Air Force Flight Test of Syntroleum Gas-to-Liquids Fuel Successful
Siemens VDO Debuts Piezo Diesel Technology for Light Commercial Vehicles

QuantumSphere Files Patent on Catalyst Device for Low-Cost, High-Efficiency Hydrogen Electrolysis

Qsi
Efficiency of QSI Nano-Electrodes versus DoE 2010 target at different flow rates. Click to enlarge.

QuantumSphere (QSI), a manufacturer of nano metals and alloys for applications in renewable energy and other markets demanding advanced materials, has announced the recent filing of another patent relating to the production of hydrogen by electrolysis using its proprietary nano electrodes.

Using electrodes composed of QSI nanometals, QuantumSphere has achieved up to 80% efficiency at lower current flow rates (100 mA/cm2) and approximately 60% efficiency at higher rates (1,000 mA/cm2). Over the next year, QSI believes it will achieve or exceed the DoE 2010 target of 75% efficiency at rates beyond 1,000 mA/cm2 through further optimization. As a result, the company believes it has enabled electrolysis to more easily compete with hydrogen generation by steam reformation.

QSI compresses and sinters high surface area metallic nanoparticles into porous plates to function as liquid and gas diffusion electrodes for water electrolysis. The electrodes have an expanded metal surface facing away from the electrolyte for strength and current collection.

Tortuous pathways within them expose large surface area to reacting water and to also allow the escape of the gaseous products. Electrolyte flows through the electrode to sweep away the bubbles as they form.

QSI sees the efficiency of its electrolysis system as an important step in working toward a hydrogen-on-demand system for direct feed into fuel cells which would eliminate the need for storing hydrogen in pressurized systems with their attendant cost, logistical and safety issues.

QSI is working with DoppStein Enterprises on the electrolysis system.

Together, we are not only finding new, unexpected and highly active combinations of nano catalysts, but in the process are also developing the test methods for evaluation of the electrodes. This allows us to determine the next round of improvements, and has catapulted us beyond the literature into uncharted territory. These devices, made to test the electrodes, are also the embryonic hydrogen generating machines of the future. The collaboration is very exciting and productive.

—Robert Dopp, president and chief scientist, DoppStein Enterprises

DoppStein Enterprises, Inc. is an R&D laboratory located in Marietta, Georgia, working in renewable energy related fields including metal-air fuel cells, direct methanol fuel cells, and hydrogen production through water electrolysis.

Resources:

Comments

Matthew

Do these people not read blogs? How could they not know that hydrogen has been declared a dead, dead end, and that all these technical breakthroughs are pointless?

wintermane

Hehehe!

eric

For transportation it is certainly a dead issue, but there are other needs for hydrogen gas, so this may actually have some value.

Jim

"For transportation it certainly is a dead issue"

Iii ddoonn'tt tthhiinkk sooo.

A fuel pump with generation capabilites, or on site storage and generation, with Hydrogen being generated at the fueling station. No shipping,pipeline or major storage costs, only electricity and some water needed. I haven't given up. Economical storage on site and in vehichles will be the major problems.

t

The key is, how much electricity will be required to produce this hydrogen? And what will be used to produce this electricity. We shall see, I guess. In the mean time, let's keep our options open. Storage, of course, remains a major problem.

Paul

Not to mention to produce 1kg of h2 requires 9 litres of pure water. A typical h2 tank for a fuel cell car would be around 8 kg. So that will take 72 litres of water. Multiply that by a few million cars and that's one hell of a lot of clean water. Some places are already suffering from water shortages and GW promises to only make the situation worse. By the time you factor in electricity and water costs it certainly isn't going to be cheap to produce h2.

Reforming natural gas is a more efficient option but isn't sustainable.

SJC

I would fill the NG pipes with SNG made from biomass. No sulphur and mostly methane. I would store it on vehicle as CNG and use it in ICEs or reform it on vehicle for fuel cells. It is estimated that we have about 10 years of NG left in the US. The Canadians are keeping theirs for tar sands and LNG is expensive and limited. I think the days for SNG from biomass are at hand.

