[Due to the increasing size of the archives, each topic page now contains only the prior 365 days of content. Access to older stories is now solely through the Monthly Archive pages or the site search function.]
First investigation of HCCI combustion of polyoxymethylene dimethyl ether; alternative diesel fuel
June 25, 2016
Researchers at Tsinghua University, along with Professor Rolf Reitz at the Engine Research Center, University of Wisconsin-Madison, have investigated for the first time the the characteristics of homogenous charge compression ignition (HCCI) of polyoxymethylene dimethyl ether (PODE).
PODE is a promising alternative fuel for diesel engines, and offers high volatility, high ignitability and high oxygen content. PODE is thus also suited for for blend and dual-fuel combustion—such as reactivity controlled compression ignition (RCCI)—due to the low-temperature chemistry. A paper on their work appears in the journal Fuel.
ICM advances pathway to cellulosic ethanol with Gen 1.5 technology; collaboration with DSM and Novozymes
June 20, 2016
ICM, a leading provider of products and services to the biofuel industry, is close to the marketintroduction of its patent-pending Generation 1.5 Grain Fiber to Cellulosic Ethanol Technology (Gen 1.5), which integrates a process for converting corn fiber to cellulosic ethanol with existing ethanol plants.
This pathway to cellulosic ethanol combines mechanical, chemical, and biological processes with ICM’s experience in integrating advanced technologies into existing corn ethanol plants. Critical elements of the Gen 1.5 process were developed through collaborations with two world-leading biotechnology companies, DSM and Novozymes.
Navy study highlights potential of alkyl dioxolanes as fuel additives, importance of 2,3-BD as biomass-derived platform molecule
June 17, 2016
Researchers at the Naval Air Warfare Center Weapons Division (NAWCWD), China Lake have developed a solvent-free process for the conversion of 2,3-Butanediol (2,3-BD)—a renewable alcohol that can be prepared in high yield from biomass sugars—to a complex mixture of 2-ethyl-2,4,5-trimethyl-1,3-dioxolane (TMED) and 4,5-dimethyl-2-isopropyl dioxolane (DMID). They found that dioxolane mixture has potential applications as a sustainable gasoline blending component, diesel oxygenate, and industrial solvent (Earlier post.)
The promising results of the study, published in the journal ChemSusChem, suggest that TMED and other alkyl dioxolanes warrant further study as fuel additives, the researchers said. A wide variety of dioxolane molecules can be accessed by the reaction of renewable diols with ketones and aldehydes, allowing for custom tailoring of fuel and solvent properties. The study also suggests that—given its to be efficiently generated from a variety of biomass sources through fermentation—2,3-BD is an important platform molecule that should be exploited as a versatile intermediate to sustainable fuels and chemicals.
New report suggests bioenergy crops are not a risk to food production
June 15, 2016
In a new report, researchers have challenged the belief that growing crops for bioenergy will cut food production, a concern they say is stalling new schemes. The report also identifies five ways that countries as diverse as the United States and Brazil can achieve their targets to increase energy security, foster rural economic development and reduce greenhouse gas emissions.
Experts contributed from ten institutions across Africa, Europe and America, including the US Department of Energy’s Oak Ridge National Laboratory (ORNL), the International Food Policy Research Institute (IFPRI), the World Bank and Imperial College London in the UK.
EPA announces 2016 Presidential Green Chemistry Challenge Award winners
June 14, 2016
The US Environmental Protection Agency (EPA) has announced the Presidential Green Chemistry Challenge Award winners. The annual awards recognize landmark green chemistry technologies developed by industrial pioneers and leading scientists that turn climate risk and other environmental problems into business opportunities, spurring innovation and economic development.
The Presidential Green Chemistry Challenge Award winners were honored at a ceremony in Portland, Ore. on 13 June. The winners and their innovative technologies are:
New catalyst system for converting castor-oil-derived ricinoleic acid methyl ester into jet fuel; up to 90% carbon selectivity
June 13, 2016
Researchers at Beijing University of Chemical Technology have developed a catalytic process for the selective conversion of ricinoleic acid methyl ester—derived from castor oil—into jet fuel. A paper on their work is published in the RSC journal Green Chemistry.
A common challenge in bio-jet fuel production is the high cost due to the feedstock and processing technology. Although hydro-processing of lipid and fatty acid is well-known, the yield of jet fuel from typical lipid based oil with mainly C18 fatty acid is quite low (about 35–40%). The major reason for the low overall yield is the necessity of a hydrocracking step for converting the C18 or C16 alkane into jet fuel range paraffin (C9–C15), the researchers explained. A key improving lipid-to-jet production technology is thus to avoid the un-selective cracking.
US DRIVE releases comprehensive cradle-to-grave analysis of light-duty vehicle GHGs, cost of driving and cost of avoided GHGs
June 09, 2016
The US DRIVE Cradle-to-Grave Working Group has published the “Cradle-to-Grave Lifecycle Analysis of US Light-Duty Vehicle-Fuel Pathways: A Greenhouse Gas Emissions and Economic Assessment of Current (2015) and Future (2025–2030) Technologies” Argonne National Lab Report.
The study provides a comprehensive lifecycle analysis (LCA), or cradle-to-grave (C2G) analysis, of the cost and greenhouse gas (GHG) emissions of a variety of vehicle-fuel pathways, as well as the levelized cost of driving (LCD) and cost of avoided GHG emissions. The study also estimates the technology readiness levels (TRLs) of key fuel and vehicle technologies along the pathways. The study only addresses possible vehicle-fuel combination pathways—i.e., no scenario analysis.
DOE issues RFI on biomass supply systems to support billion-ton bioeconomy vision
The US Department of Energy (DOE) has issed a Request for Information (RFI) (DE-FOA-0001603) seeking feedback from industry, academia, research laboratories, government agencies, and other stakeholders to support a “billion-ton bioeconomy.” This request for information (RFI) asks for input about specific aspects in the development of large-scale supply systems and technologies to eventually supply up to a billion dry tons of biomass feedstocks annually for a variety of end uses.
In 2005, a joint study by the US Departments of Agriculture and Energy (USDA and DOE) concluded that the land resources of the US could produce a sustainable supply of biomass sufficient to displace 30% or more of the country’s then-present petroleum consumption. The study found that just forest land and agricultural land alone have a potential for 1.3 billion dry tons of biomass feedstock per year—leading to the shorthand “billion-ton bioeconomy.” (Earlier post.)
Siluria Technologies and Air Liquide partner to develop and deliver novel catalytic process technologies to global energy markets
June 07, 2016
Siluria Technologies has entered into a strategic partnership with Air Liquide Global E&C Solutions, the engineering and construction business of the Air Liquide Group, to collaborate on the development of novel catalytic processes utilizing both companies’ expertise in gas conversion technologies.
The novel process offering will be developed using the proven innovation platform that has given rise to Siluria’s revolutionary Oxidative Coupling of Methane (OCM) technology (earlier post), but will be focused on entirely new fields beyond the companies’ current product offerings. Siluria and Air Liquide Global E&C Solutions have agreed to work as partners in the commercialization—including marketing and licensing—of the jointly developed process technologies resulting from the collaboration.
Global companies form below50 to scale up low-carbon sustainable fuels; Audi in from automotive sector
June 06, 2016
Global companies are partnering with the World Business Council for Sustainable Development (WBCSD), Roundtable for Sustainable Biomaterials (RSB) and Sustainable Energy for All (SE4ALL) in a new global initiative called below50, to promote the best-of-breed of sustainable fuels that can achieve significant carbon reductions, and to scale-up their development and use.
A key outcome of the Low Carbon Technology Partnerships initiative (LCTPi), below50 is intended to grow a global corporate market for sustainable low-carbon transport fuels (LCTFs). Any company which produces, uses and/or invests in fuels that are at least 50% less carbon intensive than conventional fossil fuels can join below50.
New correlation between fuel octane index and HCCI combustion provides basis for more robust control strategies
A team of researchers in the US and Australia has developed a new correlation between the octane index (OI) of a range of refinery stream fuels and Homogeneous Charge Compression Ignition (HCCI) combustion phasing.
The behavior of the new model is much improved compared to the original OI model—particularly in the low intake temperature range and for fuels with high aromatic and high ethanol content. The new octane index correlation can be used for designing robust HCCI control strategies, capable of handling the wide spectrum of fuel chemical compositions found in pump gasoline, the researchers said in their paper published in the International Journal of Engine Research.
Harvard “bionic leaf 2.0” exceeds efficiency of photosynthesis in nature; hydrogen and liquid fuels
June 03, 2016
Researchers at Harvard have created a hybrid water splitting–biosynthetic system based on a biocompatible Earth-abundant inorganic catalyst system to split water into molecular hydrogen and oxygen (H2 and O2) at low driving voltages.
Grown in contact with these catalysts, the bacterium Ralstonia eutropha then consumes the produced H2 to synthesize biomass and fuels or chemical products from low CO2 concentration in the presence of O2. The scalable system has a CO2 reduction energy efficiency of ~50% when producing bacterial biomass and liquid fuel alcohols, scrubbing 180 grams of CO2 per kWh of electricity. Coupling this hybrid device to existing photovoltaic systems would yield a CO2 reduction energy efficiency of ~10%, exceeding that of natural photosynthetic systems, the researchers said in their paper published in the journal Science.
