DOE will provide $6.1 million in funding over 3 years, while USDA will award $2 million over 3 years. Overall, the USDA and DOE projects are designed to improve biomass—including selected trees and grasses—to be grown for biofuels by increasing their yield, quality and ability to adapt to extreme environments. Researchers will rely on the most advanced techniques of modern genomics to develop breeding and other strategies to improve the crops. The research will be conducted on switchgrass, poplar and pine, among other plants.
Amyris and Total form joint venture to produce and market renewable diesel and jet fuel
December 05, 2013
Amyris, Inc. and Total have formed Total Amyris BioSolutions B.V., a 50-50 joint venture that now holds exclusive rights and a license under Amyris’s intellectual property to produce and market renewable diesel and jet fuel from Amyris’s renewable farnesene. (Earlier post.) Total is Amyris’ largest investor, holding approximately 18% of its outstanding common stock, and is committed to the development of next-generation renewable fuels from biomass.
Amyris’ synthetic biology platform enables the modification of the genetic pathways of microorganisms, primarily yeast, to turn them into living factories to produce target molecules via fermentation. The primary biological pathway within the microbe Amyris currently uses to produce target molecules is the isoprenoid pathway.
EPA proposes reduction in cellulosic biofuel and total renewable fuel standards for 2014
November 15, 2013
The US Environmental Protection Agency (EPA) is proposing a reduction in the cellulosic biofuel and total renewable fuel standards (RFS) for 2014. Once the proposal is published in the Federal Register, it will be open to a 60-day public comment period.
Specifically, EPA is proposing a total renewable fuel target of 15.21 billion gallons; the final 2013 overall volumes and standards require 16.55 billion gallons; the original target as specified in the Clean Air Act is 18.15 billion gallons. (Earlier post.) EPA is setting the troublesome cellulosic biofuel target at 17 million gallons—significantly lower than the Clean Air Act (CAA) target of 1.75 billion gallons—but an increase from the 6.0 million gallons specified for 2013. This reflects EPA’s current estimate of the amount of cellulosic biofuel that will actually be produced in 2014, but EPA will consider public comments before setting the final cellulosic standard.
Axens, IFPEN and Michelin launch research partnership on synthetic rubber production channel using biomass; €52M over 8 years
November 11, 2013
|Overview of BioButterfly process steps. Click to enlarge.|
Axens, IFP Energies nouvelles (IFPEN) and Michelin have launched a plant chemistry research partnership that aims to develop and bring to market a process for producing bio-sourced butadiene, or bio-butadiene. Butadiene is a chemical intermediate derived from fossil resources that is used in the production of synthetic rubber. Some 60% of global output is for the tire industry.
In response to the need to find sustainable alternative sourcing channels for elastomers, the BioButterfly process will make it possible to produce innovative, more environmentally-friendly synthetic rubber. The bio-butadiene produced will support continued innovation in procuring high performance rubber for tires.
Battelle evaluating pilot-scale mobile catalytic pyrolysis unit to convert biomass to bio-oil
November 08, 2013
Battelle researchers have developed a mobile catalytic pyrolysis unit that converts biomass materials such as wood chips or agricultural waste into bio-oil. As currently configured, the Battelle-funded unit converts one ton of pine chips, shavings and sawdust into as much as 130 gallons of wet bio-oil per day.
The bio-oil then can be upgraded by hydrotreatment into a gas/diesel blend or jet fuel. Conversion of the bio-oil to an advanced biofuel is a key element of Battelle’s (earlier post)—and many others’—research. Testing of the bio-based gasoline alternative produced by Battelle suggests that it can be blended with existing gasoline and can help fuel producers meet their renewable fuel requirements.
GE Aviation signs 10-year supply agreement for biomass FT jet fuel for engine testing; baseline of 500,000 gallons per year
November 07, 2013
|Schematic of the DG Energy facility that will produce the cellulosic synthetic jet fuel. Click to enlarge.|
GE Aviation, which consumes more than 10 million gallons of jet fuel annually at its engine testing centers, has signed an agreement to purchase cellulosic synthetic biofuel from The D’Arcinoff Group (DG), based in Washington, DC, to be used for production and development testing of GE jet engines, starting in 2016.
The 10-year agreement calls for GE’s baseline commitment of 500,000 gallons annually of the low-emissions jet fuel to be used at the company’s main jet engine testing facility in Peebles, Ohio. Options are in place to order up to 10 million gallons annually of the synthetic biofuel, which be be produced via the gasification of biomass to produce syngas, followed by Fischer-Tropsch conversion.
USDA awards nearly $10M for research on using beetle-killed trees as feedstock for on-site thermochemical conversion technologies
November 06, 2013
The US Department of Agriculture (USDA) awarded nearly $10 million to a consortium of academic, industry and government organizations led by Colorado State University (CSU) and their partners to research using insect-killed trees in the Rockies as a sustainable feedstock for bioenergy. Specifically, the team will explore recent advances in scalable thermochemical conversion technologies, which enable the production of advanced liquid biofuel and co-products on-site.
There are many benefits to using beetle-killed wood for renewable fuel production. It requires no cultivation, circumvents food-versus-fuel concerns and likely has a highly favorable carbon balance. However, there are some challenges that have been a barrier to its widespread use. The wood is typically located far from urban industrial centers, often in relatively inaccessible areas with challenging topography, which increases harvest and transportation costs. In addition to technical barriers, environmental impacts, social issues and local policy constraints to using beetle-killed wood and other forest residues remain largely unexplored.
PNNL team devises probe enabling rapid design of enzyme cocktails for maximum biomass deconstruction for biofuels
November 04, 2013
A team at Pacific Northwest National Laboratory (PNNL) has devised an activity-based probe that can rapidly identify optimal conditions for the maximum enzymatic deconstruction of lignocellulose. The probe approach promises to facilitate the rapid production of enzyme cocktails for high-efficiency lignocellulose deconstruction to support high-yield biofuel production, the researchers report in a paper in the RSC journal Molecular BioSystems.
The findings open the possibility that laboratory research that now takes months could be reduced to days, and that scientists will be able to assess more options for biofuel development than is possible today.