Paul

From a bit of research it appears that currently to produce h2 through electrolysis and compress it for storage takes about 60kWh/kg. So for a 8kg tank full that is 480 kw/h. Given a 8kg tank currently gives you around 300 miles range you would probably need to fill up 2 or 3 times a month. If you take the cost of water and electricity its starting to look pretty expensive. Plus there is no way you can produce 480 kw/h via solar on your roof.

jw

Multiply that by a few million cars and that's one hell of a lot of clean water.

Domestic water consumption in developed countries is around 500-800 liters per person per day, and domestic water consumption is about 1/5 of total water consumption (agriculture being the biggest by far).

The current generation of Honda FCX gets 57 miles/kg.

Average US household puts on about 21,000 miles/yr. There are about 110 million households, so that comes to about 2.3 trillion VMTs. At 57 miles/kg, that comes to 41 billion kg, or 365 billion liters, or 1 billion liters/day. Using the above average of 650 liters per person per day, US total domestic consumption is about 195 billion liters/day.

So, making hydrogen would increase domestic water consumption by 0.5%, and overall consumption by 0.1%. Double that to account for all ground transportation, then adjust according to whatever average efficiency you project. No matter how you slice it, water won't be the constraint.

Bike Commuter Dude

Not to pop any bubbles but:
"Do these people not read blogs? How could they not know that hydrogen has been declared a dead, dead end, and that all these technical breakthroughs are pointless?"


Whoa, that was ill conceived. I think that these people are trying to address the problems that are highlighted all to clearly on these blogs. It's too expensive --> Make it cheaper. Also, I suppose these folks didn't recieve there education from reading blogs on the internet, but more likely post graduate engineering schools...


"If you take the cost of water and electricity its starting to look pretty expensive. Plus there is no way you can produce 480 kw/h via solar on your roof."


Yes, but some very intelligent people are already on the right track to providing unlimited low cost electricity. You may not be able to generate that kind of power with photovoltaics, but wait until nanotech has been applied more to judge it's long term role. And maybe I'm nuts, but aren't the issues with water use pretty close to zero net water usage? I mean, you use water to make hydrogen, and then you either burn the H2 in an ICE, or run it through a fuel cell. In any event, water is then produced as a waste. So, any water you use, drops right back into the atmosphere to continue a multi-billion year cycle of water formation.


Patrick

The Chevy Equinox FCV gets about 47.6 miles per kg of H2 (granted this is going to be an optimistic estimate). 2.9625 Trillion miles traveled (urban & rural) in 2004 by passenger vehicles requires 62.238 billion kgs of H2 or 560.14 billion liters of distilled water in a year. Land transport of goods would probably triple that number.

An estimated 477.4 Trillion liters of fresh water was used in the US in 2000.

Jim

"From current research it takes about 60 KWh/Kg of Hydrogen"

The last I read it took about14KWh/Kg, plus an additional 7 percent of cost for compression. (the 7 percent cost is probably for large scale compression at 350 bars)

jw

Land transport of goods would probably triple that number.

Cars, motorcycles, and light trucks account for 78% of surface transportation liquid fuel consumption in the US.

Patrick

OK you made me look up the numbers. Passenger vehicles and motorcycles consume 43.7% of the liquid fuels and other land vehicles consume 56.3%.

Regardless, the amount of water which would be consumed is still relatively little next to the total water currently consumed.

Jim

I will have to take back my 14KWh/Kg figure. After posting I tried to find where I read it, and cannot find.(I know I have seen it, but was it a reliable site) I did find a couiple that refered to the 53-67KWh/Kg.

