[Due to the increasing size of the archives, each topic page now contains only the prior 365 days of content. Access to older stories is now solely through the Monthly Archive pages or the site search function.]
DLR, AEB developing new injection heads enabling use of ethanol as rocket fuel
February 16, 2017
The German Aerospace Center (Deutsches Zentrum für Luft- und Raumfahrt; DLR) and the Brazilian aerospace agency Agência Espacial Brasileira (AEB) have successfully completed the first burn tests for two newly designed injection heads enabling the development of a new rocket that is fueled with oxygen and alcohol.
The final injection head will eventually be the core of the new L75 liquid propellant rocket engine (LPRE), intended to propel a Brazilian small launch vehicle in the future. The engine delivers 75 kN thrust, fueled with liquid oxygen and ethanol, with a burn time of up to 400 seconds. (For comparison, Space X’s Falcon 9’s second stage—used to place large payloads into orbit—is powered by a single Merlin engine with 934 kN thrust. Falcon 9’s first stage delivers 7,607 kN at sea level.) The burn test series for the upper stage engine was completed within the framework of a German-Brazilian partnership established in 2011.
Lux Research forecasts global biofuels output to rise to 67B GPY in 2022; advanced biofuels will nearly double to 9.6B GPY
February 14, 2017
New biofuel technology is finally starting to push aside traditional biofuels such as first-generation biodiesel, according to a new report by Lux Research. New facilities based on non-food feedstocks and producing novel fuels account for over half of new capacity deployment for the first time in the biofuel industry’s history, according to Lux. However, overall output will grow at a slower pace to 67 billion gallons a year (BGY) in 2022, from 59 BGY in 2016.
The report, titled “Biofuels Outlook 2022: The Dawn of a New Era in Global Biofuel Capacity Expansion,” is part of the Lux Research Alternative Fuels Intelligence service. Lux Research analysts quantified the commercial deployment of new technologies in the global biofuels industry using a database of nearly 2,000 facilities from 1,461 companies in 90 countries with nameplate capacity data through 2022. Among their findings:
DOE to award up to $1.2M to project converting wastewater solids to biogas and liquid fuels; hydrothermal processing
February 11, 2017
Southern California Gas Co. (SoCalGas) announced a pilot hydrothermal wastewater processing project has been selected by the US Department of Energy (DOE) to receive up to $1.2 million in federal funding. SoCalGas is part of a consortium conducting the pilot, which will be required to share the cost at a minimum of 50% in order to receive federal funds. The consortium is being led by the Water Environment & Reuse Foundation (WERF).
The project will use Genifuel hydrothermal processing technology (HTP) to convert wastewater solids into renewable natural gas as well as liquid fuels. DOE funding is expected to pay for about half of the design and planning of a pilot plant to produce these renewable fuels at a municipal wastewater treatment facility near Oakland, California. SoCalGas will help oversee the project’s design and assist in obtaining state and federal regulatory approvals and incentives.
Global Bioenergies reports first production of ETBE entirely from renewable resources
February 07, 2017
Global Bioenergies announced the production of ETBE—Ethyl tert-butyl ether, an oxygenate additive for gasoline—purely from renewable resources. ETBE features very different and advantageous physical and chemical characteristics, compared to ethanol, when blended into gasoline. These include significantly lower blending volatility; no significant distortion of the distillation curve; better tolerance of wet distribution systems; double the octane increase per “barrel” at equivalent ethanol content and narrower octane sensitivity; and better material compatibility. (ETBE RON = 119, MON = 103, AKI = 111)
ETBE also provides a series of environmental benefits compared to ethanol used alone, such as lower VOCs emission, lower permeation losses in the vehicle, and additional CO2 emissions reduction due to less severe refinery operations.
Clariant, Mercedes-Benz, Haltermann Carless report successful fleet test of E20 cellulosic ethanol blend
February 06, 2017
Clariant, a leading global specialty chemicals company, together with Mercedes-Benz and Haltermann Carless, a well-established HCS Group brand, tested the use of sustainable cellulosic ethanol from agricultural residues in a fleet test with Mercedes-Benz series vehicles over a period of 12 months for the first time in Germany. sunliquid 20 was used for the test—a fuel produced by Haltermann Carless with a cellulosic ethanol content of 20 vol% (E20) from Clariant’s sunliquid plant in Straubing.
The cellulosic ethanol allows greenhouse gas emission savings of up to 95% across the entire value chain without competing with food production or tying up agricultural land.
Study suggests GTL-naphtha-gasoline-ethanol blends can function as well as gasoline with lower emissions
February 05, 2017
Results of a study by a team from the University of Birmingham (UK) and Shell Global Solutions suggest that blends of gasoline with gas-to-liquids (GTL) naphtha can perform comparable combustion and full power output to conventional gasoline, with less than 2% difference in normalized ISFC (indicated specific fuel consumption) and gaseous emissions similar to, if not lower than that of conventional gasoline. A paper on their study is published in the journal Fuel.
The GTL Fischer-Tropsch process produces GTL diesel (the cleaner combustion and emissions qualities of which have been well studied), GTL naphtha, GTL kerosene, GTL normal Paraffin and GTL base oils. GTL naphtha mainly contains C4 to C11 hydrocarbons with a high proportions of straight chain paraffins. Although it has a consistent quality and near-zero sulfur and heavy metals, GTL naphtha has a low octane rating, making it unsuitable for blending in gasoline. (GTL naphtha currently is used as an alternative high-quality feedstock for plastics.) However, that low octane rating can be addressed by using ethanol as an octane booster.
Study: splash blended ethanol fuels with higher ethanol percentage enable higher thermal efficiency in SI engine
February 03, 2017
A team from the University of Birmingham (UK) and Shell Global Solutions has investigated the effect of RON, octane sensitivity and charge cooling in splash-blended ethanol fuels with different volume percentages of ethanol on a single-cylinder direct-injection spark ignition (DISI) research engine.
In a paper published in the journal Fuel, the researchers report that at the knock-limited engine loads, splash-blended ethanol fuels with a higher ethanol percentage enabled higher engine thermal efficiency through allowing more advanced combustion phasing and less fuel enrichment for limiting the exhaust gas temperature under the upper limit of 850 °C, which was due to the synergic effects of higher RON and octane sensitivity, as well as better charge cooling.
Researchers find shade from stand density can cost farmers about 10% of potential crop yield
January 30, 2017
A team from the University of Illinois has found that compared to top leaves, the shaded lower level leaves of C4 crops planted in dense stands such as corn and Miscanthus underperform, costing farmers about 10% of potential yield.
These findings, published in an open-access paper in the Journal of Experimental Botany, could help scientists further boost the yields of corn and Miscanthus, as well as other C4 crops that have evolved to photosynthesize more efficiently than C3 plants such as wheat and rice.
Saudi Aramco R&D proposes SuperButol as new low-cost high-octane blend component
January 27, 2017
A team from Saudi Aramco Research and Development Center has developed a novel low-cost, high-octane gasoline blend component it calls SuperButol. SuperButol is made from low-value mixed butenes using a new process the team has named Butenes to Butanol (BTB); it has slightly lower blending RON compared to MTBE but has lower blending vapor pressure and higher energy content compared to ethanol.
It also has an insignificant effect on key gasoline specifications, including potential and actual gum; oxidation stability; intake valve deposits; port fuel injector fouling; haze formation; and water extractability performance. The team suggests that SuperButol is thus a viable and affordable gasoline component, which can help to meet future demands for high-octane gasoline. In addition, the process helps to optimize refinery operations by valorizing low-value products. The team describes SuperButol in a paper in the journal Fuel.
Velocys establishes strategic alliance with TRI for gasification systems for BTL plants
Velocys plc, the developer of smaller scale gas-to-liquids (GTL), signed a memorandum of understanding (MoU) with ThermoChem Recovery International, Inc. (TRI), establishing a strategic alliance. TRI—a leading provider of steam reforming gasification systems suitable for woody biomass and other waste feedstocks—will be Velocys’ preferred supplier of gasification systems for its biomass-to-liquids (BTL) plants.
The agreement will see the alliance partners rapidly deploy an integrated biorefinery offering that combines Velocys’ Fischer-Tropsch (FT) technology with TRI’s proven gasification technology.
BP Energy Outlook: 30% growth in global demand to 2035; fuel demand continues to rise, even with EVs & fuel efficiency
January 25, 2017
The 2017 edition of the BP Energy Outlook, published today, forecasts that global demand for energy will increase by around 30% between 2015 and 2035, an average growth of 1.3% per year. However, this growth in energy demand is significantly lower than the 3.4% per year rise expected in global GDP, reflecting improved energy efficiency driven by technology improvements and environmental concerns. The Outlook looks at long-term energy trends and develops projections for world energy markets over the next two decades.
While non-fossil fuels are expected to account for half of the growth in energy supplies over the next 20 years, the Outlook projects that oil and gas, together with coal, will remain the main source of energy powering the world economy, accounting for more than 75% of total energy supply in 2035, compared with 86% in 2015.
US DOD to award $55M for advanced drop-in biofuels production; 10M gallons/year
The US Air Force Research Laboratory, Materials and Manufacturing Directorate (AFRL/RX) has issued a funding opportunity (FOA-RQKM-2017-0006) for up to $55 million to design, retrofit, construct, operate, validate and qualify domestic, commercial-scale, an integrated biorefinery(s) capable of producing bio-equivalent fuels suitable for military use with a rated capacity of at least 10 million gallons of neat biofuel per year. Cost competitiveness of the neat biofuel fraction with conventional petroleum-derived fuels is a primary goal.