RIT and Synergy Biogas partner on algae for wastewater cleanup and biofuel production
Rochester Institute of Technology (RIT) and Synergy Biogas are exploring the environmental benefits of microalgae to clean agricultural wastewater and make biofuels. Jeff Lodge, associate professor in RIT’s Thomas Gosnell School of Life Sciences, is running a three-month pilot program at Synergy Biogas, a high-tech anaerobic digester located on Synergy Farms in Covington, N.Y, to grow microalgae on digested biomass. Microalgae will consume contaminants in wastewater and produce an algal biomass that Lodge will use as a feedstock for renewable energy.
Lodge will grow the microalgae in a 1,000-gallon tank at Synergy in a process that can be scaled up to treat 52,000 gallons, or 200,000 liters, of wastewater a day. The trial project will demonstrate the organisms’ ability to consume ammonia, phosphorous and nitrogen from digested biomass and reduce contaminants below state-mandated levels. Lodge’s laboratory experiments with microalgae have reduced phosphorous in wastewater by greater than 90% to levels of 0.1 parts per million, exceeding the required 1 parts per million in New York.
Licella and Canfor to form JV for advanced biomass-based biofuels; catalytic hydrothermal technology
May 30, 2016
Australia-based Licella Fibre Fuels Pty Ltd. and Canada-based Canfor Pulp Products Inc. (CPPI), through its subsidiary Canfor Pulp Ltd., signed an agreement to form a joint-venture: Licella Pulp Joint Venture.
Licella Pulp Joint Venture will investigate opportunities to integrate Licella’s Catalytic Hydrothermal Reactor (Cat-HTR) upgrading platform into Canfor Pulp's kraft and mechanical pulp mills to convert biomass—including wood residues from Canfor Pulp’s kraft pulping processes—economically into biocrude oil to produce next generation biofuels and biochemicals. This additional residue stream refining would allow Canfor Pulp to further optimize their pulp production capacity.
PSI team demonstrates direct hydrocarbon fuel production from water and CO2 by solar-driven thermochemical cycles
May 26, 2016
Solar-driven thermochemical cycles offer a direct means of storing solar energy in the chemical bonds of energy-rich molecules. By utilizing a redox material such as ceria (CeO2) as a reactive medium, STCs can produce hydrogen and carbon monoxide—i.e., syngas—from water and CO2. The syngas can subsequently be upgraded to hydrocarbon fuels by the Fischer-Tropsch process.
Now, a team from the Paul Scherrer Institute (PSI) in Switzerland has demonstrated the direct production of hydrocarbon fuel—specifically methane—from water and CO2 by incorporating a catalytic process into STCs. A paper on their work is published in the RSC journal Energy & Environmental Science.
ULEMCo delivers first hydrogen-diesel dual-fuel refuse trucks to Fife Council in Scotland
May 23, 2016
ULEMCo, the developer of a hydrogen-diesel dual fuel conversion system for commercial vehicles, has delivered its first hydrogen dual-fuel refuse vehicles to Fife Council in Scotland. The trucks, which deliver reduced CO2 emissions as well as improving air quality for the local community, are planned for use in densely populated urban areas, where improving air quality is a major concern.
The dual-fuel engines are equipped with hydrogen injection and a separate ECU control system. A diesel pilot injection initiates combustion of the hydrogen, which is stored onboard at 350 bar. CO2 emissions under dual fuel mode are approximately 70% less than a comparable diesel vehicle, according to the company.
JBEI, UCSD scientists develop systems biology-based workflow to improve biofuels productivity
May 21, 2016
Researchers at the US Department of Energy (DOE)’s Joint BioEnergy Institute (JBEI), in collaboration with researchers at the University of California, San Diego, have developed a workflow that integrates various “omics” data and genome-scale models to study the effects of biofuel production in a microbial host.
The development of omics technologies, such as metabolomics and proteomics, and systems biology have significantly enhanced the ability to understand biological phenomena. Nevertheless, the interpretation of large omics data into meaningful “knowledge” as well as the understanding of complex metabolic interactions in engineered microbes remains challenging. This new open-source workflow—which integrates various omics data and genome-scale models—drives the transition from vision to conception of a designed working phenotype.
Clariant to scale-up catalysts for Gevo’s Ethanol-to-Olefins (ETO) technology; renewable diesel and hydrogen
May 19, 2016
Gevo, Inc. has entered into an agreement with Clariant Corp., one of the world’s leading specialty chemical companies, to develop catalysts to enable Gevo’s Ethanol-to-Olefins (ETO) technology.
Gevo’s ETO technology, which uses ethanol as a feedstock, produces tailored mixes of propylene, isobutylene and hydrogen, which are valuable as standalone molecules, or as feedstocks to produce other products such as diesel fuel and commodity plastics, that would be drop-in replacements for their fossil-based equivalents. ETO is a chemical process, not a biological process as is Gevo’s conversion of biomass to isobutanol.
EPA proposes increase in renewable fuel levels for CY 2017
May 18, 2016
The US Environmental Protection Agency (EPA) proposed increases in renewable fuel volume requirements across all types of biofuels under the Renewable Fuel Standard (RFS) program.
The proposed volume requirements and associated percentage standards for are for calendar year 2017 for cellulosic biofuel, biomass-based diesel, advanced biofuel, and total renewable fuel. Total renewable fuel volumes would grow by some 690 million gallons between 2016 and 2017. EPA also proposed the volume requirement for biomass-based diesel for 2018.
California’s Low Carbon Fuel Standard compliance rate is 98%
The California Air Resources Board’s report on the state of the Low Carbon Fuel Standard (LCFS) program for the compliance year 2015 indicates a compliance rate of 98%, with a total of 5.49 million credits generated in the year. These credits are roughly the same as removing 1 million cars from the roads for a year in terms of preventing greenhouse gases from entering the atmosphere.
The 2015 annual reports demonstrate exceedingly high levels of overall compliance. Of the 52 entities who sell high carbon fuels, and have an obligation under the program, only a single company—Astra Oil Company LLC—ended the compliance period with a small shortfall of 337 credits and will be required to purchase the necessary credits from the LCFS Credit Clearance Market (CCM) between 1 June and 31 July 2016.
DOE awards up to $10M to 6 projects for non-food biomass and algal biofuels and biochemicals
May 16, 2016
The US Department of Energy is awarding up to $10 million in funding for six projects that will support the Bioenergy Technologies Office’s (BETO) work to develop renewable and cost-competitive biofuels and biochemicals from non-food biomass feedstocks by reducing the technical risk associated with potentially breakthrough approaches and technologies for investors.
The projects selected include the following:
California ARB staff releases first batch of recertified CI pathways for fuels under readopted LCFS using CA-GREET 2.0
May 10, 2016
The staff of the California Air Resources Board (ARB) released the first full set of carbon intensity (CI) pathways certified under the readopted LCFS regulation using the CA-GREET 2.0 model. (Earlier post.) These pathways include both new applications and requests to have “legacy” pathways (adopted under the prior LCFS rule) recertified.
The initial batch of released CIs contains only ethanol pathway; similar batches will be released for other fuel types in the future.
Argonne rolls out updated version of AFLEET alternative fuels and advanced vehicles analysis tool
The US Department of Energy (DOE’s) Argonne National Laboratory is releasing an updated version of its AFLEET tool to reflect the latest advances in alternative fuels and advanced vehicle technologies and updated emissions data. Sponsored by the DOE Clean Cities program, AFLEET (Alternative Fuel Life-Cycle Environmental and Economic Transportation Tool) is a free, publicly-available tool that provides users with a roadmap for assessing which types of vehicles and fuels are right for them. The 2016 AFLEET Tool and user guide are available online. Although anyone can download and use the tool, AFLEET was designed for managers that purchase and maintain a fleet of vehicles.
The latest version includes, for the first time: gaseous hydrogen fuel cell vehicles; state-based (rather than national-based) fuel pricing, private station fuel pricing and fueling infrastructure costs. Updates to existing inputs include new light-duty vehicle costs; vehicle air pollutant emission factors derived from the Environmental Protection Agency’s emissions modeling system, MOVES 2014a; and petroleum use and greenhouse gas and relative air pollutant emissions from the 2015 GREET model, Argonne’s leading fuel life-cycle analysis model that is now in its twentieth year.
DOE and USDA award $10M to advance biofuels, bioenergy, and biobased products
The U.S. Department of Agriculture (USDA)’s National Institute of Food and Agriculture (NIFA) and the Department of Energy (DOE) announced the joint investment of $10 million in seven projects towards research that will drive more efficient biofuels production and agricultural feedstock improvements. These awards were made through the Biomass Research and Development Initiative (BRDI), authorized by the 2014 Farm Bill
With up to $3 million in available funding, DOE has selected two projects: one from Ohio State University and one from Massachusetts Institute of Technology that will receive between $1 million to $2 million. The USDA is funding five projects for a total of $7.3 million, and selections include the University of California-Riverside; the University of Montana; Missoula; the North Carolina Biotechnology Center; the State University of New York; and Pennsylvania State University.