DOE BETO issues request for information on advanced biofuel, bioproducts and biopower validation and deployment
October 31, 2013
The Department of Energy’s Office of Energy Efficiency and Renewable Energy (EERE) Bioenergy Technologies Office (BETO) is soliciting feedback from industry, academia, research laboratories, government agencies, and other stakeholders on issues related to advanced biofuel, bioproducts, and biopower technology validation and potential deployment strategies. (DE-FOA-0001013)
BETO’s mission is to develop and transform biomass resources into commercially viable, high performance biofuels, bioproducts, and biopower through targeted research, development, demonstration, and deployment supported through public and private partnerships. Specific goals are: 1) through R&D, make cellulosic biofuels competitive with petroleum-based fuels at a modeled cost for mature technology of $3 per gallon of gasoline equivalent (GGE) ($2011) based on EIA projected wholesale prices in 2017; and 2) help create an environment conducive to maximizing the production and use of biofuels by 2022.
Brookhaven researchers identify key genes for significantly increasing oil content in plant leaves
October 21, 2013
Scientists at the US Department of Energy’s Brookhaven National Laboratory have identified two key genes required for oil production and accumulation in plant leaves and other vegetative plant tissues.
In separate papers published in the journals The Plant Journal and The Plant Cell, they report that overexpression of these genes resulted in significantly increased oil content in leaves, the most abundant sources of plant biomass. In one test plant, they achieved almost twice the oil yield by weight that can be obtained from canola seeds. The finding that could have important implications for increasing the energy content of plant-based foods and renewable biofuel feedstocks.
USDA announces availability of $181M to support development of advanced biofuels projects
US Department of Agriculture Secretary Tom Vilsack announced the availability of $181 million via its Biorefinery Assistance Program to develop commercial-scale biorefineries or retrofit existing facilities with appropriate technology to develop advanced biofuels.
The Biorefinery Assistance Program was created through the 2008 Farm Bill and is administered by USDA Rural Development. It provides loan guarantees to viable commercial-scale facilities to develop new and emerging technologies for advanced biofuels. Eligible entities include Indian tribes, State or local governments, corporations, farmer co-ops, agricultural producer associations, higher education institutions, rural electric co-ops, public power entities or consortiums of any of the above.
Univ. of Illinois team argues that renewable fuel standard needs to be modified, not repealed
October 16, 2013
A policy analysis by two University of Illinois researchers argues that Congress should minimally modify, not repeal, the Renewable Fuel Standard (RFS). In the study, law professor Jay P. Kesan and Timothy A. Slating, a regulatory associate with the Energy Biosciences Institute, argue that RFS mandates ought to be adjusted to reflect current and predicted biofuel commercialization realities; that its biofuel categories be expanded to encompass all emerging biofuel technologies; and that its biomass sourcing constraints be relaxed.
In the paper, to be published in the NYU Environmental Law Journal, Kesan and Slating contend that the RFS can serve as a “model policy instrument” for the federal support of all types of socially beneficial renewable energy technologies.
UCLA engineers develop new metabolic pathway for more efficient conversion of glucose into biofuels; possible 50% increase in biorefinery yield
October 01, 2013
Researchers at UCLA led by Dr. James Liao have created a new synthetic metabolic pathway for breaking down glucose that could lead to a 50% increase in the production of biofuels. The new pathway is intended to replace the natural metabolic pathway known as glycolysis, a series of chemical reactions that nearly all organisms use to convert sugars into the molecular precursors that cells need. The research is published in the journal Nature.
Native glycolytic pathways—a number of which have been discovered—oxidize the six-carbon sugar glucose into pyruvate and thence into two-carbon molecules known acetyl-CoA for either further oxidation or biosynthesis of cell constituents and products, including fatty acids, amino acids, isoprenoids and alcohols. However, the two remaining glucose carbons are lost as carbon dioxide.
KIT’s fast biomass pyrolysis to liquids bioliq plant produces first gasoline
September 30, 2013
|The multi-stage bioliq process produces high-quality synthetic fuels from straw and other biogenous residues. Graphic: N. Dahmen, KIT/IKFT. Click to enlarge.|
The synthesis stage of Karlsruhe Institute of Technology’s (KIT’s) multi-stage bioliq pilot plant has begun operation and has produced biogasoline. All stages of the bioliq process—flash pyrolysis, high-pressure entrained-flow gasification, and now synthesis—have now been realized and the project will now be completed by testing the entire process chain and optimizing it for the large industrial scale.
As soon as all stages of the bioliq process will have been linked, the pilot plant will supply high-quality fuel from straw, probably in mid-2014. The complete bioliq process (Biomass to Liquid Karlsruhe) comprises four stages (earlier post):
KAIST team engineers novel pathway for direct production of biogasoline by E. coli bacteria
A team at the Korea Advanced Institute of Science and Technology (KAIST) has developed a a novel strategy for microbial gasoline production through the metabolic engineering of Escherichia coli. The team engineered engineered platform E. coli strains that are capable of producing short-chain alkanes (SCAs; i.e., gasoline); free fatty acids (FFAs); fatty esters; and fatty alcohols via the fatty acyl (acyl carrier protein (ACP)) to fatty acid to fatty acyl-CoA pathway.
As reported in their paper in Nature, the final engineered strain produced up to 580.8 mg per liter of SCAs consisting of nonane (327.8 mg l−1), dodecane (136.5 mg l−1), tridecane (64.8 mg l−1), 2-methyl-dodecane (42.8 mg l−1) and tetradecane (8.9 mg l−1), together with small amounts of other hydrocarbons.
KiOR seeks to double cellulosic fuels production at Columbus plant; $50M in from Khosla for Columbus II
September 26, 2013
Cellulosic gasoline and diesel company KiOR, Inc. is pursuing plans to double production capacity at its Columbus, Mississippi, facility through construction of a second facility incorporating KiOR’s commercially proven technology. KiOR estimates that the Columbus II project will cost approximately $225 million; will break ground within 90 days of it raising sufficient equity and debt capital to commence the project; and will take approximately 18 months to construct and start up.