The biorefinery—which may be either a brownfield expansion/modification of existing facilities, or new greenfield construction—is required to use domestic feedstock, and create an Integrated Biofuels Production Enterprise (IBPE). Expansions must add an additional 10 million gpy of capacity; new construction must support the 10 million gpy capacity.
TU Bergakademie Freiberg launches OTTO-R project with VW Group, Shell, OMV as partners; P2X for green gasoline
January 24, 2017
Researchers at the Technische Universität Bergakademie Freiberg, with partners from the automotive industry (Audi, VW) and the petroleum industry (Shell, OMV) have launched the €1.46-million OTTO-R project for the production of gasoline from “green” methanol produced from CO2, water and renewable electricity.
The new OTTO-R synthesis process is based on the Syngas-To-Fuel-Process (STF) developed by Chemieanlagenbau Chemnitz GmbH (CAC) at the Institute for Energy Process Engineering and Chemical Engineering (IEC). STF first converts natural gas-based synthesis gas to methanol in an isothermal reactor; the methanol is then transformed into high-octane gasoline via the intermediate methanol. Residual methanol and light hydrocarbons are separated downstream and recycled into the process.
MIT team engineers yeast to boost lipid production for biofuels
January 20, 2017
MIT engineers have genetically engineered strains of the oleaginous yeast Yarrowia lipolytica to boost the production of lipids by about 25% compared to previously engineered yeast strains. Their approach could enable commercialization of microbial carbohydrate-based lipid production, supporting the renewable production of high-energy fuels such as diesel.
A paper on their work is published in the journal Nature Biotechnology; the MIT team, led by Gregory Stephanopoulos, the Willard Henry Dow Professor of Chemical Engineering and Biotechnology at MIT, is now working on additional improvements to the lipids yield.
DOE Co-Optima initiative publishes report reviewing first 12 months; progress on fuels and engines
January 16, 2017
The US Department of Energy’s (DOE’s) Co-Optima initiative—a broad, joint effort to co-optimize the development of efficient engines and low greenhouse-gas fuels for on-road vehicles with the goal of reducing petroleum consumption by 30% by 2030 beyond what is already targeted (earlier post)—has published a year-in-review report for FY 2016—the initiative’s first 12 months.
Co-Optima’s premise is that current fuels constrain engine design—and thus engine efficiency. The researchers suggest that there are engine architectures that can provide higher thermodynamic efficiencies than available from modern internal combustion engines; however, new fuels are required to maximize efficiency and operability across a wide speed/load range. The report details the technical progress in a selection of projects across the initiative’s two main thrusts: spark ignition (SI) and advanced compression ignition (ACI).
DOE and USDA issue notice of intent for Biomass Research and Development Initiative
January 15, 2017
The US Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy’s (EERE’s) Bioenergy Technologies Office, in coordination with the US Department of Agriculture’s (USDA's) National Institute of Food and Agriculture (NIFA), announced its intent to issue a Request for Applications (RFA) through the Biomass Research and Development Initiative. (DE-FOA-0001711)
Projects funded through this RFA, titled “Fiscal Year 17 Biomass Research and Development Initiative (BRDI),” will help develop economically and environmentally sustainable sources of renewable biomass, and increase the availability of renewable fuels and biobased products. The BRDI program requires that funded projects address at least one of the following three legislatively mandated technical areas:
BETO report identifies biofuel/bioproducts opportunities from wet and gaseous waste: ~22.2B GGE/year
January 11, 2017
The US Department of Energy’s (DOE’s) Bioenergy Technologies Office has published a report, titled Biofuels and Bioproducts from Wet and Gaseous Waste Streams: Challenges and Opportunities. The report is the first comprehensive assessment of the resource potential and technology opportunities provided by wet and gaseous feedstocks, including wastewater treatment-derived sludge and biosolids, animal manure, food waste, inedible fats and greases, biogas, and carbon dioxide streams.
These feedstocks can be converted into renewable natural gas, diesel, and aviation fuels, or into valuable bioproducts.
DOE BETO releases new strategic plan; biofuels to constitute 25% of US transportation fuels by 2040
December 31, 2016
The US Department of Energy’s Bioenergy Technologies Office (BETO) released its new strategic plan, titled Strategic Plan for a Thriving and Sustainable Bioeconomy. The strategic plan—with a vision for 2040—lays out BETO’s mission to accomplish its vision in a dynamic setting that realizes changes in the energy landscape, advances in technology, growing environmental awareness, and public expectations.
The strategic plan sets the foundation for the development of BETO’s multi-year program plans, annual operating plans, and technology program areas. It also takes a crosscutting approach to identify opportunities to adapt and align BETO activities and project portfolios with those in both the public and private sectors. The plan centers around four key opportunities: enhancing the bioenergy value proposition; mobilizing US biomass resources; cultivating end-use markets and customers; and expanding stakeholder engagement and collaboration.
DOE awards LanzaTech $4M for low-carbon jet & diesel demo plant; 3M gpy; Audi evaluating fuel properties
December 30, 2016
LanzaTech has been selected by the Department of Energy’s Bioenergy Technologies Office (BETO) to receive a $4-million award to design and plan a demonstration-scale facility using industrial off gases to produce 3 million gallons/year of low-carbon jet and diesel fuels. The LanzaTech award was one of six totaling $12.9 million. (Earlier post.)
The LanzaTech facility will recycle industrial waste gases from steel manufacturing to produce a low cost ethanol intermediate: “Lanzanol.” Both Lanzanol and cellulosic ethanol will then be converted to jet fuel via the Alcohol-to-Jet" (ATJ) process developed by LanzaTech and the Pacific Northwest National Laboratory (PNNL). (Earlier post.)
DOE awarding up to $7M to 8 universities for co-optimization of fuels and engines: Co-Optima
December 29, 2016
The US Department of Energy (DOE) will award up to $7 million to projects at eight universities to accelerate the introduction of affordable, scalable, and sustainable high-performance fuels for use in high-efficiency, low-emission engines.
Under the Co-Optimization of Fuels and Engines (Co-Optima) initiative (earlier post), DOE’s Bioenergy Technologies Office and Vehicle Technologies Office are collaborating to maximize energy savings and on-road vehicle performance, while significantly reducing transportation-related petroleum consumption and harmful emissions. The goal is to reduce petroleum consumption by 30% by 2030 beyond what is already targeted.
Researchers in China develop new process for direct synthesis of drop-in jet-fuel-range blendstock from lignocellulose
Researchers in China have developed an integrated two-bed continuous flow reactor process for the direct synthesis with high carbon yields (~70%) of dodecanol (C12H26O) or 2,4,8- trimethylnonane (C12H26O2)—a jet-fuel-range C12 branched alkane—from methyl isobutyl ketone (MIBK), which can be derived from lignocellulose.
The dodecanol as obtained can be used as the feedstocks in the production of sodium dodecylsulphate (SDS) and sodium dodecyl benzene sulfonate (SDBS)—widely used as surfactants or detergents. The 2,4,8-trimethylnonane as obtained can be blended into conventional jet fuel without hydroisomerization. A paper on their work is published in the journal ChemSusChem.
UC Irvine team discovers nitrogenase Fe protein can reduce CO2 to CO; implications for biofuel production
December 28, 2016
A team at the University of California, Irvine has discovered that the iron protein (the reductase component) of the natural enzyme nitrogenase can, independent of its natural catalytic partner, convert CO2 to carbon monoxide (CO)—a syngas used to produce useful biofuels and other chemical products.
The team, led by Professor Yilin Hu (Molecular Biology and Biochemistry), also found that they could express the reductase component alone in the soil bacterium Azotobacter vinelandii to convert CO2 in a manner more applicable to large-scale production of CO. This whole-cell system could be explored further for new ways of recycling atmospheric CO2 into biofuels and other commercial chemical products. A paper on their work is published in the journal Nature Chemical Biology.
On the road to solar fuels and chemicals
December 27, 2016
In a new paper in the journal Nature Materials (in an edition focused on materials for sustainable energy), a team from Stanford University and SLAC National Accelerator Laboratory has reviewed milestones in the progress of solid-state photoelectrocatalytic technologies toward delivering solar fuels and chemistry.
Noting the “important advances” in solar fuels research, the review team also noted that the largest scientific and technical milestones are still ahead. Following their review, they listed some of the scientific challenges they see as the most important for the coming years.
Global Bioenergies plans to acquire Dutch start-up Syngip; gaseous carbon feedstocks for renewable isobutene process
December 21, 2016
Global Bioenergies, the developer of a process to convert renewable resources into light olefin hydrocarbons via fermentation (with an initial focus on isobutene) (earlier post), signed a contribution agreement with the shareholders of Syngip B.V. to transfer all Syngip shares to Global Bioenergies S.A. Syngip is a third-generation industrial biotech start-up created in 2014 in the Netherlands that has developed a process to convert gaseous carbon sources such as CO2, CO, and industrial emissions such as syngas, into various valuable chemical compounds.
Syngip has identified a specific micro-organism capable of growing using these gaseous carbon sources as its sole feedstock, and has developed genetic tools to allow the implementation of artificial metabolic pathways into it. Its recent work has been directed to the implementation of metabolic pathways leading to light olefins: major petrochemical molecules, which include isobutene.