DOE to award up to $90M for integrated biorefinery projects
May 07, 2016
“Project Development for Pilot and Demonstration Scale Manufacturing of Biofuels, Bioproducts, and Biopower” is a funding opportunity that will support efforts to improve and demonstrate processes that break down complex biomass feedstocks and convert them to gasoline, diesel and jet fuel, as well as plastics and chemicals.
ANGP commercializes 1st ANSI NGV2-certified on-board low pressure ANG technology storage system for LDVs
May 04, 2016
Adsorbed Natural Gas Products, Inc. (ANGP) has successfully installed the industry’s first ANSI NGV2-certified adsorbed natural gas (ANG) active storage system. The system, which ANGP calls its first-generation (GEN 1) ANG System, comprises six activated carbon monolith-filled seamless aluminum cylinders, fully ANSI NGV2-certified for an operating pressure of 900 psig, and ANGP’s low-pressure fuel management system.
The first system was successfully installed on ANGP’s 2014 Ford F-150 pick-up truck equipped with Ford’s CNG/LPG-ready 3.7 liter V6 bi-fuel engine for gasoline or natural gas operation. The ANGP GEN 1 ANG system includes several industry firsts:
U Mich study explores performance of renewable diesel, FT diesel and ULSD in PCCI combustion
May 03, 2016
A team at the University of Michigan has investigated the performance of three different fuels—ultralow sulfur diesel (ULSD), diesel fuel produced via a low temperature Fischer–Tropsch process (LTFT), and a renewable diesel (RD), which is a hydrotreated camelina oil under partially premixed compression ignition (PCCI) combustion. Their paper is published in the ACS journal Energy & Fuels.
Partially premixed compression ignition (PCCI) combustion is an advanced, low-temperature combustion mode that creates a partially premixed charge inside the cylinder before ignition occurs. PCCI prolongs the time period for mixing of the fuel–air mixture by separating the end of injection and start of combustion. As a result, NOx and particulate matter (PM) emissions can be reduced simultaneously relative to those of conventional diesel combustion.
Roland Berger study outlines integrated vehicle and fuels roadmap for further abating transport GHG emissions 2030+ at lowest societal cost
April 30, 2016
A new study by consultancy Roland Berger defines an integrated roadmap for European road transport decarbonization to 2030 and beyond; the current regulatory framework for vehicle emissions, carbon intensity of fuels and use of renewable fuels covers only up to 2020/2021.
The study was commissioned by a coalition of fuel suppliers and automotive companies with a view to identifying a roadmap to 2030+ to identify GHG abatement options at the lowest cost to society. The coalition comprises BMW, Daimler, Honda, NEOT/St1, Neste, OMV, Shell, Toyota and Volkswagen. Among the key findings of the study were:
DOE and DOT collaborate to support smart transportation systems and alternative fuel technologies
The US Departments of Energy (DOE) and Transportation (DOT) announced a collaboration to accelerate research, development, demonstration, and deployment of innovative smart transportation systems and alternative fuel technologies.
The agencies formalized this collaborative relationship through a Memorandum of Understanding (MOU) that was unveiled at a symposium this week called Achieving Zero-Emission Mobility: The Role of Innovative Electric Vehicle Companies, hosted by the University of California Center on Economic Competitiveness in Transportation in Berkeley, California.
JBEI team engineers E. coli for one-pot production of bio-jet fuel precursor from ionic-liquid-pretreated biomass
April 13, 2016
A team led by researchers at the DOE’s Joint BioEnergy Institute (JBEI) in Emeryville, CA, has engineered E. coli bacteria for the one-pot production of the monoterpene bio-jet fuel precursor D-limonene from ionic-liquid-pretreated cellulose and switchgrass. A paper on their work is published in the RSC journal Green Chemistry.
The ionic liquid 1-ethyl-3-methylimidazolium acetate is highly effective in deconstructing lignocellulose, but leaves behind residual reagents that are toxic to standard saccharification enzymes and the microbial production host. The JBEI researchers discovered a strain of E. coli that is tolerant to that ionic liquid due to a specific mutation. They engineered this strain to express a D-limonene production pathway.
Texas A&M-led team identifies synthetic hydrocarbon pathway in green alga B. braunii
April 07, 2016
The green microalga Botryococcus braunii is considered a promising biofuel feedstock producer due to its prodigious accumulation of hydrocarbon oils that can be converted into fuels. Now, a team led by researchers from Texas A&M AgriLife Research has identified the first committed step in the biosynthesis of hydrocarbon oil in B. braunii and has described a new enzyme which carries out this reaction.
The study, published as an open-access paper in the current issue of the journal Nature Communications, could enable scientists to use the enzyme in a plant to make large amounts of fuel-grade oil, according to Dr. Tim Devarenne, AgriLife Research biochemist in College Station and lead scientist on the team.
EIA: trends in downsized engine design leading to increased demand for higher-octane gasoline
April 06, 2016
Since 2013, the share of premium gasoline in total motor gasoline sales in the US has steadily increased to 11.3% in August and September 2015—the highest share in more than a decade, according to data from the US Energy Information Administration (EIA).
This trend of increasing demand for higher octane gasoline is likely driven by changes in fuel requirements for light-duty vehicles (LDV) in response to increasing fuel economy standards, which will have widespread implications for future gasoline markets, according to EIA analysts.
U Copenhagen team discovers “reverse photosynthesis” process for the breakdown of biomass for fuels or chemicals production
April 04, 2016
Researchers at the University of Copenhagen have discovered a natural process for the breakdown of biomass they describe as “reverse photosynthesis”—as opposed to the building of biomass as is the case with photosynthesis. Combined with a specific enzyme, the energy of sunlight can break down plant biomass.
Oxidative processes are essential for the breakdown of plant biomass. Lytic polysaccharide monooxygenases (LPMOs)—a class of powerful and widely distributed oxidative enzymes—oxidize the most recalcitrant polysaccharides. These enzymes require extracellular electron donors. In their work, described in an open access paper in the journal Nature Communications, the University of Copenhagen team researchers investigated the effect of using excited photosynthetic pigments as electron donors.
ASTM ballot greenlights approval of ATJ-SPK biojet from alcohol; Gevo 1st commercial test flight with Alaska Airlines
March 29, 2016
Renewable isobutanol company Gevo announced that the ASTM International Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants and Subcommittee D02.J on Aviation Fuel passed a concurrent ballot this week approving the revision of ASTM D7566 (Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons) to include alcohol-to-jet synthetic paraffinic kerosene (ATJ-SPK) (the “D02.J Ballot”). (Earlier post.)
This approval prepares the way for the use of Gevo ATJ—as well as ATJ-SPK fuels produced by other manufacturers—in commercial operations. As previously announced, Alaska Airlines is now poised to fly the first commercial test flight using Gevo’s renewable ATJ-SPJ fuel. (Earlier post.) Gevo is preparing the shipment of ATJ to Alaska Airlines for this first flight. Alaska Airlines will work with the Federal Aviation Administration to schedule the flight using Gevo’s ATJ.
IIT team explores combustion, performance and emissions characteristics of HCNG blends in spark ignition engine
March 28, 2016
A new study by a team from the Engine Research Laboratory at the Indian Institute of Technology Kanpur explores the combustion, performance and emission characteristics of a prototype spark ignition engine operating with different blend ratios of HCNG (hydrogen and compressed natural gas blends). Their paper is published in the journal Fuel.
Use of lower carbon natural gas and carbon-free hydrogen have potential to reduce harmful emissions of criteria pollutants and greenhouse gas (GHG) emissions and and could displace a portion of conventional liquid fossil fuels, the IIT noted. However, both fuels pose different challenges for use in internal combustion (IC) engines.
Double catalyst for the direct conversion of syngas to lower olefins
March 21, 2016
The light olefins ethylene, propylene, and butylene—usually made from petroleum—are key building blocks for chemical industry, and are starting materials for making plastics, synthetic fibers, and coatings. In the journal Angewandte Chemie, Chinese scientists report on a new bifunctional catalyst that converts syngas to lower olefins (C2-C4) with high selectivity. This could make it more attractive to make olefins from alternative sources of carbon, such as biomass, natural gas, or coal.
The design of bifunctional catalysts could result in further breakthroughs in developing one-step processes for selective production of fuels and chemicals such as gasoline, diesel, and aromatics from synthesis gas.
NREL updates Survey of Advanced Biofuel Producers in the United States
March 17, 2016
The National Renewable Energy Laboratory (NREL) updated its annual survey of US non-starch ethanol and renewable hydrocarbon biofuels producers. The 2015 Survey of Non-Starch Ethanol and Renewable Hydrocarbon Biofuels Producers provides an inventory of the domestic advanced biofuels production industry as of the end of calendar year 2015, documenting important changes (e.g., biorefinery development, production capacity, feedstock use, and technology pathways) that have occurred since the publication of the original 2013 survey.
During 2015, NREL surveyed 114 companies that were reported to be pursuing commercial-scale biofuel production capacity. Companies were classified as either non-starch (cellulosic or algae-derived) ethanol producers or renewable hydrocarbon producers. The questionnaire included topics such as facility stage of development, facility scale, feedstock, and biofuel products. The NREL team supplemented missing survey data elements (when possible) with publicly available data obtained directly from company websites, press releases, and public filings.
