Sandia, Berkeley and Los Alamos labs in $9M effort for automotive onboard solid-state hydrogen storage; HyMARC
Sandia National Laboratories will lead a new tri-lab consortium to address unsolved scientific challenges in the development of viable solid-state materials for storage of hydrogen onboard vehicles. Better onboard hydrogen storage could lead to more reliable and economic hydrogen fuel cell vehicles.
Called the Hydrogen Materials—Advanced Research Consortium (HyMARC), the program is funded by the US Department of Energy’s (DOE) Fuel Cell Technologies Office within the Office of Energy Efficiency and Renewable Energy at $3 million per year for three years ($9 million total), with the possibility of renewal. In addition to Sandia, the core team includes Lawrence Livermore and Lawrence Berkeley national laboratories.
HyMarc is one of three multi-lab consortia being put forward by the DOE in the hydrogen arena; the other two are FC-PAD (Fuel Cell Performance and Durability) and H2RENEW (Hydrogen Production from Renewables).
The HyMarc consortium will address the gaps in solid-state hydrogen storage by leveraging recent advances in predictive multiscale modeling, high-resolution in situ characterization and material synthesis. Past efforts, which synthesized and characterized hundreds of materials for solid-state hydrogen storage, laid a solid foundation for current work including the understanding of the kinetics and thermodynamics governing the physical properties of these types of storage methods.
By focusing on the underlying properties and phenomena that limit the performance of storage materials, we will generate much-needed understanding that will accelerate the development of all types of advanced storage materials, including sorbents, metal hydrides and liquid carriers.—Brandon Wood, leader of the Lawrence Livermore team
Sandia is an international leader in hydrogen materials science, exemplified by its role as the lead lab in DOE’s Metal Hydride Center of Excellence, which ran from 2005-2010. The consortium will leverage the core capabilities of the three partners, primarily synthetic chemistry at Sandia; theory and modeling at Lawrence Livermore, with additional contributions from the Lab’s synthetic and characterization expertise; and characterization at Berkeley Lab.
|The FC-PAD consortium seeks to enhance the performance and durability of polymer electrolyte membrane (PEM) fuel cells, while simultaneously reducing their cost.|
|Consortium members in this effort are Argonne National Laboratory, Lawrence Berkeley National Laboratory with Adam Weber serving as the consortium’s deputy director, Los Alamos National Laboratory, the National Renewable Energy Laboratory and Oak Ridge National Laboratory.|
|The consortium will coordinate national laboratory activities related to fuel cell performance and durability, provide technical expertise, and integrate activities with industrial developers. Dimitrios Papageorgopoulos, Los Alamos Fuels Cells program manager, will lead the consortium.|
|In addition to leading the overall project, Los Alamos will coordinate the evaluation of membrane electrode assembly’s performance and durability using the Laboratory’s wealth of fuel cell expertise and materials characterization tools, with Los Alamos scientist Rangachary Mukundan as thrust coordinator.|
The world-class supercomputing facilities at Lawrence Livermore and Sandia are key elements of the team’s strategy to develop the enabling science for hydrogen solid storage technologies, along with advanced experimental tools available at Berkeley Lab’s Advanced Light Source and Molecular Foundry facilities.
Current hydrogen storage misses capacity, cost targets. In the past five years, fuel cell electric vehicles (FCEVs) have gone from a concept to reality. Automakers are starting to roll out commercial FCEVs and investments are being made to deploy hydrogen refueling infrastructure, especially in early markets, such as California and the Northeast.
However, the commercial FCEV light-duty vehicles are designed for 700-bar compressed hydrogen storage on board the vehicle and hydrogen-refueling infrastructure is being deployed for compressed hydrogen refueling. Although compressed hydrogen provides a near-term pathway to commercialization, this storage method falls short of DOE targets for onboard hydrogen storage, particularly for volumetric hydrogen energy density and cost.
Hydrogen, as a transportation fuel, has great potential to provide highly efficient power with nearly zero emissions. Storage materials are the limiting factor right now.—Sandia chemist Mark Allendorf, the consortium’s director
Thermodynamics, kinetics challenges. Although HyMARC will consider all types of hydrogen storage materials, two categories of solid-state materials, novel sorbents and high-density metal hydrides, are of particular interest. These materials have the potential to meet DOE targets to deliver hydrogen at the right pressure and energy density to power a hydrogen fuel cell vehicle.
A key challenge is the thermodynamics—the energy and conditions necessary to release hydrogen during vehicle operation. Sorbents, which soak up hydrogen in nanometer-scale pores, bind hydrogen too weakly. In contrast, metal hydrides, which store hydrogen in chemical bonds, have the opposite problem—they bind the hydrogen too strongly.
The kinetics, the rate at which a chemical process occurs, is also an issue for high-density metal hydrides. These materials undergo complicated reactions during hydrogen release and uptake that can involve transitions between liquid, solid and gaseous phases. In some cases, the chemical reactions can form intermediates that trap hydrogen.
The consortium will explore several innovative ideas for solving these problems. The overall concept is to synthesize well-controlled materials to serve as model systems and develop experimental platforms for systematically probing key processes that limit performance.
Using these tools, we can study the hydrogen reactions with these materials using state-of-the-art techniques, such as those at Berkeley Lab’s Advanced Light Source and Molecular Foundry, which can provide unprecedented spatial resolution of material composition and character in real time.—Jeff Urban, Berkeley Lab team lead
The HyMARC strategy embodies the approach highlighted within the recent Materials Genome Initiative (MGI) Strategic Plan for accelerated materials development. The focus is on developing a set of ready-to-use resources accessible to the entire hydrogen storage community.
With our extensive knowledge base of hydrogen storage materials and new tools for characterization, modeling and synthesizing materials, many of which were not available even five years ago, our goal is to develop codes, databases, synthetic protocols and characterization tools. These resources will create an entirely new capability that will enable accelerated materials development to achieve thermodynamics and kinetics required to meet DOE targets.—Mark Allendorf