ARPA-E awards $35M to 16 REFUEL projects for energy-dense carbon-neutral liquid fuels; leveraging ammonia
December 17, 2016
The Energy Department’s Advanced Research Projects Agency-Energy (ARPA-E) has selected 16 projects for a combined $35 million in funding under the new program “Renewable Energy to Fuels Through Utilization of Energy-Dense Liquids (REFUEL)”. (Earlier post.) The 16 REFUEL projects seek to develop scalable technologies for converting water and molecules from the air into energy-dense, carbon-neutral liquid fuels (CNLFs) using electrical energy from renewable sources. REFUEL projects will convert low-cost renewable energy into a transportable chemical fuel and use these fuels for transportation applications, while reducing production costs and environmental impact.
Most of the selected REFUEL projects target the production of ammonia or its conversion to hydrogen or electricity, due ammonia’s attractiveness as a hydrogen and energy carrier. State-of-the-art industrial ammonia production using the Haber-Bosch process requires a hydrogen source (usually natural gas), remains highly capital and energy intensive, and is only economical at a large scale. Many projects seek to overcome these limitations to enable economically competitive, distributed production of this prototypical CNLF.
Global Bioenergies reports first production of green isobutene at demo plant
December 15, 2016
Global Bioenergies is now entering the final phase of demonstrating its technology for converting renewable carbon into hydrocarbons. The first trials on the demo plant in Leuna were successfully completed, within schedule, in the fall of 2016 and Global Bioenergies announced first production of green isobutene via fermentation. (Earlier post.)
With a nameplate capacity of 100 tons/year, the demo plant will allow the conversion of various resources (industrial-grade sugar from beets and cane, glucose syrup from cereals, second-generation sugars extracted from wheat straw, bagasse, wood chips…), into high-purity isobutene.
ITM Power to launch 100 MW electrolyzer plant designs at Hannover Messe 2017
December 13, 2016
ITM Power will showcase a series of large scale electrolyzer configurations up to 100MW in size at Hannover Messe 2017 (24 - 28 April). This is in response to utility and oil and gas industry demand for larger scale industrial installations.
ITM Power has sold a number of MW-scale plants over the last year and is now responding to enquires for much larger plant for bus and heavy goods vehicle refueling stations in the to 10MW range and, increasingly, industrial applications ranging from power-to-gas, refineries and steel-making in the 10MW to 100MW range.
LANL team develops simple catalyst system to upgrade acetone to range of chemicals and fuels
December 12, 2016
Researchers at Los Alamos National Laboratory (LANL) have developed a simple inexpensive catalyst system (Amberlyst 15 and Ni/SiO2–Al2O3) to upgrade bio-derived acetone to provide C6, C9, and C12 aliphatic ketones, along with C9, C12, and C15 aromatic compounds. Stepwise hydrodeoxygenation of the produced ketones can yield branched alcohols, alkenes, and alkanes. A paper on their work is published in the journal ChemSusChem.
Predicted and measured fuel properties of a selection of these produced molecules showed that certain compounds are candidates as drop-in fuel replacements for spark- and compression-ignition engines.
JISEA: nuclear-renewable hybrid energy systems can reduce GHG from industry, produce fuels and support the power system
December 09, 2016
Nuclear-renewable hybrid energy systems (N-R HESs) can enable low-carbon, on-demand electricity while providing reduced-emission thermal energy for industrial processes. N-R HES systems are managed by a single entity that link a nuclear reactor that generates heat, a thermal power cycle for heat-to-electricity conversion, at least one renewable energy source, and an industrial process that uses thermal and/or electrical energy.
However, the economic feasibility of these systems may depend on future natural gas prices, electricity market structures, and clean energy incentives. A series of new reports from the Joint Institute for Strategic Energy Analysis (JISEA) and Idaho National Laboratory (INL) examines various hybrid system configurations to provide a basis to identify opportunities for clean energy use and examine the most economically viable configurations.
DOE to issue funding opportunity for integrated biorefinery optimization
December 06, 2016DOE to issue funding opportunity for integrated biorefinery optimization
The US Department of Energy’s Office of Energy Efficiency and Renewable Energy (EERE) intends to issue, on behalf of the Bioenergy Technologies Office (BETO) and the US Department of Agriculture’s National Institute of Food and Agriculture, a funding opportunity announcement (DE-FOA-0001689) entitled, “Integrated Biorefinery Optimization.”
This FOA will support research and development to increase the performance efficiencies of biorefineries resulting in continuous operation and production of biofuels, bioproducts, and biopower at prices competitive with fossil-derived equivalents.
WSU Tri-Cities researchers receive $50K NSF grant to test market potential for lignin pathway for biojet
December 03, 2016
Researchers at Washington State University Tri-Cities have been awarded a $50,000 National Science Foundation I-Corps grant to explore the commercialization potential of their new pathway for biojet from biomass waste. The WSU process, described in a 2015 paper in the RSC journal Green Chemistry, uses hydrodeoxygenation (HDO) of dilute alkali extracted corn stover lignin catalyzed by a noble metal catalyst (Ru/Al2O3) and acidic zeolite (H+-Y) to produce lignin-substructure-based hydrocarbons (C7-C18), primarily C12-C18 cyclic structure hydrocarbons in the jet fuel range. (Earlier post.)
Current biorefineries undervalue lignin’s potential, largely because selective conversion of lignin has proven to be challenging. Processes that have been successful at breaking the lignin bonds have typically resulted in shorter chain monomers as opposed to the longer chain hydrocarbons needed for fuel. In contrast, the output of the WSU processis a mix of hydrocarbons that are long-chain and can be made into nearly the right mix for jet fuel.
New ORNL hardware-in-the-loop capability to integrate advanced combustion, new fuels, and electrification pathways
December 02, 2016
A multi-disciplinary team of researchers at Oak Ridge National Laboratory (ORNL) has developed a new testing capability which integrates a driver model, full vehicle model, and hardware to explore the synergies of advanced combustion, new fuels, and emerging hybrid vehicle architectures over real-world drive cycles. This new facility is focused on low temperature combustion engines but builds upon the powertrain-in-the-loop expertise established with the Vehicle Systems Integration Laboratory (VSI) at ORNL.
The transient advanced combustion laboratory is initially supporting research on the potential of low temperature combustion modes with new fuel and vehicle technologies. The hardware-in-the-loop setup includes a transient dynamometer cell (AVL 300 kW AC) with a low-temperature combustion (LTC) multi-cylinder engine instrumented for combustion and emissions analysis. The light-duty diesel engine used in these experiments (earlier post) was modified for dual-fuel use for port fuel injection of low-reactivity fuel (i.e. gasoline, ethanol etc.) and a high-reactivity fuel (i.e. diesel, biodiesel etc.).
DOE BETO to issue $8M funding opportunity for algae-based biofuels
The US Department of Energy’s Bioenergy Technologies Office (BETO) plans (DE-FOA-0001708) to issue a funding opportunity announcement (DE-FOA-0001628) for up to $8 million, subject to appropriations, for the development of algae-based biofuels.
The FOA, entitled Productivity Enhanced Algae and Tool-Kits (PEAK), will support innovative technologies and approaches to help advance bioenergy and bioproducts from algae. These projects will support the development of cost-competitive biofuels from algal biomass by focusing on breakthroughs in advanced biology, as well as biology-based tools to improve algae cultivation productivity. Selected projects will also accelerate future innovations through data sharing within the research and development community.
GAO study concludes Renewable Fuel Standard will miss advanced biofuel program targets; EPA generally concurs
November 29, 2016
A new study from the US Government Accountability Office (GAO) concludes that the Renewable Fuel Standard program will miss its advanced biofuel targets due to the the high costs of creating advanced biofuel; the relatively low price of fossil fuel; the timing and cost to bring new tech to commercial-scale production; regulatory uncertainty; and other issues as challenges to increased production.
GAO was asked by Congress to review issues related to advanced biofuels R&D. The report describes (1) how the federal government has supported advanced biofuels R&D in recent years and where its efforts have been targeted; and (2) expert views on the extent to which advanced biofuels are technologically understood and the factors that will affect the speed and volume of production. GAO interviewed DOD, DOE, EPA, NSF, and USDA officials and worked with the National Academy of Sciences to convene a meeting of experts from industry, academia, and research organizations. EPA generally agreed with the conclusions of the report, the GAO said.
Update on DOE Co-Optima project to co-optimize fuels & engines; goal of 30% per vehicle reduction in petroleum
November 28, 2016
In October 2015, the US Department of Energy’s (DOE) launched a broad, joint effort to co-optimize the development of efficient engines and low greenhouse-gas fuels for on-road vehicles with the goal of reducing petroleum consumption by 30% by 2030 beyond what is already targeted. (Earlier post.) The intended application is light-, medium-, and heavy-duty markets including hybrid architectures.
The Co-Optima project team, which is leveraging the technical contributions of nine of DOE’s 17 national laboratories, has grown to more than 130 researchers, according to Robert Wagner, Director of the Fuels, Engines, and Emissions Research Center at Oak Ridge National Laboratory (ORNL), and a member of the Co-Optima leadership team, in a briefing at the lab earlier this month. In August 2016, DOE announced funding of up to $7 million further to support the initiative.
Government of Canada to work with provinces, territories, and stakeholders to develop a clean fuel standard
November 26, 2016
The Government of Canada will consult with provinces and territories, Indigenous peoples, industries, and non-governmental organizations to develop a clean fuel standard. The standard would require reductions in the carbon footprint of the fuels supplied in Canada, based on lifecycle analysis. The overall objective of a clean fuel standard would be to achieve annual reductions of 30 megatonnes (Mt) of GHG emissions by 2030.
The approach would not differentiate between crude-oil types produced in or imported into Canada. These consultations would inform the development of a regulatory approach under the Canadian Environmental Protection Act (CEPA).