MIT Energy Initiative report on transforming the US transportation system by 2050 to address climate challenges
March 16, 2016
A new MIT Energy Initiative report spearheaded by John Heywood, Sun Jae Professor of Mechanical Engineering Emeritus at MIT, identifies three important paths forward reducing light-duty vehicle energy use and greenhouse gas emissions: improve the existing system and technologies for shorter-term benefits; conserve fuel by changing driver habits for nearer- to longer-term benefits; and transform the transportation system into one that is radically less carbon-intensive for longer-term benefits.
According to the report, “On the Road Toward 2050: Potential for Substantial Reductions in Light-Duty Vehicle Energy Use and Greenhouse Gas Emissions,” each element is separately important, but must collectively be pursued aggressively to achieve necessary emissions reductions. More research, development, and demonstration studies are needed to lay the foundation for such a long-term transformation.
DOE seeking input on operation of integrated biorefineries
March 14, 2016
The US Department of Energy’s Office of Energy Efficiency and Renewable Energy’s (EERE’s) Bioenergy Technologies Office (BETO) is seeking (DE-FOA-0001481) input from industry, academia, research laboratories, government agencies, and other stakeholders that will help it better understand capabilities—as well as barriers and opportunities—for the operation of integrated biorefineries (IBRs) to produce biofuels, biochemicals, and bioproducts.
BETO is seeking information on all IBR processes and technologies, including any and all systems processes, technologies, methods and equipment employed to convert woody biomass, agricultural residues, dedicated energy crops, algae, municipal solid waste (MSW), sludge from wastewater treatment plants, and wet solids, into biofuels, biochemicals, and bioproducts.
United Airlines begins commercial-scale use of renewable jet fuel; 15M gallons over 3-year period
March 12, 2016
United Airlines has become the first US airline to begin use of commercial-scale volumes of sustainable aviation biofuel for regularly scheduled flights, beginning with the departure of United Flight 708 from Los Angeles International Airport (LAX). The launch marks a milestone in the commercial aviation industry by moving beyond demonstration flights and test programs to the use of advanced biofuels for United’s ongoing revenue operations.
United has agreed to purchase up to 15 million gallons of sustainable biofuel from AltAir Paramount over a three-year period. The biofuel will be mixed with traditional jet fuel at a 30/70 blend ratio: 30% biofuel, 70% traditional fuel. The airline has begun using the biofuel in its daily operations at LAX, storing and delivering it in the same way as traditional fuel.
DOE selects 33 clean energy businesses for nearly $6.7M in support under Small Business Vouchers pilot
March 11, 2016
The US Department of Energy (DOE) selected 33 small businesses to work directly with DOE national labs to accelerate the commercialization of new clean energy technologies.
The department’s Office of Energy Efficiency and Renewable Energy is investing nearly $6.7 million under Round 1 of the new Small Business Vouchers (SBV) pilot. For Round 1, the small businesses and laboratories will collaborate on advancing a number of clean energy technologies, including water, wind, bioenergy, solar, buildings, vehicles, fuel cells, geothermal technologies, and advanced manufacturing. The selected small businesses will work with scientists at nine department laboratories: Oak Ridge National Laboratory (ORNL); National Renewable Energy Laboratory (NREL); Lawrence Berkeley National Laboratory (LBNL); Sandia National Laboratories (SNL); Pacific Northwest National Laboratory (PNNL); Idaho National Laboratory (INL); Los Alamos National Laboratory (LANL); Argonne National Laboratory (ANL); and Lawrence Livermore National Laboratory (LLNL).
Government of Alberta awarding $10M to SBI Bioenergy for production of drop-in hydrocarbon fuels; funds from carbon levy
March 10, 2016
Using revenue from the price Alberta’s large emitters pay for releasing greenhouse gases, the Climate Change and Emissions Management Corporation (CCEMC) has earmarked a $10-million contribution for Alberta-based SBI BioEnergy to support a $20-million facility for the demonstration-scale production of drop-in, renewable diesel, jet and gasoline fuels from plant oils and waste fats.
With this investment, SBI will be able to produce 10 million liters (2.6 million gallons US) of renewable diesel fuel annually. This support works in concert with Alberta’s Renewable Fuels Standard which requires commercial fuel producers to blend renewable products into their fuels. SBI’s facility strengthens Alberta’s expanding industrial bio-product sector and gives Alberta farmers a new market for off-grade canola.
Argonne and Marathon partner in DOE Optima initiative to co-optimize fuels and engines
The US Department of Energy’s (DOE) Argonne National Laboratory is partnering with Marathon Petroleum Corporation (MPC) to support an ongoing effort by DOE to explore fuels and engines holistically in search of greater efficiency.
The collaboration between Argonne and MPC is designed to support the “Co-Optimization of Fuels and Engines” initiative, which was recently launched jointly by the DOE’s Vehicle Technologies Office and Bioenergy Technologies Office. (Earlier post.) The new collaboration leverages MPC’s and Argonne’s complementary capabilities in fuel design, analysis and production, as well as advanced engine combustion and emissions formation.
Stanford team devises new bio-inspired strategy for using CO2 to produce multi-carbon compounds such as plastics and fuels
Researchers at Stanford University have devised a new strategy for using CO2 in the synthesis of multi-carbon compounds. They first have applied their technology to the production of a plastic—a promising alternative to polyethylene terephthalate (PET) called polyethylene furandicarboxylate (PEF)—but are now working to apply the new chemistry to the production of renewable fuels and other compounds from hydrogen and CO2.
Matthew Kanan, an assistant professor of chemistry at Stanford, and his Stanford colleagues described the process and their results in synthesizing PEF in a paper in the journal Nature.
Argonne LCA study finds many alternative fuels consume more water than petroleum and natural gas fuels
March 09, 2016
Researchers at Argonne National Laboratory have analyzed the water consumption for transportation fuels in the United States using an extended lifecycle system boundary that includes the water embedded in intermediate processing steps.
In a paper published in the RSC journal Energy & Environmental Science, they compared the water consumed per unit energy and per km traveled in light-duty vehicles. They found that many alternative fuels consume larger quantities of water on a per km basis than traditional petroleum and natural gas pathways. The authors concluded that it will be important to consider the implications of transportation and energy policy changes on water resources in the future.
Rice study finds using natural gas for electricity and heating, not transportation, more effective in reducing GHGs
Rice University researchers have determined a more effective way to use natural gas to reduce climate-warming emissions would be in the replacement of existing coal-fired power plants and fuel-oil furnaces rather than burning it in cars and buses.
The Rice study by environmental engineer Daniel Cohan and alumnus Shayak Sengupta compared the net greenhouse gas-emission savings that could be realized by replacing other fuels in vehicles, furnaces and power plants. They found that gas-fired power plants achieved the greatest reduction—more than 50%—in net emissions when replacing old coal-fired power plants. The use of compressed natural gas in vehicles yielded the least benefit, essentially matching the emissions of modern gasoline or diesel engines.
New highly selective catalytic process for conversion of vegetable oils to diesel-range alkanes under mild conditions
March 08, 2016
A team led by researchers from the University of Oxford has developed a simple but highly selective catalytic process for the direct hydrodeoxygenation of vegetable oils (triglycerides) into diesel-range alkanes under mild conditions over a Pd/NbOPO4 catalyst. As reported in their paper in the RSC journal Chemical Communications The mass yields of diesel-range alkanes from palm oil and soybean oil can approach to quantitative values.
A number of approaches are being developed and commercialized to convert vegetable oils into diesel fuels. The current primary commercial pathway is the production of first-generation biodiesel—the transesterification of triglycerides with methanol to form fatty acid methyl ester (FAME), with glycerol as the by-product.
Tohoku researchers develop efficient hydrodynamic reactor for pretreatment of biomass
March 07, 2016
Researchers at Tohoku University in Japan have developed a new system combining hydrodynamic cavitation with sodium percarbonate (SP) (an environmentally benign oxidation reagent) for the efficient pre-treatment of biomass. Compared to a pretreatment system using ultrasonication and SP (US-SP), the new HD-SP system was more efficient for glucose and xylose production; both systems resulted in a similar degree of lignin removal, and neither generated the inhibitor furfural, while it was detected in dilute acid (DA)-pretreated biomass.
In a paper published in the ACS journal Industrial & Engineering Chemistry Research, the Tohoku team sugested that the HD-SP system could be easily scaled up for a high-throughput system. Because compared to an US cavitation reactor it requires much lower energy input, it is promising for the industrial-scale pretreatment of lignocellulosic biomass, they said.
Audi expanding e-gas capacity through partnership with Viessmann; power-to-gas with biological methanation of CO2 and H2
February 29, 2016
Audi is expanding capacities for the production of sustainably produced e-gas. (Earlier post.) The Viessmann Group is Audi’s first partner company to produce additional quantities of the synthetic fuel using a new biological methanation process. The pilot plant in Allendorf, Germany officially opened today.
Audi e-gas is currently produced using two process steps: electrolysis and methanation. In the first step, renewably generated electricity is used to split water into hydrogen and oxygen. In the second step, the hydrogen is reacted with CO2 to yield synthetic methane. In the Audi e-gas plant in Werlte in the German state of Lower Saxony, this is done using a chemical-catalytic process under high pressure and high temperature.
