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Kanagawa University Develops New Diesel Emulsion Fuel

Kanagawa2_1
Test vehicle for Super Emulsion Fuel.

Researchers at Kanagawa University in Japan have developed a new emulsified diesel fuel—Super Emulsion Fuel—that reduces emissions and improves fuel economy compared to standard diesel and also maintains stability much longer than conventional emulsified fuels.

Emulsified diesel fuel is a mixture of diesel fuel with water and emulsifying and stabilizing additives. The practice of adding water to diesel dates back to the early 1900s, and there are hundreds of different patented implementations. Depending on the application, the water content may vary from 8%-35%, with a typical 13% water formulation for diesel engine use.

There are numerous benefits to adding water to diesel. Water vaporization increases fuel dispersion in the form of smaller droplets and the contact surface between fuel and air is increased. As a result, combustion is more efficient; combustion temperature peaks are lowered, thereby reducing NOx; and PM formation is reduced.

The newly developed emulsion fuel is also a mixture of water and oil, but the team developed a novel method of emulsification. Rather than relying on surfactants, the new three-phase emulsification process uses the weak molecular attraction (van der Waals force) between hydrophilic nano-particles. A single type of emulsifying particle can be used to emulsify many different oil types. Conventional surfactant-based emulsification uses different surfactants for different oils.

The new process relies on the size and shape of the particles alone and not on the unique properties of a surfactant substance.

Kanagawa2
Click to enlarge.

Tests with a heavy-duty (30-ton) dump truck used two emulsified blends: 65 to 35 wt% diesel to water and 70 to 30 wt% diesel to water. Test results showed significant drops in emissions and an increase in fuel efficiency of 10-15%.

New emissions regulations phasing into effect in Japan require a 25 to 43% reduction in NOx, a 15 to 50% reduction in PM and a 33 to 60% reduction in HC over existing regulations for different weight classes of vehicles. The dump truck using the Super Emulsion Fuel met the requirements.

Resources:

Comments

yesplease

Water injection in a can. ^^

Steven

What they don't mention is emulsified fuels also carry heavy penalties in power output and fuel consumption.

yesplease

You sure 'bout that?

"Test results showed significant drops in emissions and an increase in fuel efficiency of 10-15%."

Yes I Am a Rocket Scientist

So you're saying this is not true:
"Test results showed significant drops in emissions and an increase of fuel efficiency of 10-15%"?

As to the "heavy" penalty on power, I doubt it. Yes, the fuel will have a lower energy density, but the expanding water will turn more of the fuel-energy into power. Most likely the power difference will be a wash.

Yes I Am a Rocket Scientist

Hey yesplease,

great minds think alike, some fingers just type slower than others. ;-)

yesplease

:D

Yes I Am a Rocket Scientist

I wonder if how this effects the cloud point. If it lowers it, could this method be appled to biodiesel to make it a viable winter fuel? . . .

Andrey

As usual, overdramatization bordering with direct falsification. Reduction in fuel consumption (calorific) is closer to 2-3%, and in most cases is achieved only on old diesels with low-pressure mechanical injection. Reduction in emission generation is very real, thought: about 7% in NOx and surprisingly 3% diesel soot per 10% water blended.

Water emulsification is well established and widespread emission control technology, very cost effective where a lot of old diesels work, like in ports and terminals.

The drawbacks are: water should be distilled, max power output suffers unless fuel injection system is modified to inject bigger volume, and in some cases there were reports about excessive fuel system wear.

Andy

So we now can have D70W30 or would that be ULSD70W30 or just B10ULSD60W30 or... Oh to much, just fill'er up please.

Yes I Am a Rocket Scientist

Andrey,

Sounds like what you are referring to is the old surfactant method of emulsification. The method being discussed here is not "well established" nor "widespread"

This method supposedly doesn't need distilled water either. . .

Robert Schwartz

Four parts of Olive Oil to one part of Lemon Juice. Mix thoroughly.

Mark R. W. Jr.

It sounds like this could work with petro-based diesel. What about about biodiesel?

Vin Diesel

I am very interested to know about any tests using diesel mixed with hydrated ethanol. If you can add water, then why not add hydrated ethanol?

All ethanol for gasoline motor consumption must be dehydrated, an expensive process... but what if hydrated ethanol is added to diesel fuel? How will this mix affect engine performance, gas mileage, BTU content, emissions, etc.?

Andrey

Rocket Scientist;
It does not really matter what method of emulsification is used. If they developed better way to produce water emulsion, without expensive surfactant agents – good. Diesel/water emulsion is by far the most effective way to reduce NOx emissions from fleet diesel engines concentrated at one location. One blending installation on the site could service all of them. Port servicing equipment is good example. As I know, this method is certified by CARB and is used at Long Beach port in LA.

Distilled water is a must because regular water deposits salts at evaporation, which could clog injectors and for sure significantly increase engine liners/piston rings wear due to abrasive properties of these salts. For stationary installations relatively cheap reverse osmosis water demineralization system solves this problem quite economically. In most cases, heavy diesel engines are derated, and have ample reserve of injector’s capacity to compensate for less energy dense fuel.

Vin Diesel;

Addition of ethanol to diesel/water emulsion is very intriguing indeed, but I am not aware of such tests. Ethanol blended gasoline is the best way to keep gas tank on your car free of accumulated water and should be used periodically by everyone as part of preventive maintenance.

Steven

The only water emulsion fuel currently approved under the EPA's "Verified Retrofit Technologies" is Lubrizol's PuriNOX. While it has been around for years, it's performance is very close to this new method. It carries the following caveats:

End use applications must be tolerant of up to a 20% power loss when operating at maximum engine horsepower.

The typical end user will experience a 15% increase in fuel consumption for equipment operating on PuriNOx fuel.

Information from: http://www.epa.gov/otaq/retrofit/techlist-lubrizol.htm

George

What is not discussed is the problems with water going thru the injection pump. Water is a non issue to increased wear and tear "to a point" inside the cylinders where combustion occurs.

Inside the IP this is a very different thing. Micro explosions* (cavitation) caused by differences in expansion of the water molecule compared to the oil molecule during pressurizing in the Injection Pump can cause severe damage to the IP.


*(micro explosion is a simple non scientific description of cavitation and damage it causes to IP components. Do a search about "diesel, cavitation, injection pump" for more information)

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Santos

I,m interesed on Emulsion Fuel Technology.
how can i get more information about emulsion fuel ?
Can it used for genset diesel and burner?
I live in Indonesia,and in my country Fuel Diesel is more popular.

Michel

Looking for surfactant in quantity

freddy

How can I get more information about the surfactant you need for this emulsion?.
Thanks.
Freddy

freddy

How can I get more information about the process and the surfactant you recomend?
Freddy.

non chemist

will this method reduce Btu's and if so by how much?

Marizan Nor Basirun

S.I.T Schiffs-&Industrie Technik (M) Sdn Bhd manufacture the CD92 WiDE Homogenizer. It makes water diesel emulsions with up to 30% water. Its the only equipment typed approved by Llyods Register and American Bureau of Shipping for generating stable water diesel emulsion. It is already widely used in ships where residual fuel oils are the common fuel. CD92 WiDE Homogenizer system also produces distillate water diesel emulsion. You can direct your enquiry to [email protected]

Marizan Nor Basirun

To Charles Wong;
Yup, wde ( water diesel emulsion ) is applicable for gensets and burners. CD92 Homogenizers makes both residual ( usually used in steam power plants and >2MW Diesel power plants in Indonesia ) and distillate ( for <2MW Diesel Power Plant ) wde. Feel free to contact us.

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