EPA finalizes increase in renewable fuel volumes for 2017; 6% total increase to 19.28B gallons
November 23, 2016
The US Environmental Protection Agency (EPA) finalized increases in renewable fuel volume requirements across all categories of biofuels under the Renewable Fuel Standard (RFS) program. In a required annual rulemaking, the action finalizes the volume requirements and associated percentage standards for cellulosic biofuel, advanced biofuel, and total renewable fuel for 2017, and for biomass-based diesel for 2018.
The final volumes represent continued growth over historic levels. The final standards meet or exceed the volume targets specified by Congress for total renewable fuel, biomass-based diesel, and advanced biofuel. Total renewable fuel volumes grow 6% (1.2 billion gallons) from 2016 to 2017 to 19.28 billion gallons.
Chevrolet and GMC expand alternative fuel fleet offerings; expanded CNG/LPG lineup
November 22, 2016
Chevrolet and GMC are partnering with Power Solutions International, Inc. (PSI) to introduce heavy-duty pickups and full-size vans powered by 6.0-liter V-8 compressed natural gas (CNG) and liquefied petroleum gas (LPG)-capable engines starting in the first quarter of 2017. Chevrolet also will offer CNG and LPG versions of its new Low Cab Forward commercial truck.
The announcement follows the selection of PSI, based in Wood Dale, Illinois, as General Motors Fleet’s preferred upfitter for CNG and LPG trucks. PSI is one of North America’s largest and most experienced providers of integrated turn-key, alternative-fuel powertrain solutions.
New pathway for producing jet fuel range alkanes from plastics
November 21, 2016
Researchers at Washington State University have developed a novel route for the production of jet fuel range alkanes at high carbon yields from plastics. The process combines catalytic microwave-assisted degradation of low-density polyethylene (a model compound of plastics waste) followed by hydrogenation.
In a paper published in the journal Fuel, the team reported that, depending on the catalyst, the overall carbon yields of organics from raw plastics were approximately 54 or 63%. The raw organics (with the higher yield) could be hydrogenated to fit JP-5 navy fuel at 200 °C, while the raw organics (with the lower yield) could be hydrogenated to match high energy-density jet fuels (e.g. RJ-5 and JP-10) under very low-severity conditions.
S. Korean researchers develop new catalytic pathway for direct conversion of CO2 to liquid hydrocarbon fuels
A team led by Professor Jae Sung Lee at Ulsan National Institute of Science and Technology (UNIST), with colleagues at Pohang University of Science and Technology (POSTECH), have developed a new pathway for the direct conversion of CO2 to liquid transportation fuels by reaction with renewable hydrogen produced by solar water splitting.
The new carbon capture and utilization (CCU) system is enabled by their discovery of a new catalyst that produces liquid hydrocarbon (C5+) selectivity of ∼65% and greatly suppresses CH4 formation to 2–3%. This selectivity is unprecedented for direct catalytic CO2 hydrogenation and is very similar to that of conventional CO-based Fischer-Tropsch (FT) synthesis, the team reports in a paper published in Applied Catalysis B: Environmental.
Gevo enters on-road automobile gasoline market in Houston with 12.5% isobutanol blend
November 12, 2016
Gevo, Inc. announced that a 12.5% blend of its bio-isobutanol with gasoline marketed for use in automobiles has begun to be sold in the Houston area. This marks the first time that Gevo’s isobutanol has been specifically targeted towards on-road vehicles. Previously, Gevo and its partners have focused on specialty markets such as marinas and off-road engines. (Earlier post.)
Musket Corporation is Gevo’s distribution partner serving the Houston market and is blending the specially formulated gasoline containing Gevo’s isobutanol to distribute into the on-road automobile market. Buc-ee’s, a 37-store regional chain of rest stops in Texas, is the first company to sell the blend, marketed as a high-performance ethanol-free gasoline.
Compact pilot plant for solar to liquid fuels production
November 09, 2016
Partners from Germany and Finland in the SOLETAIR project are building a compact pilot plant for the production of gasoline, diesel and kerosene from solar energy, regenerative hydrogen and carbon dioxide. The plant will be compact enough to fit into a shipping container.
The plant consists of three components. A direct air capture unit developed by the Technical Research Center of Finland (VTT) extracts carbon dioxide from air. An electrolysis unit developed by Lappeenranta University of Technology (LUT) produces the required hydrogen by means of solar power. A microstructured, chemical reactor—the key component of the plant—converts the hydrogen produced from solar power together with carbon dioxide into liquid fuels. This reactor was developed by KIT. The compact plant was developed to maturity and is now being commercialized by KIT spin-off INERATEC.
BP takes $30M stake in Fulcrum Bioenergy; 500M gallon renewable jet offtake agreement
November 08, 2016
Fulcrum BioEnergy and BP signed a major strategic partnership that includes a $30-million equity investment in Fulcrum by BP. With Fulcrum’s first plant under construction, this partnership accelerates the construction schedule for Fulcrum’s next renewable jet fuel plants.
Fulcrum and Air BP, the aviation division of BP, have also agreed to terms on a 500-million gallon jet fuel offtake agreement that will provide Air BP with 50 million gallons per year of low-carbon, drop-in jet fuel. Air BP will also have the opportunity to provide fuel supply chain services for the blending, certification and delivery of Fulcrum’s jet fuel to commercial and military aviation customers.
SAE REX: PHEVs and REEVs could open door for advanced combustion regime engines
November 07, 2016
Increased market penetration of plug-in hybrid electric vehicles (PHEVs) and range-extended electric vehicles (REEVs) across vehicle segments could present an opportunity for emerging advanced combustion regime engines, such as those using various low-temperature combustion modes, according to a number of presentations at the SAE 2016 Range Extenders for Electric Vehicles Symposium held last week in Knoxville.
The REEV or PHEV also may present opportunities for more novel power sources such as turbines (Wrightspeed), fuel cell stacks (Nissan) or aluminum-air batteries (Phinergy and Arconic), speakers suggested. The REX symposium was sponsored by Mahle; the organizers were from Oak Ridge National Laboratory and Mahle.
FCA presents Fiat 500 M15 (methanol); to be sold in Israel
November 03, 2016
At the Fuel Choices Summit in Israel this week, FCA presented the Fiat 500 M15—a retail-ready version of the Fiat 500 that runs on a blend of 85% gasoline and 15% methanol; is compliant with the Euro 6 New European Driving Cycle (NEDC); delivers a 2% CO2 reduction compared with the same Euro 6 version of the vehicle running on gasoline; and maintains the same vehicle performance.
The Fiat 500M15 is bi-fuel and can run on both M15 and gasoline, as well as any mixture of the two fuels. The product will be marketed in Israel by MCA—the official Israeli importer of FCA Group.
JILA team identifies missing piece in how fossil fuel combustion contributes to air pollution
October 31, 2016
JILA physicists and colleagues have identified a long-missing piece in the puzzle of exactly how fossil fuel combustion contributes to air pollution and a warming climate. Performing chemistry experiments in a new way, they observed a key molecule that appears briefly during a common chemical reaction in the atmosphere. JILA a partnership of the National Institute of Standards and Technology (NIST) and the University of Colorado Boulder. Their paper appears in Science.
The reaction combines the hydroxyl molecule (OH, produced by reaction of oxygen and water) and carbon monoxide (CO, a byproduct of incomplete fossil fuel combustion) to form hydrogen (H) and carbon dioxide (CO2).
IMO sets 2020 date for ships to comply with low sulfur fuel oil requirement; 5000 ppm
October 29, 2016
The International Maritime Organization (IMO), the regulatory authority for international shipping, decided to implement a global sulfur cap of 0.50% m/m (mass/mass) (5,000 ppm) on fuel oil starting 1 January 2020 during its Marine Environment Protection Committee (MEPC), meeting for its 70th session in London.
The cap represents a significant cut from the 3.5% m/m (35,000 ppm) global limit currently in place and demonstrates a clear commitment by IMO to ensuring shipping meets its environmental obligations.
Study finds ethanol blending appears to reduce significantly genotoxic emissions from gasoline direct injection vehicles
October 24, 2016
A research team from Empa (Swiss Federal Laboratories for Materials Science and Technology) and the University of Applied Sciences Bern, Laboratory for Exhaust Emission Control, reports that ethanol blending appeared to reduce genotoxic emissions from a flex-fuel Euro-5 gasoline direct injection (GDI) vehicle (a Volvo V60 with a 1.6 L engine) under transient and steady driving conditions.
In a paper published in the ACS journal Environmental Science & Technology, the researchers reported that particle number emissions when operating the vehicle in the hWLTC (hot started worldwide harmonized light-duty vehicle test cycle) with E10 and E85 were lowered by 97% and 96% respectively compared with that of E0. CO emissions dropped by 81% and 87%, while CO2 emissions were reduced by 13 and 17%. Emissions of selected polycyclic aromatic hydrocarbons (PAHs) were lowered by 67–96% with E10 and by 82–96% with E85, and the genotoxic potentials dropped by 72% and 83%, respectively.
US total petroleum demand up in September year-on-year; highest September gasoline deliveries on record
October 22, 2016
Total petroleum deliveries in September increased 1.0% from September 2015, but were down 2.6% from August to average 19.6 million barrels per day, according to figures from the American Petroleum Institute (API). These September deliveries were the highest deliveries for the month in nine years, since 2007.
For the third quarter of 2016, total petroleum deliveries, a measure of US petroleum demand, decreased by 0.1% from the same period last year. For year to date, total domestic petroleum deliveries remained flat compared to the same period last year.