Berkeley Lab researchers devise new technique to reduce lignin and increase sugar yields; lowering biomass pretreatment costs
February 25, 2016
Scientists from the US Department of Energy’s Lawrence Berkeley National Laboratory (Berkeley Lab) and Joint BioEnergy Institute have devised a new strategy for reducing lignin in plants by modifying a key metabolic entrypoint for the synthesis of the most important lignin monomers.
The new technique, reported in an open-access paper in the journal Plant & Cell Physiology, could help lower the cost of converting biomass into lower carbon biofuels and bio-products.
New ammonia biomass pretreatment process improves yield with lower enzyme loading; improving cellulosic biofuel economics
February 23, 2016
A team from the US, China and India, led by researchers from Michigan State University, has developed a new liquid ammonia biomass pretreatment methodology called Extractive Ammonia (EA). EA-pretreated corn stover delivers a higher fermentable sugar yield compared to the older Ammonia Fiber Expansion (AFEX) process while using 60% lower enzyme loading.
As described in a paper in the RSC journal Energy & Environmental Science, the single-stage EA process achieves high biofuel yields (18.2 kg ethanol per 100 kg untreated corn stover, dry weight basis), comparable to those achieved using ionic liquid pretreatments. The EA process achieves these ethanol yields at industrially-relevant conditions using low enzyme loading (7.5 mg protein per g glucan) and high solids loading (8% glucan, w/v).
UTA researchers demonstrate one-step solar process to convert CO2 and H2O directly into renewable liquid hydrocarbon fuels
Researchers at the University of Texas at Arlington have demonstrated a new solar process for the one-step, gas-phase conversion of CO2 and H2O to C5+ liquid hydrocarbons and O2 by operating the photocatalytic reaction at elevated temperatures and pressures.
The photothermocatalytic process for the synthesis of hydrocarbons—including liquid alkanes, aromatics, and oxygenates, with carbon numbers (Cn) up to C13—ran in a flow photoreactor operating at elevated temperatures (180–200 °C) and pressures (1–6 bar) using a 5% cobalt on TiO2 catalyst and under UV irradiation. A paper describing the process is published in Proceedings of the National Academy of Sciences (PNAS).
Mercedes-Benz Trucks approves HVO renewable diesel for its medium- and heavy-duty engines; neat or blended
February 22, 2016
With immediate effect, Mercedes-Benz Trucks is granting approval for the use of Hydrotreated Vegetable Oil (HVO) renewable diesel for the in-line six-cylinder engine variants of the Mercedes-Benz OM 470, OM 471 (first generation) and OM 936 as well as the in-line four-cylinder variants of the OM 934 meeting the Euro VI emissions standard. The engines are designed as standard to make use of the new HVO fuel. The approval applies to all engine variants whatever their output category.
HVO is a renewable diesel produced from waste materials such as waste fat, used cooking oil and also oil from crop plants. The HVO raw material is sourced from controlled and certified cultivation facilities and as such does not compete with foodstuff production. A leading example is Neste’s NEXBTL.
Diesel/2-methylfuran blends show higher brake thermal efficiency, higher NOx than diesel
Researchers at Wuhan University report on the first comprehensive study of the combustion and emissions performance of blends of diesel and the renewable fuel 2-methylfuran (MF) in compression-ignition engines. Their paper is published in the journal Fuel.
Among their findings were that diesel–MF blends show higher brake thermal efficiency (BTE) than pure diesel. However, diesel–MF blends also lead to higher NOx emissions than pure diesel and the NOx emissions are increased with the increase of MF fraction.
Newly identified enzymes from herbivore gut fungi may lead to cheaper cellulosic biofuels
February 19, 2016
A team of researchers led by Dr. Michelle O’Malley at UC Santa Barbara has identified several promising new enzyme candidates for breaking down lignocellulsoic biomass for biofuel production from relatively unexplored gut fungi in herbivores. To do so, they developed a systems-level approach that integrates transcriptomic sequencing (RNA-Seq); proteomics; phenotype; and biochemical studies.
The biomass-degrading enzymes from the anaerobic gut fungi are competitive with optimized commercial enzyme preparations from Aspergillus and Trichoderma. Further, compared to the model platforms, the gut fungal enzymes are unbiased in substrate preference due to a wealth of xylan-degrading enzymes. The findings suggest that industry could modify the gut fungi so that they produce improved enzymes that will outperform the best available ones, potentially leading to cheaper biofuels and bio-based products. A paper on their work is published in the journal Science.
UI, ExxonMobil study finds where bioenergy crops would grow best while minimizing detrimental effects on aquatic ecosystems
February 18, 2016
A team from the University of Illinois, Urbana and ExxonMobil Research and Engineering Company (EMRE) has identified regions in the United States where bioenergy crops would grow best while minimizing effects on water quantity and quality. Their paper is published in the ACS journal Environmental Science & Technology.
The researchers applied a land surface model to evaluate the interplay between potential bioenergy grass (Miscanthus, Cave-in-Rock, and Alamo) production, water quantity, and nitrogen leaching (NL) in the Central and Eastern USA. The detailed models explored the impacts on water quantity and quality in soils that would occur if existing vegetation was replaced by various bioenergy crops used for ethanol production.
Oak Ridge researchers tap Titan supercomputer for two lignin-related projects; improving knowledge and processes for cellulosic biofuels
February 17, 2016
In nature, the resilient lignin polymer helps provide the scaffolding for plants, reinforcing slender cellulosic fibers—the primary raw ingredient of cellulosic ethanol—and serving as a protective barrier against disease and predators. Lignin’s protective characteristics persist during biofuel processing, where it becomes a major hindrance, surviving expensive pretreatments designed to remove it and blocking enzymes from breaking down cellulose into simple sugars for fermentation into bioethanol.
Oak Ridge National Laboratory (ORNL) researchers have recently tapped into the power of the Titan supercomputer there (earlier post) in two separate lignin-related investigations, both intended to benefit the production of cellulosic biofuels. One was an investigation into the basic mechanisms of lignin inhibition; the other an investigation into an experimental pretreatment.
Germany launches new study of oxymethylene ethers for optimizing clean diesel combustion
February 15, 2016
The German Federal Ministry of Food and Agriculture (BMEL) via FNR (Fachagentur Nachwachsende Rohstoffe e.V.), BMEL’s central project-coordinating agency in the area of renewable resources, is funding a 3-year study of oxymethylene ethers (OME) as clean diesel fuels with €800,000 (US$894,000).
Oxymethylene ethers (OME) are synthetic compounds of carbon, oxygen, and hydrogen (CH3O(CH2O)nCH3). Due to their high oxygen concentration, they suppress pollutant formation in combustion. As diesel fuels, they reduce the emission of carbon black and NOx. Ford is currently leading a €3.5-million (US$3.9-million) research project, co-funded with the German government, to test cars running on monooxymethylene ether (OME1) and DME. (Earlier post.)
Wisconsin, GLBRC researchers use chemical genomics to engineer IL-resistant yeast to improve biofuel production
February 14, 2016
Researchers at the University of Wisconsin-Madison and the Great Lakes Bioenergy Research Center (GLBRC) and colleagues have engineered a new strain of the yeast S. cerevisiae that is more resistant to the toxic effects of ionic liquids (ILs) used to generate sugars from lignocellulose.
As a result, their xylose-converting strain consumed glucose and xylose faster and produced more ethanol than the wild type strain. The development could improve the efficiency of making fuel from cellulosic biomass such as switchgrass. The work is reported in an open-access paper in the journal Microbial Cell Factories.
DOE to award up to $11.3M for biomass-to-hydrocarbon biofuels pathways; MEGA-BIO
February 09, 2016
The US Department of Energy (DOE) will provide up to $11.3 million in funding to develop flexible biomass-to-hydrocarbon biofuels conversion pathways that can be modified to produce advanced fuels and/or products based on external factors, such as market demand. (DE-FOA-0001433: MEGA-BIO: Bioproducts To Enable Biofuels.)
These pathways can consist of a route to a platform chemical that could be converted to products or renewable hydrocarbon fuels or a route that co-produces chemicals and renewable hydrocarbon fuels.
NREL and BESC discovery explains higher biomass degrading activity of C. thermocellum; potential boon for cellulosic biofuels
February 06, 2016
Researchers at the Energy Department’s National Renewable Energy Laboratory (NREL) and the BioEnergy Science Center (BESC) have discovered a new cell-free cellulosomal system in Clostridium thermocellum—the most efficient single biomass degrader characterized to date —that is not tethered to the bacterial cell wall and is independent of the primary (tethered) cellulosomes.
Their discovery was made during an investigation into the performance of C. thermocellum. The scientists found the microorganism utilizes the common cellulase degradation mechanisms known today (free enzymes and scaffolded enzymes—i.e., a structured architecture of enzymes—attached to the cell), and a new category of scaffolded enzymes not attached to the cell. Reported in an open-access paper in Science Advances, the finding could lead to cheaper production of cellulosic ethanol and other advanced biofuels.
Bio-isobutanol company Gevo signs licensing and joint development agreements with Porta in Argentina; corn feedstock
February 03, 2016
Gevo, Inc. has entered into a license agreement and a joint development agreement with Porta Hnos S.A. to construct multiple isobutanol plants in Argentina using corn as a feedstock.