Once completed with its latest technology improvements, KiOR expects that the Columbus II project will allow each Columbus facility to achieve greater yields, production capacity and feedstock flexibility than the original design basis for the existing Columbus facility, enabling KiOR to more quickly make progress towards its long-term goal of 92 gallons per bone dry ton of biomass.
U-Mich researcher’s first-principles analysis challenges conventional carbon accounting for biofuels; implications for climate policy
September 24, 2013
In a paper that could have a significant impact on climate policies for transportation fuels, Dr. John M. DeCicco of the Energy Institute at the University of Michigan, Ann Arbor presents a rigorous first-principles analysis that undermines the common “biofuels recycle carbon” argument.
Published in the journal Climactic Change, the open access paper shows that while the carbon mitigation challenge for liquid fuels has been seen—incorrectly—as a fuel synthesis and substitution problem, it is in reality a net carbon uptake problem. Accordingly, DeCicco concludes, strategies should move away from a downstream focus on replacing fuel products to an upstream focus on achieving additional CO2 uptake through the most cost-effective and least damaging means possible. “All parties with an interest in the issue are advised to rethink their priorities accordingly,” he finishes.
Novozymes and Raízen to collaborate on cellulosic ethanol in Brazil
September 18, 2013
Novozymes has entered into a collaboration agreement with Brazil’s largest sugarcane crusher, Raízen Energia S/A (the $12-billion joint venture between Shell and Cosan founded in 2011). (Earlier post.) As part of the agreement, Novozymes will supply enzyme technology to Raízen’s first commercial-scale cellulosic ethanol plant in Brazil, scheduled to be operational by end 2014.
The plant will be a bolt-on facility to Raízen’s Costa Pinto sugarcane mill in the state of São Paulo and will have the capacity to produce 40 million liters (10.5 million gallons US) of cellulosic ethanol a year from sugarcane bagasse and straw. The agreement also provides for Novozymes to supply enzyme technology to Raízen’s second cellulosic ethanol plant, should such a plant be constructed.
New route for upgrading bio-oil to biogasoline via molecular distillation and catalytic cracking
|Bio-oil-graded upgrading route based on molecular distillation and catalytic cracking. Credit: ACS, Wang et al. Click to enlarge.|
A team at Zhejiang University, China, has developed a novel cracking technology for the upgrading of bio-oil, produced by the fast pyrolysis of biomass, to biogasoline. In a paper published in the ACS journal Energy & Fuels, they report that the co-cracking of the distilled fraction (DF) from bio-oil molecular distillation and ethanol produced a well-defined gasoline phase, and that both increasing the reaction temperature and adopting pressurized cracking benefited the yield and quality of this gasoline phase.
Under optimum reaction temperature and pressure, co-cracking of the DF and ethanol, with different weight ratios, all generated high-quality gasoline phases. Under 400 °C and 2 MPa, co-cracking of DF and ethanol with a weight ratio of 2:3 produced a high gasoline phase yield of 25.9 wt %; the hydrocarbon content in this gasoline phase was 98.3%. CO2, CO, and C3H8 (propane) were the main gaseous products, and a low coke yield of 3.2 wt % was achieved.
European Parliament backs 6% cap on land-based biofuels, switchover to advanced biofuels; no mandate
September 11, 2013
In a vote on draft legislation, the European Parliament has backed a cap on the use of biofuels produced from starch-rich crops, sugars, oil and other crops grown on land and a speedy switchover to new biofuels from alternative sources such as seaweed and waste. The measures aim to reduce greenhouse gas emissions that result from the turnover of agricultural land to biofuel production.
According to current legislation, member states must ensure that renewable energy accounts for at least 10% of energy consumption in transport by 2020. In the adopted text, MEPs (Members of the European Parliament) say land-based biofuels should not exceed 6% of the final energy consumption in transport by 2020. (The proposal by the European Commission on which the draft legislation was based had suggested an even lower 5% cap.)
Neste Oil and Raisioagro to research the potential of straw as a renewable diesel feedstock via microbial oil
September 02, 2013
Neste Oil, developer of the NExBTL process for renewable diesel, and agritrader Raisioagro have launched a research project to investigate the potential of straw as a raw material for producing NExBTL renewable diesel via Neste’s microbial oil technology. (Earlier post.)
Large quantities of waste straw are produced as agricultural residue in Finland and elsewhere, and only a small proportion of this is currently used. The project will study whether a logistically effective and efficient, large-scale straw harvesting chain could be created in Finland. The researchers will also look at the storability of straw for use as an industrial input year-round. The project will be carried out by TTS, a research, development, and training organization.
New synthetic fungal-bacterial consortia for direct production of isobutanol from biomass
August 20, 2013
A team from the University of Michigan, Michigan State, and UCLA has designed synthetic fungal-bacterial consortia for the direct production of isobutanol from biomass. The required biological functions are divided between two specialists: the fungus Trichoderma reesei, which secretes cellulase enzymes to hydrolyze lignocellulosic biomass into soluble saccharides, and the bacterium Escherichia coli, which metabolizes soluble saccharides into the desired products.
In experiments reported in an open access paper published in the Proceedings of the National Academies (PNAS), they achieved isobutanol titers up to 1.88 g/L and yields up to 62% of theoretical maximum from the direct conversion of microcrystalline cellulose and pretreated corn stover to isobutanol.
NextFuels introduces hydrothermal process to produce biofuels from wet, unprocessed waste; solution for palm plantation residue
August 19, 2013
|Overview of the NextFuels’ GreenCrude process. Click to enlarge.|
Biofuels company NextFuels introduced its hydrothermal process for economically producing transportation and industrial fuels from wet, unprocessed agricultural waste. The underlying technology—developed by Shell Oil over several years—will allow NextFuels and its partners to produce bio-based crude at commercial scale for $75 to $85 a barrel out of wet biomass that has not been mechanically or thermally dried.
The California-based company said that its process will provide palm plantation owners and others a way to transform the tons of residual plant matter generated by agricultural operations into a new, profitable second crop.