27 teams advancing in $20M NRG COSIA Carbon XPRIZE; converting CO2 to products
October 18, 2016
XPRIZE announced the 27 teams representing six countries advancing in the $20-million NRG COSIA Carbon XPRIZE, a global competition to develop technologies that convert the most carbon dioxide emissions from natural gas and power plant facilities into products with the highest net value. The semi-finalist teams propose converting CO2 into products as varied as enhanced concrete, fuels, toothpaste, nanotubes, fish food and fertilizer.
Launched in September 2015, the 4.5-year competition includes the demonstrations by finalist technologies at either a coal or a natural gas power plant. Six of the teams are competing in both the coal and natural gas competition tracks. About half of the 27 teams are producing fuels of one sort or another, with several more producing liquid chemicals that could serve as intermediates to fuel production. Those teams producing fuels or potential intermediates include:
New three-step process for conversion of vegetable oils into cycloparaffinic and aromatic biofuels in jet fuel range
October 17, 2016
A team from the University of Science & Technology of China in Hefei has developed a three-step process for the conversion of vegetable oils (triglycerides) into cycloparaffinic and aromatic biofuels in jet fuel range.
This process cracks vegetable oils into light aromatics over the zeolite catalyst (HZSM-5(80)), followed by the aromatic alkylation of the resulting light aromatics using the ionic liquid [bmim]Cl-2AlCl3, followed by the hydrogenation of the aromatics over a Pd/AC catalyst. As reported in a paper in the journal Fuel, the process produced 86.2 wt% of C8–C15 aromatics after alkylation, yielding 84.3 wt% monocyclic cycloparaffins after hydrogenation.
Rotterdam proposed location for Enerkem waste-to-chemicals plant
October 07, 2016
A partnership comprising AkzoNobel, Van Gansewinkel, Air Liquide, AVR and Enerkem is proposing to build a waste-to-chemicals plant in Rotterdam in collaboration with the Port of Rotterdam, the City of Rotterdam, the province of South Holland and InnovationQuarter.
The new chemical plant will use Enerkem’s innovative technology to convert residual waste into methanol, a raw material used in the chemical industry. The methanol will then be converted into chemicals such as acetic acid (e.g., for fibers and adhesives), thickening agents and dimethyl ether (clean propellant gases).
NREL lowers biofuel costs through catalyst regeneration and vapor-phase upgrading; R-Cubed
October 06, 2016
This past June, researchers at the National Renewable Energy Laboratory (NREL), in partnership with Particulate Solids Research, Inc. and Springs Fabrication, installed a recirculating regenerating riser reactor (R-Cubed) in the pilot-scale Thermochemical Process Development Unit (TCPDU). Funded by the DOE Bioenergy Technologies Office (BETO), this unique unit represents the next generation of thermochemical biomass conversion technology and adds additional capabilities to NREL’s state-of-the-art Thermochemical Users Facility.
The R-Cubed system will now allow for catalytic upgrading of biomass pyrolysis vapors—a process that can significantly improve the efficiency and reduce the costs associated with upgrading bio-oil to a finished fuel product—at an industrially-relevant pilot scale.
EPA proposing updates to Renewable Fuel Standard
October 05, 2016
EPA is proposing updates to the Renewable Fuels Standard (RFS) regulations and related fuels regulations to better align the standards with the current state of the renewable fuels market and to promote the use of ethanol and non-ethanol biofuels.
Several of the proposed changes to the Renewable Fuel Standard program would align regulations with recent developments in the marketplace resulting in increased production of cellulosic, advanced and other biofuels, EPA said.
Researchers show mixotrophic fermentation process improves carbon conversion, boosting yields and reducing CO2
October 03, 2016
A team from White Dog Labs, a startup commercializing a mixotrophy-based fermentation process, and the University of Delaware have shown that anaerobic, non-photosynthetic mixotrophy—the concurrent utilization of organic (for example, sugars) and inorganic (CO2) substrates in a single organism—can overcome the loss of carbon to CO2 during fermentation to increase product yields and reduce overall CO2 emissions.
In an open-access paper published in Nature Communications, the researchers report on their engineering of the bacterium Clostridium ljungdahlii to produce acetone with a mass yield 138% of the previous theoretical maximum using a high cell density continuous fermentation process. In addition, when enough reductant (i.e., H2) was provided, the fermentation emitted no CO2. They further showed that mixotrophy is a general trait among acetogens.
Global Bioenergies reports first production of isobutene from wheat straw at the industrial pilot scale
September 29, 2016
Global Bioenergies and Clariant announced the first isobutene production from a wheat straw hydrolysate, in the industrial pilot of Pomacle Bazancourt. This success is the result of a collaboration initiated more than 18 months ago, and has been made possible by combining Clariant’s proprietary process, allowing for the conversion of agricultural residues into sugar-rich hydrolysates, with Global Bioenergies’ proprietary process for the production of isobutene from various industrial-grade sugars.
Clariant has produced the wheat straw hydrolysate, rich in non food/non feed second generation sugar, in its Straubing facility in Germany. This hydrolysate was converted into renewable isobutene in Global Bioenergies’ industrial pilot operated by ARD in its Pomacle-Bazancourt facility. This result demonstrates the maturity, the complementarity, and the versatility of the two proprietary processes.
Study shows gasoline pre-blending in ethanol production could cut energy requirements of separation by 17-40%
September 26, 2016
Researchers at the University of Witwatersrand and the University of South Africa are proposing replacing the final purification steps of conventional bio-ethanol production with a simple gasoline-blending step.
In a paper published in the ACS journal Energy & Fuels, they show that gasoline pre-blending results in a spontaneous liquid phase split which produces a viable fuel with desirable ethanol content and high recovery of ethanol; reduces the energy requirements of separation by between 17 and 40%; reduces operating costs of the process; and also eliminates capital expenses.
Toyota develops new DNA analysis technology to accelerate plant improvement; boosting biofuel crop yield
September 23, 2016
Toyota Motor Corporation (TMC) has developed a DNA analysis technology it calls Genotyping by Random Amplicon Sequencing (GRAS). This technology is capable of significantly improving the efficiency of identifying and selecting useful genetic information for agricultural plant improvement.
This newly developed technology could thus lead to substantial time and cost savings in the agricultural plant improvement process. Toyota says that the promising technology has the potential to boost sugar-cane production, and to increase biofuel crop yields per unit area of land. The company worked with analytical materials provided by the Kyushu Okinawa Agricultural Research Center (KARC) of the National Agriculture and Food Research Organization (NARO)
Navy tests 100-percent CHCJ advanced biofuel in EA-18G
September 20, 2016
The US Navy has completed flight testing of a 100% advanced biofuel in the EA-18G “Green Growler” at Naval Air Station Patuxent River, Maryland. The US Navy is a leader in incorporating alternative fuel into operational supplies, in order to increase mission capability and flexibility.
The catalytic hydrothermal conversion-to-jet (CHCJ) process 100% alternative fuel performed as expected during a ground test 30 August at NAWCAD’s Aircraft Test and Evaluation Facility (ATEF), followed by the first test flight 1 September, said Rick Kamin, energy and fuels lead for Naval Air Systems Command (NAVAIR). Kamin also leads the alternative fuel test and qualification program for the Navy.
KAUST team proposes pine-tree derived terpineol as octane booster for gasoline
September 17, 2016
A team at the Clean Combustion Research Center (CCRC), King Abdullah University of Science and Technology (KAUST), Saudi Arabia, is proposing the use of terpineol as an octane booster for gasoline in a spark ignited (SI) engine. Terpineol is a bio-derived oxygenated fuel obtained from pine tree resin, and has the advantage of higher calorific value than ethanol, enabling improved fuel economy.
Terpineol is produced by the addition of phosphoric acid with pinene, which is extracted from the resins of pine tree. It is an unsaturated cyclic alcohol; previous work on the combustion chemistry of alcohols suggested that terpineol will have a high antiknock potential.
DOE seeking input on H2@scale: hydrogen as centerpiece of future energy system; 50% reduction in energy GHGs by 2050
September 11, 2016
Earlier this year, The US Department of Energy (DOE) national laboratories identified the potential of hydrogen to decarbonize deeply a multitude of sectors in a proposal termed “H2@Scale”. Preliminary analysis performed by the national laboratories on the H2@Scale concept indicated that nearly a 50% reduction in greenhouse gas emissions is possible by 2050 via such large-scale hydrogen production and use.
The concept sees hydrogen—a flexible, clean energy-carrying intermediate—having the potential to be a centerpiece of a future energy system where aggressive market penetration of renewables (wind and solar) are coupled with renewable hydrogen production to meet society’s energy demands across industrial, transportation, and power generation sectors using clean, renewable resources and processes.
Gen 2 Audi A5 Sportback available as bivalent g-tron; Audi e-gas, natural gas or gasoline
September 07, 2016
Following on the heels of the introduction of the second-generation A5 in June (earlier post), Audi has now introduced the new A5 and S5 Sportback coupé models.
The second generation comes with a completely reengineered suspension, high-performance drives and innovative driver assistance systems. The S5 takes to the road with a new six-cylinder turbo engine developing 354 hp (264 kW) and 500 N·m (369 lb-ft). In a new departure, the A5 Sportback is also available as a bivalent g-tron, which customers can run on either Audi e-gas (earlier post), natural gas or gasoline.
Tesoro to acquire renewable fuels company Virent
Renewable fuels and chemicals company Virent and petroleum refiner and marketer Tesoro have reached an agreement for Tesoro to become Virent’s new strategic owner. The acquisition will support the scale-up and commercialization of Virent’s BioForming technology for the production of low carbon bio-based fuels and chemicals. (Earlier post.)