The first plant is to be wholly owned by Porta and is anticipated to begin producing isobutanol in 2017. The plant is expected to have a production capacity of up to five million gallons of isobutanol per year. Based on projected isobutanol pricing, Gevo estimates that it could generate approximately $1 million in annual revenues once the plant is operational, through royalties, sales and marketing fees, and other revenue streams such as yeast sales.
IMP develops new material to remove nitrogen compounds from crude oil for more efficient desulfurization
The Mexican Oil Institute (IMP) has developed a catalyst adsorbent material that removes 80% of organic compounds from crude oil prior to hydrodesulfurization. It allows Pemex, the Mexican oil company, to generate ultra-low sulfur diesel (ULSD) more quickly and cheaply. Dr. Rodolfo Mora, head of the project, said that the research was initiated by Pemex’ need to convert its diesel from 500 parts per million (ppm) of sulfur to 15 ppm ULSD.
Its use in a preliminary process will increase the life of the catalyst for up to 30 months over current standards by avoiding high temperatures and pressures during operation in the reactor.
Primus Green Energy produces 100-octane gasoline at commercial demonstration gas-to-liquids plant; improvement to STG+ technology
February 02, 2016
Primus Green Energy Inc., a gas-to-liquids (GTL) technology and solutions company that transforms methane and other hydrocarbon gases into gasoline and methanol (earlier post), has successfully produced 100-octane gasoline at its commercial demonstration plant in Hillsborough, New Jersey.
Primus achieved this milestone as a result of an improvement to its proprietary STG+ technology—itself essentially an improvement upon commercial methanol synthesis processes and ExxonMobil’s methanol-to-gasoline (MTG) process—which allows its plant to produce high-octane gasoline in addition to RBOB (“Reformulated Gasoline Blendstock for Oxygenate Blending”) gasoline and methanol.
UCR team advances direct production of chemical and fuel precursors in yeast
January 28, 2016
A team led by a researcher at the University of California, Riverside has adapted the CRISPR-Cas9 gene editing system for use in a yeast strain that can produce useful lipids and polymers. The development will lead to new precursors for biofuels, specialty polymers, adhesives and fragrances.
Published recently in an open-access paper in the journal ACS Synthetic Biology, the research involves the oleaginous (oil-producing) yeast Yarrowia lipolytica, which is known for converting sugars to lipids and hydrocarbons that are difficult to make synthetically. Until now, Y. lipolytica has been hard to manipulate at the genetic level, but the application of CRISPR-Cas9 will change that, allowing scientists to tap into its bio-manufacturing potential.
ExxonMobil projects 25% energy demand increase between 2014-2040, 50% decline in carbon intensity; hybrids to be 40% of new car sales
January 25, 2016
Global energy demand will increase 25% between 2014 and 2040, driven by population growth and economic expansion, ExxonMobil forecasts in the 2016 edition of its annual The Outlook for Energy. At the same time, energy efficiency gains and increased use of renewable energy sources and lower carbon fuels, such as natural gas, are expected to help reduce by half the carbon intensity of the global economy.
During the period, the world’s population will increase by about 2 billion people and emerging economies will continue to expand significantly, according to the forecast. Most growth in energy demand will occur in developing nations that are not part of the Organization for Economic Co-operation and Development (OECD). Per capita income in those countries is likely to increase by 135%.
Researchers find some solid-state hydrogen storage materials could serve as less toxic solid propellants for rockets
Researchers in China have found that amine metal borohydride—a novel hydrogen-enriched boron–nitrogen–hydrogen (BNH) hydrogen storage system—has potential as a solid propellant or additive for solid and hybrid rockets.
In a paper in the ACS journal Energy & Fuels, they investigated the combustion properties of two newly developed ethylene diamine aluminum borohydrides (Al(BH4)3·nEDA, n = 3, 2). They found the materials have high combustion heat of 32.20 and 36.90 MJ/kg for Al(BH4)3·3EDA and Al(BH4)3·2EDA, respectively, with ignition delay times of ∼2.0 ms.
Oslo Airport first to supply Air BP renewable biojet via main fuel hydrant system; initial batch from Neste
January 23, 2016
In a first for commercial aviation, Air BP, together with Norwegian airport operator Avinor, and sustainable biofuel specialist SkyNRG, announced that all airlines landing at Oslo Airport can have jet biofuel delivered from the airport’s main fuel farm, via the existing hydrant mechanism.
Lufthansa Group was the first airline to confirm that it will uplift the Air BP aviation biofuel at Oslo, and began by refueling an Airbus A320 aircraft. Further airlines including Scandinavian national carrier SAS and KLM Royal Dutch Airlines confirmed they will also purchase jet biofuel at Oslo.
Tesoro to support development of renewable biocrude for its refineries; Fulcrum, Virent, Ensyn partners
January 22, 2016
Tesoro Corporation plans to foster the development of biocrude, made from renewable biomass, which can be co-processed in its existing refineries along with conventional fossil crude oil to produce lower-carbon drop-in fuels.
Tesoro expects that converting renewable biomass into biocrude will enable existing refining assets to produce fuels with lower carbon intensities (CIs) at a significantly lower capital and operating cost than competing technologies. This could lower Tesoro’s compliance costs with the federal renewable fuel standard (RFS) and California’s low carbon fuel standard (LCFS) by generating credits, while producing fuels fully compatible with the nation’s existing fuel infrastructure as well as current vehicle fleet warranties.
DOE announces $58M in funding for advanced vehicle technologies
January 21, 2016
US Energy Secretary Ernest Moniz used the Washington DC Auto show as the venue to announce $58 million in funding for vehicle technology advancements. (Earlier post.) (DE-FOA-0001384: Fiscal Year (FY) 2016 Vehicle Technologies Program Wide Funding Opportunity Announcement) DOE also released a report highlighting the successes of itsAdvanced Technology Vehicles Manufacturing (ATVM) loan program.
Pre-announced in December, a $55-million funding opportunity will solicit projects across vehicle technologies such as energy storage, electric drive systems, materials, fuels and lubricants and advanced combustion. Secretary Moniz also announced that two innovative projects at CALSTART and the National Association of Regional Councils will receive $3 million to develop systems that help companies combine their purchasing of advanced vehicles, components, and infrastructure to reduce incremental cost and achieve economies of scale.
BESC study finds unconventional bacteria could boost efficiency of cellulosic biofuel production
January 14, 2016
A new comparative study by researchers at the Department of Energy’s BioEnergy Science Center (BESC), based at Oak Ridge National Laboratory, finds the natural abilities of unconventional bacteria could help boost the efficiency of cellulosic biofuel production.
A team of researchers from five institutions analyzed the ability of six microorganisms to solubilize potential bioenergy feedstocks such as switchgrass that have evolved strong defenses against biological and chemical attack. Solubilization prepares the plant feedstocks for subsequent fermentation and, ultimately, use as fuel.
New one-pot high-yield “high-gravity” process for cellulosic ethanol; potential for drop-in fuels
Researchers with the US Department of Energy (DOE)’s Joint BioEnergy Institute (JBEI) have developed a “high-gravity” one-pot process for producing ethanol from cellulosic biomass that gives unprecedented yields while minimizing water use and waste disposal. “High gravity” means high biomass loading—the higher the biomass loading, the lower the costs for converting it to fuels.
The process utilizes a combination of ionic liquid pretreatment, enzymatic saccharification, and yeast fermentation for the production of concentrated fermentable sugars that result in high-titer cellulosic ethanol. Details on this one-pot process for producing ethanol from cellulosic biomass have been reported in the RSC journal Energy and Environmental Science.
Global Bioenergies and Lanzatech strengthen cooperation to broaden feedstock flexibility of renewable isobutene process
January 11, 2016
Global Bioenergies and LanzaTech have signed a new collaboration agreement to broaden the feedstock flexibility of Global Bioenergies’ renewable isobutene process and the product-portfolio of LanzaTech’s carbon capture technology. (Earlier post.)
Global Bioenergies has developed a process in which a microorganism can produce isobutene from renewable feedstock via the fermentation of sugars. Whereas the company’s primary focus has historically been to use industrial-grade or waste-derived sugars as feedstocks, the technological maturity of the process now allows consideration of a broader range of feedstocks, including non-biomass-derived sources of carbon.
ECS and Toyota request proposals for 2016-2017 ECS Toyota Young Investigator Fellowship for projects in green energy technology
January 07, 2016
The Electrochemical Society (ECS), in partnership with the Toyota Research Institute of North American (TRINA), a division of Toyota Motor Engineering & Manufacturing North America, Inc. (TEMA), is requesting proposals from young professors and scholars pursuing innovative electrochemical research in green energy technology.
The purpose of the annual ECS Toyota Young Investigator Fellowship, established in 2014, is to encourage young professors and scholars to pursue research in green energy technology that may promote the development of next-generation vehicles capable of utilizing alternative fuels.
Testing shows Virent SAK bio-jet provides more than 50% reduction in PM emissions while maintaining engine performance
Bio-jet emissions testing by Rolls-Royce, supported by the Federal Aviation Administration (FAA) under the Continuous Lower Energy, Emissions, and Noise (CLEEN) program, has confirmed that jet fuels containing Virent’s BioForm Synthesized Aromatic Kerosene (SAK) fuel blend produced a greater than 50% reduction in particulate matter emissions compared to conventional jet fuel.