Paul

Patrick where are you getting your numbers for electricity usage from? I am getting mine from 'The National Hydrogen Association'
and they appear to be real world, not some theoretical number.

jw

OK you made me look up the numbers. Passenger vehicles and motorcycles consume 43.7% of the liquid fuels and other land vehicles consume 56.3%.

Cite your source. And define "land vehicles", since that's not a commonly used term in the field.

Here's my source:
http://www.bts.gov/publications/national_transportation_statistics/html/table_04_05.html

Nick

What will happen to the oxygen generated during electrolysis? Is it collected as a useful commodity? Does it change the economics at all?

DaChesserCat

Jim,

1 kg of H2 has about the same energy content as a gallon of gasoline. At 100% efficient conversion, that works out to 36 kWh/kg. Most commercially available hydrolyzers are only 50% efficient, so you'd have to put in 72 kWh of electricity to get 1 kg of H2 (you'd also get 36 kWh worth of heat). The fact that these guys are pushing it as high as 80% efficient, in some cases, means you'd only need 45 kWh of electricity to make 1 kg of H2 (you can't get below 36 kWh; there is no such thing as >100% efficiency).

45 kWh of electricity, at $0.10/kWh (average rate in the US) is still $4.50 for the H2 equivalent of 1 gallon of gasoline. While I applaud their efforts and their results, it's still going to be a while before electrolysis will get the cost of H2 down low enough to compete with reformed hydrocarbon fuels.

45 kWh of electricity, put into a battery, will still get you better than 36 kWh back out again. A modern, compact battery-electric vehicle gets about 5 miles/kWh. That's 180 miles for the same electrical input as the hydrogen vehicles they're describing above. Sorry guys, but fuel cells still have a long way to go before they can compete, in $/mile, with BEV's.

jw

Regardless, the amount of water which would be consumed is still relatively little next to the total water currently consumed.

Yep. I said so myself.

Nick

"45 kWh of electricity, at $0.10/kWh (average rate in the US) is still $4.50 for the H2 equivalent of 1 gallon of gasoline..."

Yes, but does a fuel cell drive train convert more of that energy into motion?

jw

A modern, compact battery-electric vehicle gets about 5 miles/kWh. That's 180 miles for the same electrical input as the hydrogen vehicles they're describing above. Sorry guys, but fuel cells still have a long way to go before they can compete, in $/mile, with BEV's.

Economics aren't going to factor in much when you take into account fueling times and range. Electric vehicles are still constrained in that way, though it's changing. The economics are much more complicated than simply the "fueling".

transparent

Efficiencies and economics make only a couple of considerations in future renewable resources. More likely is the desire of a huge liquid fuel economy to stay afloat. The change from petro to LNG, to biodiesel to ethanol or H2 is relatvely moot to them. As long as they can bottle it, control it and sell it - they're happy campers. It's the all-electrics ideas that terrify these guys - and they will not turn over a trillion dollar market without... a fight.

Patrick

Paul, Do you mean the numbers used for the FCV equinox? I pull that from their 4.2kg of H2 to go 200miles. Otherwise I make no statements concerning electrical energy (simply liters of water to produce H2 given the atomic weights of the atoms involved show 1/9 weight from H2 and 8/9 weight from oxygen in water).


jw, on the referenced table (the same source I used) take the gallons used by passenger sources divided by the gallons used by all other highway and transit vehicles + the passenger sources. Second, that is only highway useage. I refer to it as land because I was not including air or sea but then again I didn't include rail so that is not entirely accurate. It was easier than listing out every single category. Look at table 1_33 for the mileage figures I used above.

Dezakin

"Do these people not read blogs? How could they not know that hydrogen has been declared a dead, dead end, and that all these technical breakthroughs are pointless?"

Its not pointless. Someday hydrogen from efficient electrolysis may make sense for hydrogenating coal in producing synthetic diesel fuel, and in the far future for producing synthetic fuels from limestone and water.

Not terribly useful today, except for maybe getting large quantities of heavy water for nuclear programs fair and foul.

The comments to this entry are closed.