JBEI team develops one-pot, wash-free process for pretreatment and saccharification of switchgrass; avenues for driving down biofuel cost
August 14, 2013
|Conventional separate pretreatment and saccharification of biofuel feedstock (a) entails water and waste disposal that the new one-pot system (b) eliminates. (Image courtesy of Joint BioEnergy Institute). Click to enlarge.|
Researchers with the US Department of Energy (DOE)’s Joint BioEnergy Institute (JBEI) report the first demonstration of a one-pot, wash-free process that combines ionic liquid (IL) pretreatment and enzymatic saccharification into a single vessel using a thermostable IL-tolerant bacterial consortium comprising several species of thermophiles (microbes that thrive at extremely high temperatures and alkaline conditions).
Using this one-pot system, they liberated 81.2% glucose and 87.4% xylose (monomers and oligomers) at 72 h processing at 70 °C with an enzyme loading of 5.75 mg g−1 of biomass at 10% [C2mim][OAc]. Glucose and xylose were selectively separated by liquid–liquid extraction with over 90% efficiency, thus eliminating extensive water washing as a unit operation.
EPA sets 2013 percentages for Renewable Fuel Standard; anticipating adjustments to 2014 volume requirements
August 06, 2013
The US Environmental Protection Agency (EPA) finalized the 2013 percentage standards for four fuel categories that are part of the Renewable Fuel Standard (RFS) program. The final 2013 overall volumes and standards require 16.55 billion gallons of renewable fuels to be blended into the US fuel supply (a 9.74% blend).
The 2013 standard specifically requires: biomass-based diesel (1.28 billion gallons; 1.13%); advanced biofuels (2.75 billion gallons; 1.62%); and cellulosic biofuels (6.00 million gallons; 0.004%). These standards reflect EPA’s updated production projections. All volumes are ethanol-equivalent, except for biomass-based diesel which is actual volume.
DOE awarding $22 million for algal fuel and biomass feedstock supply chain projects
August 01, 2013
US Energy Secretary Ernest Moniz announced more than $22 million in new investments to help develop cost-competitive algae fuels and streamline the biomass feedstock supply chain for advanced biofuels. Moniz was speaking at the US Department of Energy’s (DOE’s) Biomass 2013 conference.
Nearly $16.5 million goes to four projects intended to boost the productivity of sustainable algae, while cutting capital and operating costs of commercial-scale production. The projects include:
Study identifies functional roles of individuals within microbial consortium for breaking down switchgrass for biofuel production
July 28, 2013
Working with a compost-derived consortium of thermophillic bacterium adapted to grow on switchgrass, and using a combination of metagenomic and metaproteomic technologies, a collaboration led by researchers with the US Department of Energy’s (DOE’s) Joint BioEnergy Institute (JBEI) has identified individual microbial species whose enzymes were the most active in deconstructing the switchgrass biomass.
The study marks the first time that the functional roles of individual microbial populations within a consortium have been linked with specific enzyme activities—in this case cellulase and hemicellulase—said Steven Singer, director of JBEI’s microbial communities program. “Since these activities are broadly relevant to biofuel production, this is one of the first real-world applications being met by combining metagenomics and metaproteomics,” Singer said.
EIA: world energy consumption to grow 56% 2010-2040, CO2 up 46%; use of liquid fuels in transportation up 38%
July 25, 2013
|World energy consumption by fuel type, 2010-2040. Source: IEO2013. Click to enlarge.|
The US Energy Information Administration’s (EIA’s) International Energy Outlook 2013 (IEO2013) projects that world energy consumption will grow by 56% between 2010 and 2040, from 524 quadrillion British thermal units (Btu) to 820 quadrillion Btu. Most of this growth will come from non-OECD (non-Organization for Economic Cooperation and Development) countries, where demand is driven by strong population and economic growth; energy intensity improvements moderate this trend
Renewable energy and nuclear power are the world’s fastest-growing energy sources, each increasing 2.5% per year, according to the biennial report. However, fossil fuels continue to supply nearly 80% of world energy use through 2040. Natural gas is the fastest-growing fossil fuel, as global supplies of tight gas, shale gas, and coalbed methane increase. Given current policies and regulations limiting fossil fuel use, worldwide energy-related CO2 emissions rise from about 31 billion metric tons in 2010 to 36 billion metric tons in 2020 and then to 45 billion metric tons in 2040, a 46% increase over the 30-year span.
VTT study concludes gasification-based pathways can deliver low-carbon fuels from biomass for about 1.90-2.65 US$/gallon
July 04, 2013
A study by researchers at Finland’s VTT has concluded that it is possible to produce sustainable low-carbon fuels from lignocellulosic biomass for as estimated gasoline-equivalent production cost of 0.5–0.7 €/liter (app. 1.90-2.65 US$/gallon US), with first-law process efficiency in the range of 49.6–66.7%—depending on the end-product and process conditions. Should the thermal energy produced as a by-product be exploited for district heat or industrial steam, the overall efficiency from biomass to salable energy products could reach 74–80%.
In their study, Ilkka Hannula & Esa Kurkela evaluated 20 individual biomass-to-liquids BTL plant designs based on their technical and economic performance. The investigation was focused on gasification-based processes that enable the conversion of biomass to methanol, dimethyl ether, Fischer-Tropsch liquids or synthetic gasoline at a large (300 MWth of biomass) scale.
DOE to award up to $13M to four advanced biofuels projects
July 01, 2013
The US Department of Energy (DOE) has selected four research and development projects designed to bring next-generation biofuels on line faster and to drive down the cost of producing gasoline, diesel, and jet fuels from biomass. The projects represent up to a combined $13-million Energy Department investment.
In the United States, the transportation sector accounts for two-thirds of total US oil consumption and about one-third of total anthropogenic greenhouse gas emissions. Hydrocarbon-based biofuels made from non-food feedstocks, waste materials, and algae can directly replace gasoline and other fuels. DOE is continuing to pursue the development of these renewable biofuels, with the goal of producing cost-competitive drop-in biofuels at $3 per gallon by 2017.
MIT team develops lower cost method to synthesize gamma-valerolactone for biofuels and chemicals
June 17, 2013
MIT chemical engineers have devised a cheaper way to synthesize gamma-valerolactone (GVL)—a potential feedstock of interest in the production of both fuels and fine chemicals—from biomass. (Earlier post.) GVL has more energy than ethanol and could be used on its own or as an additive or precursor to other fuels. GVL could also be useful as a “green” solvent or a building block for creating renewable polymers from sustainable materials.