The companies initiated a strategic relationship in January 2016 (earlier post), and have worked together to establish a forward plan to scale-up the technology and reduce deployment risks to meet the increasing demands for high quality, renewable fuels and chemicals.
European consortium begins demonstration project for conversion of woody biomass to chemicals: BIOFOREVER
BIOFOREVER (BIO-based products from FORestry via Economically Viable European Routes)—a consortium of 14 European companies—has started a demonstration project for the conversion of woody biomass to value-adding chemical building blocks such as butanol, ethanol, and 2,5–furandicarboxylic acid (FDCA) on an industrial scale.
The demonstration project will run for 3 years. The overall budget is €16.2 million (US$18 million) with a €9.9-million (US$11-million) contribution from BBI JU. Woody biomass, including waste wood, will be converted to lignin, (nano-) cellulose and (hemi-) cellulosic sugars, and further converted to lignin derivatives and chemicals. Feedstocks will be benchmarked with crop residues and energy crops.
Study finds isopropanol-n-butanol-ethanol and gasoline blend viable as alternative fuel
September 05, 2016
Researchers from the University of Illinois and colleagues in China investigating the performance, combustion and emission characteristics of a port fuel-injection SI engine fueled with isopropanol-n-butanol-ethanol (IBE)-gasoline blends have concluded that an IBE30 blend could be a good alternative to gasoline.
Bio-n-butanol itself is a promising alternative fuel, produced conventionally from the fermentation of carbohydrates by Clostridium bacteria in a well-established process referred to as ABE fermentation, after its major chemical products: acetone, butanol and ethanol. However, ABE fermentation production suffers from relatively low production efficiency as well as the high cost of component recovery; the product mixture typically has an A:B:E ratio of 3:6:1.
SLAC, Utrecht Univ. team visualize poisoning of FCC catalysts used in gasoline production; seeing changes in pore network materials
August 31, 2016
Merging two powerful 3-D X-ray techniques, a team of researchers from the Department of Energy’s SLAC National Accelerator Laboratory and Utrecht University in the Netherlands revealed new details of the metal poisoning process that clogs the pores of fluid catalytic cracking (FCC) catalyst particles used in gasoline production, causing them to lose effectiveness.
The team combined their data to produce a video that shows the chemistry of this aging process and takes the viewer on a virtual flight through the pores of a catalyst particle. More broadly, the approach is generally applicable and provides an unprecedented view of dynamic changes in a material’s pore space—an essential factor in the rational design of functional porous materials including those use for batteries and fuel cells. The results were published in an open access paper in Nature Communications.
Researchers generate methane from CO2 in one light-driven step using engineered bacteria
August 25, 2016
Using an engineered strain of the phototropic bacterium Rhodopseudomonas palustris as a biocatalyst, a team from the University of Washington, Utah State University and Virginia Polytechnic Institute and State University have reduced carbon dioxide to methane in one enzymatic step.
The work demonstrates the feasibility of using microbes to generate hydrocarbons (i.e., CH4 in this case) from CO2 in one enzymatic step using light energy. A paper on their work is published in Proceedings of the National Academy of Sciences (PNAS).
China team develops pathway for producing renewable aviation-range hydrocarbons and aromatics from oleic acid without added H2
Researchers from Zhejiang University; SINOPEC’s Fushun Research Institute of Petroleum and Petrochemicals; Nanjing Tech University; and Xinjiang Technical Institute of Physics and Chemistry have developed an “atom-economic” approach to produce renewable drop-in aviation-range hydrocarbons and aromatics from oleic acid (C18H34O2, a fatty acid that occurs naturally in various animal and vegetable fats and oils) without an added hydrogen donor. A paper on their work is published in the ACS journal Energy & Fuels.
The conversion of oleic acid in the process was 100%, and the yield of heptadecane (C17H36, the main product) can reach 71% after 80 min at 350 °C. The process also produced an aromatics yield of 19%; aromatics are a critical component of aviation fuels due to their ability to maintain the swelling of fuel system elastomers. The results, said the researchers, indicate that their process is a complicated reaction system including in situ hydrogen transfer, aromatization, decarboxylation, and cracking.
MIT team calculates lead emissions from avgas fuel in US contribute to ~$1B in annual damages due to IQ losses
August 24, 2016
Researchers at MIT have produced the first assessment of the annual costs of IQ losses from aircraft lead emissions in the US. Their study, published in the ACS journal Environmental Science & Technology, found that that atmospheric lead pollution attributable to leaded aviation gas (avgas) contributes to US$1.06 billion (the mean from a range of $0.01–$11.6 billion) in annual damages from lifetime earnings reductions, and that dynamic economy-wide methods result in damage estimates that are 54% larger.
Because the marginal costs of atmospheric lead pollution are dependent on background concentration, the researchers also expect the costs of piston-driven aircraft lead emissions to increase over time as regulations on other emissions sources are tightened.
PNNL-Lanzatech team hits milestone on waste-gas-to-ethanol-to-jet project
August 23, 2016
With funding from Bioenergy Technologies Office (BETO), Pacific Northwest National Laboratory (PNNL) has been working with industry-partner LanzaTech to convert alcohols derived from captured carbon monoxide, a byproduct in the production of steel, into synthetic paraffinic kerosene, a non-fossil-based jet fuel. The technology not only provides a viable source of sustainable jet fuel but also reduces the amount of greenhouse gasses emitted into the atmosphere.
The team recently reached a significant milestone on the project, producing over five gallons of synthetic paraffinic kerosene in a lab environment. Five gallons is the quantity needed for “fit-for-purpose” testing.
Researchers clarify role of cetane number and aromaticity in soot-NOx tradeoff
August 22, 2016
A study by researchers at Eindhoven University of Technology has found that the “persistent diesel dogma” of “the higher the cetane number (CN) the better” relative to the soot-NOx trade-off is valid in neither conventional or low temperature combustion operation. The open-access study, published in the journal Fuel also reported that a second piece of conventional wisdom—“the lower the aromaticity the better”— is valid in both combustion modes.
The researchers also devised a new, dimensionless parameter—Π—that holds distinct values for the various combustion modes. This can predict either a positive, neutral or negative impact of high CN and low aromaticity on the soot-NOx trade-off based on a given set of engine operating conditions.
Study suggests focusing on cold starts in gasoline cars as target for emissions reduction
A new study suggests that focusing on a gasoline-fueled vehicle’s cold start is the best target for future design changes to reduce emissions of criteria pollutants. The researchers are presenting their work today at the 252nd National Meeting & Exposition of the American Chemical Society (ACS) in Philadelphia.
Although the Environmental Protection Agency (EPA) has reported that air is cleaner today than it was in the 1970s, more than 130 million people in the US still live in places where smog or particle pollution rises to unhealthful levels. Smog can cause coughing and shortness of breath, and can aggravate asthma or trigger asthma attacks. Much of this haze is formed from volatile organic compounds, or VOCs, and fine particulate matter from tailpipe emissions.
EPA Office of Inspector General: EPA has not met certain statutory requirements to identify environmental impacts of RFS
August 19, 2016
The US Environmental Protection Agency Office of Inspector General (OIG) has found that the EPA has not met certain statutory requirements to identify environmental impacts of Renewable Fuel Standard.
In a newly released report, the OIG said that EPA’s Office of Research and Development has not complied with the requirement to provide a report every 3 years to Congress on the impacts of biofuels. The EPA provided a report to Congress in 2011, but has not provided subsequent reports as required.
New genome sequences target next generation of yeasts with improved biotech uses
August 16, 2016
Metabolically, genetically and biochemically, yeasts (unicellular fungi) are highly diverse; more than 1,500 yeast species have been identified. Characteristics such as thick cell walls and tolerance of pressure changes that could rupture other cells mean yeasts are easily scaled up for industrial processes. In addition, they are easy to grow and modify and, with notable exceptions such as Candida albicans, most are not associated with human illness. While these capabilities can be used for a wide range of biotechnological applications, including biofuel production, so far industry has only harnessed a fraction of the diversity available among yeast species.
To help boost the use of a wider range of yeasts and to explore the use of genes and pathways encoded in their genomes, a team led by researchers at the US Department of Energy Joint Genome Institute (DOE JGI), a DOE Office of Science User Facility at Lawrence Berkeley National Laboratory, conducted a comparative genomic analysis of 29 yeasts, including 16 whose genomes were newly sequenced and annotated. In a study being published this week in the Proceedings of the National Academy of Sciences (PNAS), the team mapped various metabolic pathways to yeast growth profiles.
EIA: US ethanol plant capacity increases to nearly 15B gallons/year; 3rd consecutive annual increase
August 10, 2016
Fuel ethanol production capacity in the United States was 14.903 billion gallons per year, or 973,000 barrels per day (b/d), at the beginning of 2016, according to the US Energy Information Administration’s (EIA’s) most recent US Fuel Ethanol Plant Production Capacity report. Total capacity of operable ethanol plants increased by more than 500 million gallons per year in January 2016 compared with the January 2015 total of 14.369 billion gallons.
Actual US production of fuel ethanol reached a total of 14.8 billion gallons (966,000 b/d) in 2015. In EIA’s August Short-Term Energy Outlook (STEO), US production of fuel ethanol was forecast to reach 15.1 billion gallons (982,000 b/d) in 2016, equivalent to slightly more than 100% utilization of reported nameplate capacity as of 1 January 2016.
