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Rice Chemists Create, Grow Nanotube “Seeds”

Rice
The Rice work demonstrates a method for the “prolific” generation of carbon nanotubes of the same type. Click to enlarge.

Rice University chemists have revealed the first method for cutting carbon nanotubes into “seeds” and using those seeds to sprout new nanotubes. The findings offer hope that seeded growth may one day produce the large quantities of pure nanotubes needed for dozens of materials applications.

The research is available online and slated to appear in an upcoming issue of the Journal of the American Chemical Society.

Carbon nanotubes come in lots of diameters and types, and our goal is to take a pure sample of just one type and duplicate it in large quantities. We’ve shown that the concept can work.

—James Tour, director of Rice’s Carbon Nanotechnology Laboratory (CNL)

The study’s lead author, CNL founder and nanotube pioneer Richard Smalley, died in October 2005 after a long battle with leukemia. Tour said Smalley devoted an enormous amount of time and energy to the seeded-growth nanotube amplification research in the final two years of his life.

Tour and a co-director, Matteo Pasquali, succeeded Smalley as CNL director following Smalley’s death.

Rick was intent on using nanotechnology to solve the world’s energy problems, and he knew we needed to find a way to make large quantities of pure nanotubes of a particular type in order to re-wire power grids and make electrical energy widely available for future needs.

—James Tour

First discovered just 15 years ago, single-walled carbon nanotubes (SWNTs) are molecules of pure carbon with many unique properties. Smaller in diameter than a virus, nanotubes are about 100 times stronger than steel, weigh about one-sixth as much and are among the world’s best electrical conductors and semi-conductors. Smalley, who devoted the last 10 years of his career to studying SWNTs, pioneered the first method for mass-producing them and many of the techniques scientists use to study them.

There are dozens of types of SWNTs, each with a characteristic atomic arrangement. These variations, though slight, can lead to drastically different properties: Some nanotubes are like metals, and others are semiconductors. While materials scientists are anxious to use SWNTs in everything from bacteria-sized computer chips to geostationary space elevators, most applications require pure compounds. Since all nanotube production methods, including the industrial-scale system Smalley invented in the 1990s, create a variety of 80-odd types, the challenge of making mass quantities of pure tubes—which Smalley referred to as SWNT amplification—is one of the major, unachieved goals of nanoscience.

Rick envisioned a revolutionary system like PCR (polymerase chain reaction), where very small samples could be exponentially amplified. We’re not there yet. Our demonstration involves single nanotubes, and our yields are still very low, but the amplified growth route is demonstrated.

—James Tour

The nanotube seeds are about 200 nanometers long and one nanometer wide—length-to-diameter dimensions roughly equal to a 16-foot garden hose. After cutting, the seeds underwent a series of chemical modifications. Bits of iron were attached at each end, and a polymer wrapper was added that allowed the seeds to stick to a smooth piece of silicon oxide. After burning away the polymer and impurities, the seeds were placed inside a pressure-controlled furnace filled with ethylene gas. With the iron acting as a catalyst, the seeds grew spontaneously from both ends, growing to more than 30 times their initial length in just a few minutes.

Tour, Chao Professor of Chemistry, professor of mechanical engineering and materials science and professor of computer science, said CNL’s team has yet to prove that the added growth has the same atomic architecture—chirality—of the seeds. However, he said the added growth had the same diameter as the original seed, which suggests that the methodology is successful.

Other researchers on the project include Yubao Li, postdoctoral researcher; Valerie C. Moore, former graduate student and assistant professor at the University of Texas Health Science Center at Houston; Katherine Price, graduate student; Ramon Colorado Jr., research scientist; Howard Schmidt, CNL executive director; Robert Hauge, distinguished faculty fellow and CNL technology director; and Andrew Barron, the Charles W. Duncan Jr.-Welch Professor of Chemistry, professor of materials science and associate dean for industry interactions and technology transfer.

Research sponsors include the Defense Advanced Research Projects Administration, NASA and the Robert A. Welch Foundation.

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Comments

allen_Z

This is like, but not exactly the same as, growing diamonds by starting with small seed pieces and growing them with more carbon.
_There might be safety problems, since nanotubes are like needles, can pierce surfaces, and then stick, as well as behaving like aerosol. They may clump deep within the lungs, or act like asbestos or other fine mineral fiber. This would be primarily a concern during manufacturing (of composites), and destruction (of material), whether it be during disposal/recycling, or violent incidents intentional or accidential.
_Surfaces of nanotubes are also almost friction free, and might prove to be a challenge to keep from slipping and sliding around within a matrix. Molecular branching, nanotubes with U shapes, or hooked ends to facilitate mechanical interconnection of nanotubes at the molecular level and remedy this issue.
_The use of C2H6 may prove interesting, since it is a raw material already in demand for polyethylene. Perhaps it might replace it in certain products. SPECTRA shield (Honeywell), made of polyethyene fiber, is the backing of Interceptor SAPI plates. Higher strength, potentially afforded by lighweight nanotube composites, backing and body armor material may make Interceptor system better, or obsolete.
_Other than that, this might pave the way for affordable, light, high quality, high strength material for a plethora of uses. A carbon fiber aluminum alloy NASCAR cage, w/an abundance of airbags, could make A and B segment cars prectically indestructible vs all current road vehicles. This would eliminate the last reservations about crash safety of small/mini cars. All vehicles could be lighter, 30-50% lighter. A 2+ton 24mpg large MPV would become a 2,100-3,000lb vehicle w/fuel mileage of a good modern B car.