The traditional process for converting plant material to GVL requires catalysts made from precious metals and must be done at very high pressures of hydrogen gas, which makes the process cost-prohibitive. The new MIT production method, described in the June 11 issue of the journal Angewandte Chemie, eliminates both of those obstacles.
Technip awarded €5M FEED contract for Ajos BtL biomass-to-liquids plant in Finland
June 14, 2013
|Forest BTL process. Click to enlarge.|
Forest BtL Oy, owned by Vapo, A Finnish bioenergy, peat and sawmill company, awarded Technip a contract, worth approximately €5 million, for the front-end engineering and design (FEED) of a new biomass-to-liquid (BTL) plant to be built on Ajos island, Finland.
This plant will produce approximately 140,000 tons of biodiesel and naphtha from wood and by-products from the wood-processing industry. This feedstock has many advantages as it is not used for human food, it does not jeopardize the existing local biomass usage and has a low CO2 footprint.
USDA announces up to $98.6M to support production of advanced biofuels
June 12, 2013
The US Department of Agriculture USDA announced the availability of up to $98.6 million to support the production of advanced biofuels, and an opportunity for eligible producers to submit applications. Of the $98.6 million, $68.6 million will be available for Fiscal Year 2013 production and the remainder of approximately $30 million is for payments for production in prior fiscal years.
The payments are provided through USDA Rural Development’s Bioenergy Program for Advanced Biofuels, commonly referred to as the Advanced Biofuel Payment Program. It was established in the 2008 Farm Bill to support the expansion of advanced biofuel production. Payments are made to eligible producers based on the amount of biofuel produced from renewable biomass, other than corn kernel starch.
CCST report: an integral role for next-gen biofuels in meeting California GHG targets requires advanced biofuels and demand reduction
June 11, 2013
Next-generation biofuels can reduce greenhouse gas emissions of transportation to meet California’s target greenhouse gas (GHG) reduction goal, but deep replacement of fossil fuels through implementation of low-carbon lignocellulosic ethanol and advanced biomass derived hydrocarbons (drop-in biofuels) and reduction in demand is required, according to a new report from the California Council on Science and Technology (CCST).
The study, “California Energy Future: the Potential for Biofuels,” co-authored by Energy Biosciences Institute (EBI) scientists Heather Youngs and Chris Somerville, is the seventh and final report in its California’s Energy Future (CEF) project. The CEF project seeks ways the State could meet the mandated reductions of greenhouse gas (GHG) emissions to 80% below 1990 levels by 2050, exploring possible energy strategies for California through in-depth examinations of different technology scenarios.
US Senate passes Farm Bill with more than $800M in mandatory funding for bioenergy programs
The United States Senate passed a five-year farm bill—the Agriculture Reform, Food, and Jobs Act of 2013 (S.954)—containing more than $800 million in mandatory funding for energy programs. The bill also contains funding to grow the renewable chemicals industry.
The Congressional Budget Office CBO estimates that direct spending stemming from the program authorization under the 12 titles in S. 954 would total $955 billion over the 2014-2023 period. That 10-year total reflects the bill’s authorization of expiring programs through 2018 and an extension of those authorizations through 2023. The energy title (Title IX) of the bill contains:
NREL, Navy and Cobalt Technologies to make jet fuel from switchgrass via butanol intermediate; cellulosic alcohol-to-jet
June 07, 2013
|Overview of the Cobalt/Navy pathway for converting butanol to renewable jet fuel (alcohol-to-jet, ATJ). Source: Dr. Michael Wright, NAVAIR. Click to enlarge.|
The US Department of Energy’s (DOE’s) National Renewable Energy Laboratory (NREL) is partnering with Cobalt Technologies, US Navy, and Show Me Energy Cooperative to demonstrate that jet fuel can be made economically and in large quantities from a renewable biomass feedstock such as switchgrass using an alcohol-to-jet pathway.
The project, which will convert biomass into sugars for fermentation into butanol with subsequent conversion of that intermediate into JP5 jet fuel, is one of four biorefinery projects funded recently by the DOE. (Earlier post.) The process is expected to result in up to a 95% reduction in greenhouse gas emissions compared to the current production of jet fuel.
UK-US team characterizes key enzyme from wood-eating gribble; potential for high-solids biomass conversion
June 04, 2013
|Limnoria—the wood-eating gribble. Credit: Laura Michie, Portsmouth University, with assistance from Alex Ball from the Natural History Museum. Click to enlarge.|
Using advanced biochemical analysis and X-ray imaging techniques, researchers from the University of York, University of Portsmouth and the National Renewable Energy Laboratory in the USA have determined the structure and function of a key enzyme used by the gribble (earlier post) to break down wood.
The gribble (Limnoria quadripunctata), a marine wood-borer with efficient gut enzymes for breaking down woody material, is the focus of one of the research hubs in the UK’s Bioenergy Center, established in 2009. The findings, published in Proceedings of the National Academies (PNAS), will help the researchers to reproduce the enzymes effects on an industrial scale in a bid to create sustainable liquid biofuels.
Converting wastepaper to biocrude and hydrogen
May 12, 2013
|Biocrude compounds, product gas and reaction pathways from APR of wastepaper at 250 °C in presence of 5 wt % Ni(NO3)2 catalyst. Credit: ACS, Tungal and Shende. Click to enlarge.|
A pair of researchers at the South Dakota School of Mines & Technology have demonstrated homogeneously catalyzed subcritical aqueous phase reforming (APR) of wastepaper to produce biocrude and hydrogen. A paper on their work is published in the ACS journal Energy & Fuels.
Wastepaper can be a combination of newspaper—a lignocellulosic biomass containing cellulose (62%), hemicellulose (16%), and lignin (16%)—and used office printing papers which consist of mainly cellulose (85−99%) and negligible (0.4%) lignin. Using a homogeneous Ni(NO3)2 catalyst, they produced about 44 wt % biocrude from wastepaper slurry at 250 °C after 120 minutes of reaction time. The biocrude contained ∼1 wt % HMF/furfural, 7.5 wt % sugars, 49.1 wt % acids, and 42.4 wt % oxygenated hydrocarbons.
