Rice scientists mixed very low concentrations of diamond particles (about 6 nanometers in diameter) with mineral oil to test the nanofluid’s thermal conductivity and how temperature would affect its viscosity. They found it to be much better than nanofluids that contain higher amounts of oxide, nitride or carbide ceramics, metals, semiconductors, carbon nanotubes and other composite materials.

Thermal fluids are used to alleviate wear on components and tools and for machining operations like stamping and drilling, medical therapy and diagnosis, biopharmaceuticals, air conditioning, fuel cells, power transmission systems, solar cells, micro- and nanoelectronic mechanical systems and cooling systems for everything from engines to nuclear reactors.

Fluids for each application have to balance an ability to flow with thermal transport properties. Thin fluids such as water and ethylene glycol flow easily but don’t conduct heat well, while traditional heat-transfer fluids can be affected by stability, viscosity, surface charge, layering, agglomeration and other factors that limit essential flow.

Researchers have been looking since the late 1990s for efficient, customizable nanofluids that offer a middle ground. They use sub-100 nanometer particles in low-enough concentrations that they don’t limit flow but still make efficient use of their heat-transfer and storage properties.

Nanodiamonds are proving to be the best additive yet. They carry most of the properties that make bulk diamond so outstanding for heat-transfer applications at the macro scale. Single diamond crystals can be 100 times better at thermal conductivity than copper while still acting as an efficient lubricant.

In tests, the researchers dispersed nanodiamonds in mineral oil and found that a very small concentration—one-tenth of a percent by weight—raised the thermal conductivity of the oil by 70% at 373 Kelvin (100 °C). The same concentration of nanodiamond at a lower temperature still raised the conductivity, but to lesser effect (about 40% at 323 K).

They suggested a mechanism somewhat like percolation—but perhaps unlike anything else yet seen—takes hold as oil and diamond molecules collide when heated.

Brownian motion and nanoparticle/fluid interactions play an important role. We observed enhancement in thermal conductivity with incremental changes in temperature and the amount of nanodiamonds used. The temperature-dependent variations told us the changes were due not just to the percolation mechanism but also to Brownian motion.

—Jaime Taha-Tijerina, lead author

Resources

• Jose Jaime Taha-Tijerina, Tharangattu Narayanan Narayanan, Chandra Sekhar Tiwary, Karen Lozano, Mircea Chipara, and Pulickel M. Ajayan (2014) “Nanodiamond-Based Thermal Fluids,” ACS Applied Materials & Interfaces doi: 10.1021/am405575t