The testing thus verified the potential for the SAK fuel to reduce the adverse environmental impact and health effects resulting from jet fuel combustion. The emissions data and other successfully completed test results have been summarized in a report released by Rolls-Royce, British Airways, and the FAA.
Global Bioenergies widens cooperation with Audi; new agreement to broaden feedstocks for bio-isobutene to isooctane process
January 04, 2016
Global Bioenergies and Audi have signed a new collaboration agreement (earlier post) to further broaden the feedstock flexibility of Global Bioenergies’ bio-isobutene process, which uses fermentation of sugars.
The two companies last year announced the delivery by Global Bioenergies to Audi of a first batch of bio-isobutene-derived iso-octane, a premium drop-in fuel for gasoline engines. (Earlier post.) Global Bioenergies had produced isobutene using its pilot plant located on the agri-business site of Pomacle, France. The isobutene was then shipped to Germany and converted into isooctane.
Fulcrum BioEnergy files LCFS application for municipal solid waste to FT diesel pathway with low CI of 37.47 g/MJ
January 03, 2016
Fulcrum BioEnergy, the parent company of Fulcrum Sierra BioFuels, has applied for a new fuel pathway under the California Low Carbon Fuel Standard (LCSF) for its process of converting municipal solid waste (MSW) into Fischer-Tropsch (“FT”) diesel fuel.
The California LCFS mandates a 10% reduction by 2020 in the carbon intensity (CI) of transportation fuels. The program requires that transportation fuels used in California meet a baseline target for carbon intensity which is reduced each year. For 2016, the target for diesel and diesel substitutes is 99.97 gCO2e/MJ (Earlier post.) Fulcrum is requesting a CI of 37.47 g/MJ for its MSW-to-FT diesel.
Large-scale reaction screening study of advanced cellulosic biofuel pathways finds ethyllevulinate and 2-MTHF promising alternatives to ethanol
December 30, 2015
A team at RWTH Aachen University has identified ethyllevulinate and 2-methyltetrahydrofuran as promising alternatives to cellulosic bioethanol with respect to cost and environmental impact based on a large-scale reaction screening study.
In addition, the study of 97 reactions for 23 advanced biofuel candidates found that lignin-based biofuels can be excluded from further consideration and that methane, while attractive economically, shows significant environmental impact. The paper on their work is published in the ACS journal Energy & Fuels.
New HPAC lignocellulose pretreatment method could accelerate cellulosic biofuel production
December 28, 2015
A team from Chonnam National University in Korea has developed a new pretreatment method for lignocellulosic biomass that is more efficient and effective for the downstream biocatalytic hydrolysis of various lignocellulosic materials. This, they suggest, will accelerate bioethanol commercialization.
The new hydrogen peroxide (H2O2)-acetic acid (CH3COOH) (HPAC) pretreatment removes lignin without the use of high temperatures or strong acids. It can be applied to multiple lignocellulosic materials; reduces enzyme loading and downstream enzymatic hydrolysis time; and lowers generation of fermentation inhibitors during the process. An open-access paper on the process is published in the journal Biotechnology for Biofuels.
Study shows branched ketone biofuels derived from alcohols have potential for use in aviation fuel blends
December 25, 2015
Researchers at the University of Bath (UK) have demonstrated that branched ketone biofuels produced from the alkylation of isoamyl alcohol and isobutanol with acetone have the potential to be used as blending agents with Jet A-1 fuel. A paper on their work is published in the ACS journal Energy & Fuels.
Although the technology to produce cellulosic ethanol is becoming established, ethanol’s low energy density and high affinity for water have led to the development of higher energy density alochol alternatives such as n-butanol, isoamyl alcohol, and isobutanol. However, the water affinity, low flash point, and low boiling point still make these compounds unsuitable for aviation use without further upgrading.
Bauhaus Luftfahrt analysis finds solar thermochemical jet fuel production viable only if CO2 captured from renewable sources and not flue gases
December 23, 2015
A team from Bauhaus Luftfahrt in Germany has analyzed the climate impact and economic performance of solar thermochemical jet fuel production. According to their analysis, published in the ACS journal Environmental Science & Technology, favorable assumptions for all involved process steps (30% thermochemical energy conversion efficiency; 3000 kWh/(m2 a) solar irradiation, low CO2 and heliostat costs) result in jet fuel production costs of €1.28/L (US$5.30/gallon) at lifecycle (LC) GHG emissions close to zero (0.10 kgCO2‐equiv/L.
The non-profit Bauhaus Luftfahrt is an internationally-oriented think tank created in November 2005 by the three aerospace companies EADS (today Airbus Group); Liebherr-Aerospace; and MTU Aero Engines as well as the Bavarian Ministry for Economic Affairs. In January 2012, IABG-Industrieanlagen-Betriebsgesellschaft became the latest member of the institution.
$3M UK project to develop low-carbon aviation fuels from captured CO2 and waste biomass
December 22, 2015
Heriot-Watt University in the UK will lead a £2-million (US$3-million) project (EP/N009924/1) to develop low-carbon aviation fuels from captured CO2 and waste biomass. The multi-disciplinary project, funded by the Engineering and Physical Sciences Research Council (EPSRC) will be led by Heriot-Watt engineers and scientists in conjunction with teams from Aston and Oxford Universities and the University of Edinburgh.
The project aims to produce low-carbon synthetic aviation jet fuel using renewable energy from waste agricultural and forestry biomass and captured CO2. The project team will use integrated chemistry (a bottom-up method to develop novel catalysts and electrodes) and engineering (a top-down method to tailor heat and mass transport parameters influencing reaction conditions) with a focus on high selective and efficient jet fuel production.
ExxonMobil, UW-Madison partner on biomass-to-transportation fuel research
December 19, 2015
The University of Wisconsin-Madison and ExxonMobil announced a two-year agreement to research the fundamental chemistry of converting biomass into transportation fuels.
UW-Madison long has been known for its expertise in biomass conversion, and the project leverages the university’s expertise alongside the resources and technology development of ExxonMobil. George Huber, the Harvey D. Spangler professor of chemical and biological engineering at UW-Madison, is working closely with ExxonMobil scientists to build a stronger understanding of the basic chemical transformations that occur during biomass conversion into diesel and jet fuels.
Port of Seattle partners with Alaska Airlines and Boeing to supply sustainable aviation biofuel at Sea-Tac Airport
December 18, 2015
The Port of Seattle, Alaska Airlines and Boeing are partnering to move toward powering all flights by all airlines at Seattle-Tacoma International Airport with sustainable aviation biofuel. Sea-Tac is the first US airport to lay out a long-term roadmap to incorporate aviation biofuel into its infrastructure in a cost-effective, efficient manner.
At the Sea-Tac fuel farm earlier this week, executives for the port, Alaska Airlines, and Boeing signed a Memorandum of Understanding (MOU) to launch a $250,000 Biofuel Infrastructure Feasibility Study that will assess costs and infrastructure necessary to deliver a blend of aviation biofuel and conventional jet fuel to aircraft at Sea-Tac.
Hydrogen from biomethane; gasoline & diesel from tree residue; cellulosic ethanol among new proposed California LCFS fuel pathways
California Air Resources Board (ARB) staff posted 32 new Low Carbon Fuel Standard (LCFS) fuel pathway applications for comments at the LCFS website. Among the multiple applications for different processing pathways of corn or sorghum ethanol are four pathways from LytEn for hydrogen produced from biomethane; four pathways for renewable gasoline and diesel produced from tree residue from Ensyn; and one application for cellulosic ethanol using corn stover feedstock from POET.
The LCFS is a regulation to reduce the carbon intensity (CI) of fuels sold in California by 10% by 2020. The LCFS applies to liquid and non-liquid fuels. If a product is above the annual carbon intensity target, the fuel incurs deficits. If a product is below that target, the fuel generates credits which may be used later for compliance, or sold to other producers who have deficits. So far, fuel producers are over-complying with the regulation. (Earlier post.)
DOE BETO seeking input on Optima initiative for co-optimization of fuels and engines
December 17, 2015
The US Department of Energy, Office of Energy Efficiency and Renewable Energy’s (EERE) Bioenergy Technologies Office (BETO) and Vehicle Technologies Office (VTO) have released a request for information (RFI) (DE-FOA-0001460) titled “Co-Optimization of Fuels and Engines” (Optima).
The Optima program is a key collaborative initiative being pursued by EERE, VTO, and BETO. The Optima initiative is focused on the development of new fuels and engine architectures that are co-optimized—i.e., designed in tandem to maximize performance and carbon efficiency. (Earlier post.) The initiative intends to accelerate the widespread deployment of significantly improved fuels and vehicles (passenger to light truck to heavy duty commercial vehicles) by 2030. Specifically, Optima is targeting a reduction in per-vehicle petroleum consumption by 30% versus the 2030 business as usual.