New ionic liquid biomass pretreatment method eliminates need for enzymes, reduces water use
May 09, 2013
|The new ionic liquid pretreatment of cellulosic biomass yields a biphasic solution, a lower phase rich in sugar and an upper phases rich in ionic liquid. (Courtesy of Simmons/JBEI) Click to enlarge.|
Researchers at the US Department of Energy (DOE)’s Joint BioEnergy Institute (JBEI) have developed a new technique for pre-treating cellulosic biomass with ionic liquids that could reduce the cost of producing advanced biofuels from plant sugars.
This new technique requires none of the expensive enzymes used in previous ionic liquid pretreatments, and yields a biphasic solution—a lower phase rich in sugar and an upper phases rich in ionic liquid—making it easier to recover fuel sugars and recycle the ionic liquid. An open access paper describing this research has been published in the journal Biotechnology for Biofuels.
Study finds large-scale ramp-up in biofuel crops could result in warming in some tropical regions, cooling in temperate and polar regions
May 08, 2013
Global land-use changes caused by a major ramp-up in biofuel crops—enough to meet about 10% of the world’s energy needs—could make some regions warmer, according to a new integrated modeling study by researchers from MIT and the Marine Biological Laboratory, Woods Hole.
Using an integrated assessment model that links an economic model with climate, terrestrial biogeochemistry, and biogeophysics models, the team examined the biogeochemical and biogeophysical effects of possible land use changes from an expanded global second-generation bioenergy program on surface temperatures over the first half of the 21st century.
U. Minn. team proposes strategy for automated selection of optimal biomass-derived fuel blends and synthesis paths
May 07, 2013
|Proposed strategy for connecting automated network generation and optimization. Credit: ACS, Marvin et al. Click to enlarge.|
Researchers at the University of Minnesota are proposing a novel strategy that simultaneously identifies (a) the most desirable biomass-derived chemical products for an application of interest, such as fuels, and (b) the corresponding synthesis routes.
In a paper published in the ACS journal Energy & Fuels, they describe the strategy, and then apply it to identify potential renewable oxygenates and hydrocarbons obtained from heterogeneous catalysis of biomass that can be blended with gasoline to satisfy ASTM specifications.
UPM and VTT begin fleet tests of BioVerno wood-based renewable diesel in Golf 1.6 TDIs
April 29, 2013
Finland-based forestry-industry company UPM, VTT and VV-Auto Group will start fleet tests of renewable diesel produced mainly from crude tall oil, which is a residue of chemical pulp production, UPM BioVerno. (Earlier post.) The biofuel will be produced by UPM, fleet tests will be coordinated by VTT, and cars will be supplied by VV-Auto Group, an importer and marketer of Volkswagen Group cars in Finland. Fleet tests with UPM BioVerno will start in May, lasting several months.
UPM BioVerno diesel has previously been studied in engine and vehicle tests conducted by VTT and others. The fleet tests will focus on investigating UPM renewable diesel in terms of fuel functionality in engine, emissions and fuel consumption.
DOE seeks input on environmental impact of engineered high energy crops for fuels
April 14, 2013
The US Department of Energy (DOE) has issued a Request for Information (DE-FOA-0000908, RFI-0000003) regarding the potential environmental impacts of engineered high energy crops, such as those being investigated under the Advanced Research Projects Agency-Energy’s (ARPA-E) Plants Engineered to Replace Oil (PETRO) program (earlier post), and potential future DOE programs to support the development and demonstration of such crops through field trials.
Such crops could be the source of significant fuel resources from biological production DOE said, noting that therefore it is extremely important to understand their potential impact on the environment. DOE will consider responses to the RFI in the development of an Advance Notice of Intent (NOI) to prepare a Programmatic Environmental Impact Statement (PEIS), which would analyze the potential environmental impacts of such DOE programs.
President’s FY2014 Budget boosts DOE vehicle technology spending 75% to $575M; $282M for advanced biofuels
April 10, 2013
President Obama’s FY 2014 budget proposal submitted to Congress provides $28.4 billion in discretionary funds for the Department of Energy, an 8% increase above the 2012 enacted level. Among the direct transportation-related highlights of the department’s budget proposal are $575 million for advanced vehicle technologies research, an increase of 75% over the enacted 2012 level; $282 million for the next-generation of advanced biofuels research; and the $2 billion Energy Security Trust to transition cars and trucks off of oil. (Earlier post.)
Other highlights include more than $5 billion (+5.7% over the 2012 enacted level) for the Office of Science for basic research and research infrastructure; $615 million to increase the use and decrease the costs of clean power from solar, wind, geothermal, and water energy; $365 million in advanced manufacturing research and development; and $147 million in research and development of smart grid investments, cybersecurity for energy control systems, and permitting, sitting, and analysis activities.
EBEI researchers shed light on how multiple cellulase enzymes attack cellulose; potential avenue to boosting sugar yields for biofuels
April 08, 2013
|PALM enables researchers to quantify how and where enzymes are binding to the surface of cellulose in heterogeneous surfaces, such as those in plant cell walls. Source: Berkeley Lab. Click to enlarge.|
Researchers with the Energy Biosciences Institute, University of California, Berkeley have provided insight into how multiple cellulase enzymes attack cellulose, potentially yielding a way to improve the collective catalytic activity of enzyme cocktails that can boost the yields of sugars for making fuels.
Increasing the sugar yields from cellulosic biomass to help bring down biofuel production costs is essential for the widespread commercial adoption of these fuels. A paper on their work is published in Nature Chemical Biology.
NSF to award up to $13M for fundamental work on sustainable production of electricity and transportation fuels
April 07, 2013
The US National Science Foundation (NSF) has issued a grants opportunity notice (PD-14-7644) for up to about $13 million in awards to fundamental research and education that will enable innovative processes for the sustainable production of electricity and transportation fuels. Processes for sustainable energy production must be environmentally benign, reduce greenhouse gas production, and utilize renewable resources.