Rafael Seidl

Allen -

your safety concerns are very valid. Anything that small is particulate matter as far as human health is concerned. PM smaller than 7 microns (7000 nanometers) can pass through the alveolae into the bloodstream and accumulate in organs such as the liver, even cross the blood/brain barrier.

Getting insurance cover may prove even harder for nanotube companies than figuring out how to make the stuff is.

JC

Nano-science marches on. But Allen's prediction of the super-safe mini-car don't make sense to me. Yes, the car's safety cage would be strong. But wouldn't the technology be prohibitively expensive? More importantly, this still does nothing to "ride down" the force of an impact through material distortion. If anything, a crash using such a cage would register higher G forces. Mini-cars need much work in deformable structures to overcome rational safety concerns. In addition, we need to see investment in Ford's inflatable safety belt, stronger pillars, roofs and foot boxes using high-strength steel, better headlights, higher standards in braking, and a sensible built-in limit to top speed dependent upon driving zone via short range transmitter.

Reality Czech

Ethylene is C2H4, not C2H6.

Harvey D.

JC:

You have a good point. Making the box lighter + stronger will translate into more driver confidence, more speed, more loss of control and more accidents of all types.

Road casualties, presently at about 50 times the Irak war rate, seem to creep up and match the number of vehicles on the roads and streets.

Speed, cell phones usage, driver negligence-foolhardiness-inexperience, poor road condition and design etc cannot be overcome with lighter-stronger materials.

Some kind of automated systems to reduce the speed and even stop the vehicle when known dangerous factors occur would help.

Lucas


Assuming that cost is not a consideration, it is possible to build a very light, very strong automobile structure today. Unfortunately that does not overcome the basic physics involved. (See laws of motion.)

No matter how strong of a cage we put around the occupants, the bottom line is the limits of the deceleration forces that humans can survive without injury.

A few months ago, I designed a vehicle structure that used carbon fiber, polycarbonate, kevlar, spectra and expanded polypropylene foam. (to fill all voids)

Using computer simulations, I subjected my design to various types of crashes. The structures survived fairly well. Unfortunately, I can't say the same for the occupants.

Short of ejection seats, I have no idea how this reality can be overcome.

Rafael Seidl

JC -

well-designed composites can actually absorb far more energy via delamination than metal parts can via plastic deformation (except for localized buckling, but that is only possible for a limited set of crash scenarios).

Harvey D. -

making a vehicle lighter does not necessarily increase its top speed. After all, you can fit a less powerful engine. Active safety systems are popular gadgets these days, at least in luxury vehicles: ABS, ESP, look-ahead radar, infrared cameras, head-up displays, adaptive cruise control w/ crash anticipation, curve lights, lane deviation warning systems, cameras for blind spot and parking, self-deploying rollover guards in convertibles etc.

Of course, none of these measures is a substitute for an alert and defensive driver. Too many traffic accidents are caused by alcohol consumption, drowsiness, distractions incl. misbehaving children and phone calls as well as unsafe speeds in inclement weather and/or terrain. Mechanical failure is rarely to blame and then usually only as a result of poor maintenance.

It would indeed be useful to couple acceleration and rotation sensors with differential GPS, navigation computers and road condition data broadcast received via reliable multicast. This would allow the vehicle to identify certain unsafe driver behavior patterns and issue warnings and/or take fail-safe action. This might be especially useful for at risk-drivers, e.g. teenagers, college kids and senior citizens.

If vehicles actually broadcast their position, compass heading and speed to the traffic around them, each could maintain a dynamic map of its immediate neighbors. Of course, the success of such a system depends on the software's ability to infer the likely location of any vehicles that are unable or unwilling to participate. For privacy, the standardized communications protocol would on a crypto hash of the VIN plus the timestamp of the last engine start. This is virtually guaranteed to be unique.

Neil

Being a parent of two, I have to shake my head at "baby on board" signs. What they should say is "distracted parent driving"

JC

Lucas,

Imagine a side impact into a carbon fiber door panel. The occupant would be subject to a hail of high speed chards. To offset, the standard un-armored airbag would be shredded, and also forced toward the occupant.

Without consideration of cost, what you've done is to have a bunch of CAD fun designing your car. I'm interested in practical, do-it-ASAP measures to build our sustainable future, the only one worth living in. It's hard for me to imagine kevlar or carbon fiber being used for mass-produced major automobile structures, nevermind carbon nano-structures. I CAN imagine a mixture of plastic and some cheap, small, hollow structures which blooms or is blown into a matrix. Such a mystery material must be cheap enough to be widely used. What is obvious to us both is that any lower mass alternative to steel or aluminum will have to be engineered to smoothly decelerate the vehicle upon impact. Small cars have a big job to do in keeping us safe.

Lucas


JC - You put your finger on it.

If it were cheap and easy, we would all be driving composite cars.

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