HeidelbergCement and Joule partnering to explore carbon-neutral fuel application in cement manufacturing
December 14, 2015
Joule, a pioneer in the production of liquid fuels from recycled CO2, and HeidelbergCement, a German multinational building material company, are partnering to explore application of Joule’s technology to mitigate carbon emissions in cement manufacturing. Cement manufacturing is highly energy and emissions intensive, currently contributing about 6% of global CO2 (Zhang et al. 2014).
As part of the agreement, emissions (or offtake gas) from various HeidelbergCement factories could provide Joule with the waste CO2 required to feed its advanced Helioculture platform that effectively recycles CO2 back into fuel.
IH2 biomass to drop-in fuels technology demonstration plant to be built in India
December 13, 2015
Shell India Markets Pvt Ltd (SIMPL) will proceed with the installation of a 5 tonne/day IH2 technology demonstration plant on the site of SIMPL’s new Technology Centre in Bangalore, India. SIMPL will build, operate and own the demonstration scale IH2 plant. IH2 technology is a continuous catalytic thermo-chemical process which converts a broad range of forestry/agricultural residues and municipal wastes directly into renewable hydrocarbon transportation fuels and/or blend stocks. (Earlier post.)
The IH2 technology was developed by US-based Gas Technology Institute in 2009 and is being further developed in collaboration with CRI Catalyst Company (CRI), Shell’s Catalyst business. CRI will supply the proprietary catalysts for the unit. The Basic Engineering Package for the plant will be provided by Zeton, Inc. of Ontario, Canada.
USDA announces conditional commitment for $70M loan guarantee for Ensyn cellulosic biofuel refinery
December 11, 2015
The US Department of Agriculture (USDA) announced a conditional commitment for a $70-million loan guarantee to help build a cellulosic biorefinery in central Georgia. USDA is providing the loan guarantee conditional commitment through its Biorefinery Assistance Program.
Ensyn Georgia Biorefinery I, LLC (Ensyn) will construct and operate a cellulosic biofuel refinery in Dooly County, Georgia. The company will produce 20 million gallons of renewable fuel per year employing its Rapid Thermal Processing (RTP) technology. RTP uses a fast thermal process to convert non-food-based feedstocks into biobased fuels.
New catalytic process to convert lignin into jet-range hydrocarbons
Researchers at Washington State University (WSU) Tri-Cities have developed a catalytic process to convert corn stover lignin into hydrocarbons (C7–C18)—primarily C12–C18 cyclic structure hydrocarbons in the jet fuel range. The work is featured on the cover of the December issue of the RSC journal Green Chemistry.
The developer of the process, Bin Yang, an associate professor of biological systems engineering at WSU and his team are working with Boeing Co. to develop and test the hydrocarbons targeted to be jet fuel. Yang has filed for a patent on the process, with WSU as the assignee.
UMass Amherst computationl chemist to optimize zeolite biofuel production catalysts; more gasoline, less coke
December 09, 2015
University of Massachusetts Amherst computational chemist Scott Auerbach has been awarded a three-year, $330,000 grant from the National Science Foundation to improve basic understanding and optimize the catalytic process of producing fuels such as gasoline from plant biomass instead of from petroleum.
The study involves theoretical calculations aimed at understanding the complex catalysis involved in converting biomass-derived organic compounds to liquid fuel precursors in the confined spaces of zeolites while avoiding deactivation due to coke formation. Auerbach will employ a novel theoretical approach and benchmark it against experimental data.
UCLA–UC Berkeley paper outlines how CA can boost biofuel production to cut pollution and help the economy
December 07, 2015
California has not taken full advantage of opportunities to increase its in-state production of biofuel, despite state policies that encourage biofuel consumption, according to a policy paper by the Climate Change and Business Research Initiative at the UCLA and UC Berkeley law schools. The paper is the sixteenth in a series of reports on how climate change will create opportunities for specific sectors of the business community and how policy-makers can facilitate those opportunities.
The report—titled Planting Fuels: How California Can Boost Local, Low-Carbon Biofuel Production—underscores the importance of local production of low-carbon biofuel, suggesting that the state could reduce emissions by not shipping feedstocks from out-of-state or overseas; spurring development of carbon-reducing byproducts such as biochar compost; and reducing the risk of wildfire.
New method for creating interspecies yeast hybrids could boost biofuels production
December 05, 2015
Researchers at the University of Wisconsin-Madison have developed a simple, robust, and efficient method for generating interspecies yeast hybrids. As reported in the journal Fungal Genetics and Biology, this method provides an efficient means for producing novel synthetic hybrids for beverage and biofuel production, as well as for constructing tetraploids to be used for basic research in evolutionary genetics and genome stability.
Some 500 years ago, the accidental natural hybridization of Saccharomyces cerevisiae—the yeast responsible for things like ale, wine and bread—and a distant yeast cousin gave rise to lager beer. Today, cold-brewed lager is the world’s most consumed alcoholic beverage, fueling an industry with annual sales of more than $250 billion.
Boeing, Canadian aviation industry launch sustainable aviation biofuel project using forestry waste
December 03, 2015
Boeing, the University of British Columbia (UBC) and SkyNRG, with support from Canada’s aviation industry and other stakeholders, are collaborating to turn leftover branches, sawdust and other forest-industry waste into sustainable aviation biofuel.
Canada, which has extensive sustainably certified forests, has long used mill and forest residues to make wood pellets that are used to generate electricity. A consortium that includes Boeing, Air Canada, WestJet, Bombardier, research institutions and industry partners will assess whether forest waste could also be harnessed to produce sustainable aviation biofuel using thermochemical processing.
EPA nudges up volume of renewable fuel in final requirements for 2014-2016 under RFS
November 30, 2015
The US Environmental Protection Agency (EPA) announced the final volume requirements under the Renewable Fuel Standard (RFS) program today for the years 2014, 2015 and 2016, and final volume requirements for biomass-based diesel for 2014 to 2017.
This rule finalizes higher volumes of renewable fuel than the levels EPA proposed in June (earlier post), but still represents a reduction compared to the original statutory requirements.
TMFB researchers investigate engine performance of two possible future tailor-made biofuels
Researchers at RWTH Aachen University in Germany report on their evaluation of two possible future biofuels—tailor-made from biomass—in a paper in the journal Fuel. The team investigated the use of 2-butanone (also referred to as methyl ethyl ketone, MEK) and 2-methylfuran, both of which had been identified within the Cluster of Excellence “Tailor-Made Fuels from Biomass” (TMFB) (earlier post).
Investigations of the fuels’ autoignition tendency were carried out on a rapid compression machine (RCM); thermodynamic investigations were conducted on a direct injection spark ignition single cylinder research engine.
Stanford team increases power of corrosion-resistant solar cells; advance for solar fuels
Researchers at Stanford, with colleagues at University College Cork in Ireland, have shown how to increase the power of corrosion-resistant solar cells, setting a record for solar energy output under water. Instead of pumping electricity into the grid, the power these cells produce would be used in the production of solar fuels.
This new work, published in Nature Materials, was led by Stanford materials scientist Paul McIntyre, whose lab has been a pioneer in the field of artificial photosynthesis. Artificial photosynthesis proposes using the energy from specialized solar cells to combine water with captured carbon dioxide to produce industrial fuels.
Propel Fuels reports strong consumer adoption of renewable diesel in SoCal; retail sales up 300% over biodiesel
November 18, 2015
Propel launched Diesel HPR across Southern California in August 2015, and consumer adoption of the fuel has risen 300% compared to its former biodiesel product (B20). (Earlier post.) Utilizing Neste’s NEXBTL renewable diesel, Propel’s Diesel HPR is a low-carbon, drop-in renewable fuel that meets the ASTM D-976 petroleum diesel specifications for use in diesel engines, while offering drivers better performance and lower emissions.
Performance features include a 75 cetane rating, 40 percent higher than regular diesel. Diesel HPR provides cleaner and more efficient combustion for more power and a smoother ride at a cost similar to or lower than petroleum diesel.
DOE releases SBIR/STTR FY16 Phase 1 Release 2 topics; hydrogen, electric vehicles, more efficient combustion engines; biogas-to-fuels
November 16, 2015
The US Department of Energy has announced the 2016 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 2 Topics, covering eight DOE research program organizations.
Among the many topics listed are magnetocaloric materials development for hydrogen delivery; two hydrogen technology transfer opportunities (TTO); EV traction batteries and power electronics; new combustion engine technologies; and the co-utilization of CO2 and methane in biogas to produce higher hydrocarbon fuels. DOE plans to issue the full Funding Opportunity Announcement (FOA) on 30 November 2015.
Aramco opens R&D center in Detroit area; fuels research with focus on novel fuels/engines systems for reduced CO2
November 14, 2015
The Aramco Research Center-Detroit was inaugurated as one of three US-based research and development (R&D) centers aimed at expanding the global research capabilities of Saudi Aramco, the leading global integrated energy and chemicals company. The new facility, located in Novi, Mich., and owned and operated by US subsidiary Aramco Services Company, further strengthens the company’s global fuels research program.
Aramco’s fuels technology program is focused on reducing the overall environmental impact, cost and complexity of both current and future fuel-engine systems. With a global refining presence, Aramco brings a perspective into how fuels can be designed and matched to engines for higher performance and lower emissions. A planned outcome of Aramco’s research is to generate vehicle and fleet demonstrations to showcase the benefits of novel fuel/engine systems.