The duration of unsolicited awards is typically three years. The average annual award size for the program is $100,000. Proposals requesting a substantially higher amount than this, without prior consultation with the Program Director, may be returned without review. Current interest areas in sustainable energy technologies are as follows:
Task 39 report finds significant advances in advanced biofuels technologies; hydrotreating accounting for about 2.4% of global biofuels production
April 06, 2013
|Capacities of the demonstration and commercial facilities sorted by technology. Source: “Status of Advanced Biofuels Demonstration Facilities in 2012”. Click to enlarge.|
Advanced biofuels technologies have developed significantly over the past several years, according to a status report on demonstration facilities prepared for IEA Bioenergy Task 39—a group of international experts working on commercializing sustainable biofuels used for transportation that is part of the International Energy Agency’s (IEA) implementation agreement for bioenergy, IEA Bioenergy.
Hydrotreatment—as exemplified by Neste Oil’s NExBTL—has been commercialized and currently accounts for approximately 2.4% of biofuels production worldwide (2,190,000 t/y), according to the report. Fermentation of lignocellulosic raw material to ethanol has also seen a strong development and several large scale facilities are just coming online in Europe and North America. The production capacity for biofuels from lignocellulosic feedstock has tripled since 2010 and currently accounts for some 140,000 tons per year.
Virginia Tech team develops process for high-yield production of hydrogen from xylose under mild conditions
April 03, 2013
|Flow of the new process; enzymes are in red. Credit: Martín del Campo et al. Click to enlarge.|
A team of Virginia Tech researchers, led by Dr. Y.H. Percival Zhang, has developed a process to convert xylose—the second-most abundant sugar in plants—into hydrogen with approaching 100% of the theoretical yield. The findings of their study, published in the journal Angewandte Chemie, International Edition, suggest that cell-free biosystems could produce hydrogen from biomass xylose at low cost.
In the process, hydrogen is produced from xylose and water in one reactor containing 13 enzymes, including a novel polyphosphate xylulokinase (XK). The method can be performed using any source of biomass.
Joint BioEnergy Institute researchers engineer plant cell walls to boost sugar yields and reduce cell wall recalcitrance for biofuels
April 01, 2013
|Genetically engineered Arabidopsis plants (#89) yielded as much biomass as wild types (WT) but with enhanced polysaccharide deposition in the fibers of their cell walls. (Image courtesy of JBEI.) Click to enlarge.|
Researchers at the US Department of Energy’s (DOE’s) Joint BioEnergy Institute (JBEI) have developed a new approach to decrease lignin content in biomass while preventing vessel collapse and have devised a new strategy to boost transcription factor expression in native tissues. A paper describing their work recently was published in Plant Biotechnology Journal.
Abundant lignocellulosic biomass could potentially supply the sugars needed to produce advanced biofuels that can supplement or replace fossil fuels, providing several key technical challenges are met. One of these challenges is finding ways to more cost-effectively extract those sugars.
Converting the acetone-butanol-ethanol mixture to drop-in hydrocarbons
Researchers at Auburn University report on the catalytic dehydration of the acetone-butanol-ethanol (ABE) mixture produced by fermentation by genetically modified Clostridium acetobutylicum. Their paper appears in the ACS journal Energy & Fuels.
C. acetobutylicum produces a mixture of acetone, butanol and ethanol via fermentation. While the catalytic dehydration of the individual components—n-butanol, acetone, and ethanol—has been studied, not much work has been reported on the dehydration or deoxygenation of the mixture as produced from the ABE fermentation process, Shaima Nahreen and Ram Gupta note in their paper.
Navigant forecasts global 6% CAGR for biofuels to 2023
March 29, 2013
|Total Biofuels production by fuel type, world markets: 2013-2023. Source: Navigant. Click to enlarge.|
Navigant Research forecasts global biofuels production will grow at a compound annual growth rate (CAGR) of 6% between 2013 and 2023, despite slower than expected development of advanced biofuels pathways (such as cellulosic biofuels); an expected expansion in unconventional oil production in key markets such as the United States; and a decline in global investment for biofuels in recent years.
In contrast, Navigant expects the CAGR for fossil-based gasoline, diesel, and jet fuel to be 3.1% over the forecast period. The research firm projects that total biofuels production will reach 62 billion gallons by 2023 or 5.9% of global transportation fuel production from fossil sources.
Primus Green Energy to support gas-to-liquids research at Princeton University; comparing STG+ to other GTL platforms
March 28, 2013
|Schematic diagram of the Primus STG+ process. Click to enlarge.|
Primus Green Energy Inc., developer of a proprietary process to produce gasoline and other fuels from biomass and/or natural gas (earlier post), will provide financial support to engineers at Princeton University for general research on synthetic fuels, which will include assessments of various gas-to-liquids (GTL) technologies—including Primus’ own STG+—for sustainability and economic viability.
STG+ technology converts syngas into drop-in high-octane gasoline and jet fuel with a conversion efficiency of ~35% by mass of syngas into liquid transportation fuels (the highest documented conversion efficiency in the industry) or greater than 70% by mass of natural gas. The fuels produced from the Primus STG+ technology are very low in sulfur and benzene compared to fuels produced from petroleum, and they can be used directly in vehicle engines as a component of standard fuel formulas and transported via the existing fuel delivery infrastructure.
JBEI team develops new one-pot process to extract biomass sugars from ionic liquid solutions
March 21, 2013
|Process of biomass pretreatment, acid hydrolysis and sugar extraction using alkaline solutions. Sun et al. Click to enlarge.|
A team from the Joint BioEnergy Institute (JBEI), Lawrence Berkeley National Laboratory has developed a novel one-pot process to extract sugars liberated from biomass in aqueous ionic liquid (IL) solutions. The new approach, described in an open access paper in the journal Biotechnology for Biofuels, potentially could significantly reduce costs of sugar production from lignocellulose by eliminating the need for costly enzymes and decreasing the water consumption requirements.
Many recent research and development efforts for cellulosic biofuels have explored a two-step bioconversion process involving: 1) liberation of fermentable sugars from lignocellulose; and 2) conversion of sugars into fuels and/or chemicals by fermentation. However, easily liberating the sugars and other monomers from cellulosic biomass for conversion is one of the major challenges to the cost-effectiveness of cellulosic pathways.