Researchers say fuel market rebound effect can result in increased GHG emissions under RFS2; suggest taxes over mandates
August 08, 2016
The US Renewable Fuel Standard (RFS2) is intended to reduce greenhouse gas emissions from transportation. However, argues a team from the University of Minnesota in an open-access paper published in the journal Energy Policy, once the “fuel market rebound effect” is factored in, RFS2 actually increases GHG emissions when all fuel GHG intensity targets specified under the act are met.
Increasing the supply of low-carbon alternative fuels is a basic strategy to reduce greenhouse gas emissions. However, the Minnesota team notes, increasing the supply of fuels tends to lower energy prices, which encourages in turn encourages additional fuel consumption. This “fuel market rebound effect” can undermine climate change mitigation strategies, even to the point where efforts to reduce GHG emissions by increasing the supply of low-carbon fuels may actually result in increased GHG emissions.
MIT, Novogy team engineers microbes for competitive advantage in industrial fermentation; the ROBUST strategy
August 06, 2016
Researchers at MIT and startup Novogy have engineered bacteria and yeast (Escherichia coli, Saccharomyces cerevisiae and Yarrowia lipolytica) used as producer microbes in biofuel production to use rare compounds as sources of nutrients. The technique, described in a paper in the journal Science, provides the producer microbes with competitive advantage over other, contaminating microbes with minimal external risks, given that engineered biocatalysts only have improved fitness within the customized fermentation environment.
Ethanol is toxic to most microorganisms other than the yeast used to produce it, naturally preventing contamination of the fermentation process. However, this is not the case for the more advanced biofuels and biochemicals under development. Thus, one problem facing the production of advanced biofuels via large-scale fermentation of complex low-cost feedstocks (e.g., sugarcane or dry-milled corn) is the contamination of fermentation vessels with other, unwanted microbes that can outcompete the designated producer microbes for nutrients, reducing yield and productivity.
New ceramic membrane enables first direct conversion of methane to liquids without CO2 emissions
August 05, 2016
A team from CoorsTek Membrane Sciences, the University of Oslo (Norway), and the Instituto de Tecnología Química (ITQ) (Spain) has developed a new process for the direct, non-oxidative conversion of methane to liquids—reducing cost, eliminating multiple process steps, and avoiding CO2 emissions.
The process uses a novel ceramic membrane that simultaneously extracts hydrogen and injects oxide ions. The resulting aromatic precursors are source chemicals for insulation materials, plastics, textiles, and jet fuel, among other valuable products. A paper describing the process is published in the journal Science.
Nissan: more electric car charging stations than fuel stations in UK by 2020
August 03, 2016
There will be more public locations to charge electric cars in the UK than there are gasoline stations by the summer of 2020, according to new analysis by Nissan. At the end of 2015, there were just 8,472 fuel stations in the UK, down from 37,539 in 1970—a 77% drop. Assuming a steady rate of decline, Nissan predicts that by August 2020 this will fall to below 7,870.
The supply of fuel within the Capital is also becoming scarcer. Central London has nearly half as many gasoline stations per car as the Scottish Highlands; only four remain within the congestion-charge zone. A notable closure in 2008 was one of the country’s oldest forecourts, the Bloomsbury Service Station, which had been operational since 1926.
DOE awarding up to $11.3M to 3 projects under MEGA-BIO for biomass-to-hydrocarbon fuels, products
The US Department of Energy (DOE) will award up to $11.3 million to three projects under MEGA-BIO: Bioproducts to Enable Biofuels (earlier post) that support the development of biomass-to-hydrocarbon biofuels conversion pathways that can produce variable amounts of fuels and/or products based on external factors, such as market demand.
Producing high-value bioproducts alongside cost-competitive biofuels has the potential to support a positive return on investment for a biorefinery. This funding is intended to develop new strategies for biorefineries to diversify revenue streams, including chemicals and products manufacturing, resulting in long-term economic benefits to the United States. Projects selected for funding are:
DOE to award $7M to accelerate fuel and engine co-optimization technologies; Co-Optima initiative
August 01, 2016
The US Department of Energy (DOE) will award up to $7 million in project funding to accelerate the introduction of affordable, scalable, and sustainable high-performance fuels for use in high-efficiency, low-emission engines as part of the Co-Optimization of Fuels and Engines (Co-Optima) initiative. (Earlier post.)
Co-optimized fuels and engines offer the opportunity to build on decades of advancements in both fuels and engines. Groundbreaking research in the last 10 years has identified combustion engine strategies that—especially if optimized to run on new fuels—would offer significantly higher efficiency and produce fewer engine-out pollutants than current engines. The new funding opportunity (DE-FOA-0001461) will advance the long-term objective of the Co-Optima initiative to accelerate widespread deployment of significantly improved fuels and vehicles (from passenger to light truck to heavy-duty commercial vehicles) by 2030.
Orbital ATK and ECAPS partner on high performance green propulsion system; bringing LMP-103S to market
July 26, 2016
Orbital ATK signed an agreement with leading European green propulsion technology firm ECAPS to develop, demonstrate and market a high performance green propulsion (HPGP) system. The HPGP system, which offers significant cost advantages and reduces the environmental risks associated with traditional monopropellants, is aimed at both attitude control and main propulsion.
Orbital ATK’s team will leverage exclusive use of ECAPS’ LMP-103S, a very-low toxicity monopropellant technology designed as a direct replacement for hydrazine-based systems. LMP-103S—a blend of ammonium dinitramide (ADN), water, methanol and ammonia—offers a specific impulse 6% higher and a propellant density 24% higher than hydrazine-based systems—resulting in a 30% increase in density-specific impulse.
EPA finds moderate or severe corrosion in majority of diesel fuel underground storage tank systems studied
In a report released recently on corrosion inside diesel fuel underground storage tanks (USTs), the US Environmental Protection Agency (EPA) found moderate or severe corrosion that could affect metal components inside both steel and fiberglass underground tank systems. Corrosion inside USTs can cause equipment failure by preventing proper operation of release detection and prevention equipment. If left unchecked, corrosion could cause UST system failures and releases, which could lead to groundwater contamination.
Beginning around 2007, UST owners reported to servicing companies new incidents of severe and rapid corrosion of internal metal components of tanks storing diesel fuel. These reports usually described severe corrosion of equipment in upper portions of UST systems in the regions generally not submerged in fuel. Prior to 2007, a corrosion risk in diesel fuel tanks was considered minor and, if it occurred, appeared in the wetted, or lower, portion of the tank.
Rice team develops “antenna-reactor” plasmonic catalysts for increased energy savings and efficiency in catalytic processes
July 24, 2016
Researchers at Rice University’s Laboratory for Nanophotonics (LANP), with colleagues at Princeton University, have developed a new method for uniting light-capturing photonic nanomaterials and high-efficiency metal catalysts, creating an “antenna-reactor” plasmonic catalyst.
By placing a catalytic reactor particle adjacent to a plasmonic antenna, the highly efficient and tunable light-harvesting capacities of plasmonic nanoparticles can be exploited to increase absorption and hot-carrier generation significantly in the reactor nanoparticles. The modularity of this approach provides for independent control of chemical and light-harvesting properties and paves the way for the rational, predictive design of efficient plasmonic photocatalysts, the researchers suggest in their open-access paper, published in Proceedings of the National Academy of Sciences (PNAS).
JBEI scientists use CO2 to control toxicity of ionic liquids in biomass pretreatment; lowering production costs
July 22, 2016
Researchers at the Department of Energy’s Lawrence Berkeley National Laboratory and Sandia National Laboratories working at the Joint BioEnergy Institute (JBEI) have demonstrated that adding CO2 during the deconstruction phase of biofuel production successfully neutralizes the toxicity of ionic liquids, the room-temperature molten salt solvent used at JBEI to break down cellulosic plant material.
The process is easily reversible, allowing the liquid to be recycled for use as a solvent again. Their study, published RSC journal Energy & Environmental Science, addresses a significant obstacle to expanding the market for biofuels: lowering the cost of production.
New study finds that ship emissions from HFO and diesel adversely affect pulmonary macrophages
July 20, 2016
A study by European researchers has found that ship emissions from the combustion of heavy fuel oil (HFO) and diesel fuel (DF) have adverse effects on pulmonary macrophages, from increased cell death to altered metabolic profile, depending upon the aerosol component. Their open access paper is published in the journal PLOS ONE.
Macrophages are white blood cells and are part of the immune system. Often referred to as scavenger cells, they absorb and engulf microorganisms. In addition, the cells destroy tumor cells, remove cell debris, present antigens and promote wound healing. There are four types of pulmonary macrophages: alveolar; interstitial; intravascular; and the dendritic. The alveolar macrophages are the only macrophages in the body which are exposed to air. Located at the interphase between air and lung tissue, they represent the first line of defense against inhaled airborne elements.
Lux: biojet fuel to account for 56% of targeted 2050 CO2 emissions reductions in aviation
July 19, 2016
Biojet fuels will be key to achieving the aviation industry’s pledge to cut CO2 emissions to 0.2 billion tons (GT) in 2050—half the 2005 figure—as opposed to the staggering 2.1 GT projected by current growth rates, according to a new report from Lux Research, “Biojet Fuel Technology Roadmap.”
Lux forecasts that biojet fuel innovations, led globally by Honeywell UOP and Boeing, will account for 56% of the targeted CO2 emissions reductions, while a third of the requisite cuts will come from new aircraft technology, and optimization of operations and infrastructure.