Mærsk Group exploring use of lignin-based marine biofuels; CyclOx and B21st
March 20, 2013
With an annual fuel bill of US$7 billion for vessel operations, the Mærsk Group continually considers ways to reduce its bunker fuel consumption. Greater efficiency is the primary way of achieving this; alternative fuels are another. Mærsk Group is currently involved in two projects focused on realizing the marine fuel potential of one of the world’s most abundant and sustainable biomass resources: lignin.
Lignin already has a variety of industrial uses because of its chemical characteristics, energy content and its abundance; yet its potential as a marine diesel fuel is a relatively uncharted area, says Peter Normark Sørensen, with Mærsk Oil Trading, the Mærsk Group’s oil buying arm.
DOE TEF project finds US can eliminate petroleum and reduce GHG by more than 80% in transportation by 2050; less use, more biofuels, expansion of electricity and hydrogen
March 15, 2013
|TEF project points to deep cuts in petroleum and emissions in the transportation sector by focusing on modes, fuels, and demand. Source: DOE. Click to enlarge.|
The US Department of Energy (DOE) released findings from a new project—Transportation Energy Futures (TEF)—that concludes the United States has the potential to eliminate petroleum use and greenhouse gas (GHG) emissions by more than 80% in the transportation sector by 2050. The project identifies possible paths to a low-carbon, low-petroleum future in the US transportation sector, and also looks beyond technology to examine the marketplace, consumer behavior, industry capabilities, and infrastructure.
TEF is organized into four research areas: light-duty vehicles; non-light-duty vehicles; fuels; and transportation demand. Findings are being detailed in a series of nine reports, six of which are now available.
SRI wins $925,000 DOE award to liquefy biomass for production of transportation fuels
March 13, 2013
Southern Research Institute (SRI) entered into a cooperative agreement with the US Department of Energy (DOE) to develop a mild liquefaction process that will economically convert biomass to petroleum refinery-ready bio-oils. The process will convert biomass to stabilized bio-oils that can be directly blended with hydrotreater and cracker input streams in a petroleum refinery for production of gasoline and diesel range hydrocarbons.
Dr. Santosh Gangwal, Southern Research principal investigator, said co-processing of bio-oil with petroleum refinery streams can help refineries comply with new renewable fuels standards (RFS-2.) The process will be evaluated and optimized using a continuous flow lab-scale biomass liquefaction system simulating the commercial embodiment of Southern Research’s liquefaction process. Also a lab-scale reactor will be constructed and tested for hydrotreating and cracking the bio-oils to produce gasoline and diesel range hydrocarbons.
ZeaChem begins production of cellulosic chemicals and ethanol, advances toward commercialization
March 12, 2013
|Zeachem’s C2 platform uses an acetogenic organism to ferment sugars to acetic acid, which is converted to ethanol. Source: Zeachem. Click to enlarge.|
ZeaChem Inc. has produced commercial-grade cellulosic chemicals and ethanol at its 250,000 gallons per year (GPY) demonstration biorefinery in Boardman, Ore. The demonstration facility is intended to showcase the scalability of ZeaChem’s biorefining process and serve as a stepping-stone toward large-scale commercial production.
Similar to a petrochemical refinery that makes multiple fuels and chemicals, ZeaChem’s demonstration facility is employing its C2 (two-carbon) platform to produce cellulose-based ethanol and intermediate chemicals such as acetic acid and ethyl acetate. (Earlier post.) The commercial market potential for all C2 products is $485 billion.
Codexis introduces next-generation Codexyme cellulase enzymes with improved performance for reduced costs
|Codexis has delivered significant improvements in enzyme performance (left) and enzyme manufacturing cost (right). Source: Codexis. Click to enlarge.|
Codexis, Inc., a developer of engineered enzymes for pharmaceutical, biofuel and chemical production, launched CodeXyme 4 and CodeXyme 4X cellulase enzyme packages for use in producing cellulosic sugar for production of biofuels and bio-based chemicals.
Codexis’ latest generation of advanced cellulase enzymes, CodeXyme 4 for dilute acid pretreatments and CodeXyme 4X for hydrothermal pretreatments, converts up to 85% of available fermentable sugars at high biomass and low enzyme loads. Combined with high strain productivity using the CodeXporter enzyme production system, this allows for a cost-in-use that the company believes will be among the lowest available once in full-scale commercial production.
Petrobras joining DIBANET biofuels consortium; diesel miscible biofuels from biomass
|DIBANET aimes to advance the art in several key areas in diesel miscible diesel production. Source: DIBANET. Click to enlarge.|
Petrobras is joining the DIBANET (Development of Integrated Biomass Approaches Network) consortium—a 45-month, €3.73-million (US$4.9-million) research project that is funded by the EU’s Seventh Framework Program. (Earlier post.) DIBANET is coordinated by the Carbolea Research Group at the University of Limerick in Ireland.
DIBANET focuses on the conversion, by non-biological means, of the lignocellulosic biomass residues and wastes of Europe and Latin America to platform chemicals, such as levulinic acid and furfural, and biofuels. More specifically, DIBANET is advancing the art in the production of ethyl-levulinate from organic wastes and residues. Ethyl levulinate (EL) is a novel diesel miscible biofuel (DMB) produced by esterifying ethanol with levulinic acid.
China-US team concludes duckweed biorefineries can be cost-competitive with petroleum-based processes
March 07, 2013
Researchers from the US and China have determined that a duckweed biorefinery producing a range of gasoline, diesel and kerosene products can be economically competitive with petroleum-based processes, even in some cases without environmental legislation that penalizes greenhouse gas emissions. A paper describing their analysis of four different scenarios for duckweed biorefineries is published in the ACS journal Industrial & Engineering Chemistry Research.
Duckweed, an aquatic plant that floats on or near the surface of still or slow-moving freshwater, is attractive as a raw material for biofuel production. It grows fast, thrives in wastewater that has no other use, does not impact the food supply and can be harvested more easily than algae and other aquatic plants. However, few studies have been done on the use of duckweed as a raw material for biofuel production.