Six refineries in $425M settlement with EPA and DOJ over emissions violations
The Department of Justice and the US Environmental Protection Agency (EPA) announced a $425-million settlement with subsidiaries of Tesoro Corp., and Par Hawaii Refining that resolves alleged Clean Air Act violations and protects public health by reducing air pollution at six refineries. Under the settlement, the two companies will spend about $403 million to install and operate pollution control equipment, and Tesoro will spend about $12 million to fund environmental projects in local communities previously impacted by pollution. Tesoro will also pay a $10.45 million civil penalty.
The settlement, a consent decree lodged in US District Court for the Western District of Texas, includes provisions that resolves ongoing Clean Air Act violations at refineries in Kenai, Alaska; Martinez, California; Kapolei, Hawaii; Mandan, North Dakota; Salt Lake City, Utah; and Anacortes, Washington. Of the $10.45-million civil penalty that Tesoro will pay, the United States will receive $8,050,000, and co-plaintiffs including the states of Alaska and Hawaii, and the Northwest Clean Air Agency will share $2.4 million. Under the settlement, all six refineries must implement specific provisions to reduce flaring and enhance leak detection and repair:
DOE to issue funding opportunity to support Co-Optimization of Fuels and Engines initiative
July 16, 2016
The US DOE Office of Energy Efficiency and Renewable Energy (EERE) intends (DE-FOA-0001623) to issue, on behalf of the Bioenergy Technology Office (BETO) and Vehicle Technologies Office (VTO), a funding opportunity announcement (FOA) entitled “Co-Optimization of Fuels and Engines.” The FOA (DE-FOA-0001461) will be restricted to US institutions of higher education and non-profit research institutions.
This FOA will support the Co-Optimization of Fuels and Engines (Co-Optima) initiative (earlier post), a collaborative initiative being pursued by BETO and VTO to accelerate the introduction of affordable, scalable, and sustainable high-performance fuels for use in high-efficiency, low-emission engines.
Boeing, South African Airways and Mango celebrate Africa’s 1st commercial flights with sustainable aviation biofuel from tobacco
July 15, 2016
Boeing, South African Airways (SAA) and low-cost carrier Mango celebrated Africa’s first passenger flights with sustainable aviation biofuel. The flights coincided with Boeing’s 100th anniversary and centennial celebrations worldwide.
The SAA and Mango flights carried 300 passengers from Johannesburg to Cape Town on Boeing 737-800s using a blend of 30% aviation biofuel produced from Sunchem’s nicotine-free tobacco plant Solaris, refined by AltAir Fuels and supplied by SkyNRG. (Earlier post.)
DOE awarding $15M to 3 algae-based biofuel and bioproducts projects
July 14, 2016
The US Department of Energy (DOE) is awarding up to $15 million for three projects aimed at reducing the production costs of algae-based biofuels and bioproducts through improvements in algal biomass yields.
These projects will develop highly productive algal cultivation systems and couple those systems with effective, energy-efficient, and low-cost harvest and processing technologies. This funding will advance the research and development of advanced biofuel technologies to speed the commercialization of renewable, domestically produced, and affordable fossil-fuel replacements.
Governments of Canada & Québec award $76.5M to AE Côte-Nord Canada Bioenergy for renewable fuel oil from forest residues w/ Ensyn RTP
The Governments of Canada and Québec will provide $76.5 million in funding to AE Côte-Nord Canada Bioenergy Inc. for the production of renewable fuel oil (RFO) from forest residues. The plant, which will use Ensyn’s RTP (rapid thermal processing) (earlier post), will be the first commercial RTP facility designed and optimized for the production of biocrude used for heating, cooling and refinery applications, according to Dr. Robert Graham, Chairman, Ensyn Corporation.
The Port-Cartier plant will also be the first commercial-scale facility of this kind in Québec. The goal of the project is to convert forest residues into 40 million liters (10.6 million gallons US) of renewable fuel oil per year. When upgraded into transportation fuels, this will remove up to 70,000 tonnes of CO2-equivalent emissions per year. Production of renewable fuel oil is set to begin in 2017.
New hybrid sweetgum trees could boost paper, bioenergy production
Researchers at the University of Georgia (UGA) have crossed American sweetgums with their Chinese cousins, creating hybrid sweetgum trees that have a better growth rate and denser wood than natives, and can produce fiber year-round. The hybrid sweetgum trees have enormous potential for the production of bioenergy and paper, said Scott Merkle, a professor in UGA’s Warnell School of Forestry and Natural Resources.
Sweetgum trees thrive under diverse conditions, grow as fast as pine trees and provide the type of fiber needed for specialty papers-and they’ve long been desired by paper and bioenergy producers. However, harvesting mature sweetgums can often be too costly or even ill-advised because they typically grow the best on the edges of swamps and in river bottoms, which are often inaccessible during the wet winter months.
2016 Billion Ton Report shows US could sustainably produce at least 1B tons biomass by 2040 for bioeconomy
July 13, 2016
Within 25 years, the United States could produce enough biomass to support a bioeconomy, including renewable aquatic and terrestrial biomass resources that could be used for energy and to develop products for economic, environmental, social, and national security benefits, according to the new 2016 Billion-Ton Report, jointly released by the US Department of Energy and Oak Ridge National Laboratory (ORNL).
The 2016 Billion-Ton Report, volume 1, updates and expands upon analysis in the 2011 US Billion-Ton Update (earlier post), which was preceded by the 2005 US Billion Ton Study (earlier post). The report uses scientific modeling systems to project biomass resource availability under specified economic and sustainability constraints.
Global Bioenergies, IBN-One and Lantmännen Aspen partner on renewable isooctane for specialty fuel applications
July 11, 2016
Global Bioenergies, IBN-One and Lantmännen Aspen, world market leader in alkylate gasoline for two- and four-stroke small engines, have entered into a partnership on renewable isooctane (earlier post) for specialty fuel applications.
Aspen is part of the Swedish Lantmännen group, an agricultural cooperative and Northern Europe’s leader in agriculture, machinery, bioenergy and food products with annual revenues of €3.4 billion (US$3.8 billion). In particular, Lantmännen Aspen’s commercial activities include specialty fuels for usage in two- and four-stroke small engines—e.g. chainsaws and lawn mowers—where the operator, machine and environment benefit from a cleaner fuel quality regarding harmful substances compared to regular gasoline.
Toyota Tsusho strategic equity investor in bio-BTX company Anellotech
Catalytic pyrolysis company Anellotech, which focuses on producing cost-competitive BTX (benzene, toluene and xylene) from non-food biomass, revealed Toyota Tsusho Corporation as a multinational strategic equity investor and corporate partner in the renewable aromatic chemicals supply chain. The renewable aromatic chemical can be used use in making plastics such as polyester, nylon, polycarbonate, polystyrene, or for renewable transportation fuels.
Toyota Tsusho is a member of the Toyota Group and is one of the major value chain partners (along with Suntory) in the Anellotech alliance, further validating the global market opportunity for Anellotech’s Bio-TCat technology.
Ricardo and Recycling Technologies to characterize Plaxx plastic-waste-derived-fuel for marine applications
July 05, 2016
UK-based Recycling Technologies is industrializing a process—originally developed at the University of Warwick (UK)—to convert residual plastic waste into a low-sulfur hydrocarbon compound called Plaxx. Plaxx is created from residual mixed plastic waste that is not amenable to direct recycling and would otherwise go to landfill.
The company, a 2013 spin-out from the University, is now working with Ricardo to characterize the use of this recycled, low-sulfur fuel as a substitute for fossil based heavy fuel oil (HFO) and diesel in applications such as power generation and marine propulsion.
Global Bioenergies obtains a €400K grant from BMBF to produce renewable gasoline additives; Audi to use for engine testing
July 04, 2016
France-based Global Bioenergies announced that its German subsidiary, Global Bioenergies GmbH, secured a €400,000 (US$446,000) grant from the BMBF (the German federal ministry for research and education) to finance a 14-month-project aimed at producing renewable gasoline additives.
Global Bioenergies has developed a process to convert renewable resources into gaseous isobutene via fermentation. Under the new grant, Global Bioenergies will first produce 100% renewable ETBE, a molecule obtained by the condensation of ethanol and isobutene, and presently used as a gasoline additive in large volumes (worldwide market: 3.4 million tons per year).
U of I study: synthetic fuels via CO2 conversion and FT not currently economically & environmentally competitive
July 03, 2016
A study by a team at University of Illinois at Urbana−Champaign has found that, with currently achievable performance levels, synthetic fuels produced via the electrochemical reduction of CO2 and the Fischer-Tropsch (FT) process system are not economically and environmentally competitive with using petroleum-based fuel. A paper detailing the study is published in the ACS journal Energy & Fuels.
In their paper, the team investigated an integrated system that converts CO2 released from fossil fuel-burning power plants to synthetic diesel fuel via a combination of the electrochemical reduction of CO2 to CO and the FT process, which uses CO and H2 from electrolysis) as feedstocks.
First investigation of HCCI combustion of polyoxymethylene dimethyl ether; alternative diesel fuel
June 25, 2016
Researchers at Tsinghua University, along with Professor Rolf Reitz at the Engine Research Center, University of Wisconsin-Madison, have investigated for the first time the the characteristics of homogenous charge compression ignition (HCCI) of polyoxymethylene dimethyl ether (PODE).
PODE is a promising alternative fuel for diesel engines, and offers high volatility, high ignitability and high oxygen content. PODE is thus also suited for for blend and dual-fuel combustion—such as reactivity controlled compression ignition (RCCI)—due to the low-temperature chemistry. A paper on their work appears in the journal Fuel.