New silicon oxycarbide glass/graphene anode material; lightweight, high-capacity and long cycle life
11 April 2016
Researchers at Kansas State University have developed a new high-performance Li-ion battery anode material combining silicon oxycarbide (SiOC) glass and graphene. The self-standing (i.e., no current collector or binder) anode material comprises molecular precursor-derived SiOC glass particles embedded in a chemically-modified reduced graphene oxide (rGO) matrix.
The porous reduced graphene oxide matrix serves as an effective electron conductor and current collector with a stable mechanical structure, and the amorphous silicon oxycarbide particles cycle lithium-ions with high Coulombic efficiency. The SiOC-rGO composite electrode delivers a charge capacity of ~588 mAh g−1electrode (~393 mAh cm−3electrode) at the 1,020th cycle and shows no evidence of mechanical failure.
The electrode has first cycle charge capacity of 702 mAh g−1electrode and ~470 mAh cm−3electrode at 100 mA g−1electrode and stable charge capacity of 543 mAh g−1electrode (~363 mAh cm−3electrode) at charge current density of 2,400 mA g−1electrode. The capacity is ~200 mAh g−1electrode when cycled at ~-15 °C.
Further, the composite electrode has exceptionally high strain-to-failure (exceeds 2%) as measured in a uniaxial tensile test and the mode of failure differ significantly from pristine rGO papers.
The elimination of inactive ingredients such as metal current collector and polymeric binder reduces the total electrode weight and may provide the means to produce efficient lightweight batteries, the researchers suggest. An open-access paper on their work is published in the journal Nature Communications.
Concentrated efforts are currently employed to discover a practical replacement for traditional Li-ion battery electrodes that is, graphite anode and LiCoO2 cathode with materials that continuously deliver high power and energy densities at high cycling efficiencies without damage. Alloying reaction electrodes such as silicon that can deliver as much as 5–10 times higher discharge capacity than traditional graphite, are at the forefront of this research. High capacity electrodes, however, are prone to enormous volume changes (~300%) that generally lead to structural collapse and capacity fading during successive lithiation/delithiation.
Recent work has shown that decreasing particle size or electrode nanostructuring allows the electrode to withstand high volumetric strains associated with repeated Li alloying and de-alloying. Pomegranate-inspired carbon-coated Si nanoparticles, yoke shell-structured SiC nanocomposites and Si/C core/shell composites (prepared at low mass loading) have proven to survive several hundred cycles without damage. Yet, electrode nanostructuring has lead to new fundamental challenges such as low volumetric capacity (low tap density), increased electrical resistance between the nanoparticles, increased manufacturing costs and lower Coulombic efficiency due to side reactions with the electrolyte. These challenges have not been fully addressed. What’s more, a particle-based electrode’s long-term cyclability hinges on the inter-particle electrical connection and particle adhesion to the metallic substrate, which decreases rapidly with increasing charge/discharge cycles, particularly for thick high-loading electrodes.—David et al.
Graphene-based multicomponent composite anodes have attracted interest as solutions to these issues—mainly because of graphene’s superior electronic conductivity, mechanical strength and ability to be interfaced with Li active redox components, such as silicon. However, it has been difficult to incorporate graphene and silicon into practical batteries because of challenges that arise at high mass loadings—e.g., low capacity per volume, poor cycling efficiency and chemical-mechanical instability.
The team led by Gurpreet Singh has addressed these challenges by manufacturing a self-supporting and ready-to-go electrode that consists of a glassy ceramic called silicon oxycarbide sandwiched between large platelets of chemically modified graphene, or CMG. The paper-like design is made of 20% chemically modified graphene platelets.
The design enables an approximate 10% weight reduction in the cell. The lightweight electrode is capable of near 100% cycling efficiency. The low temperature performance suggests that rechargeable batteries from silicon-glass and graphene electrodes may also be suitable for unmanned aerial vehicles flying at high altitudes, or maybe even space applications, Singh said.
The silicon oxycarbide material is prepared by heating a liquid resin to the point where it decomposes and transforms into sharp glasslike particles. The silicon, carbon and oxygen atoms are rearranged into random 3-D structure and any excess carbon precipitates out into cellular regions.
Such an open 3-D structure creates large sites for reversible lithium storage and smooth channels for lithium-ion transportation. This structure and mechanism of lithium storage is different than crystalline silicon electrodes. Silicon oxycarbide electrodes are expected to be low cost because the raw material—liquid resin—is a byproduct of the silicone industry.
Moving forward, Singh and his team want to address practical challenges. Singh’s goal is to produce this electrode material at even larger dimensions. The team also would like to perform mechanical bending tests to see how they affect performance parameters.
Ultimately, we would like to work with industry to explore production of lithium-ion battery full-cells. Silicon oxycarbide can also be prepared by 3-D printing, which is another area of interest to us.—Gurpreet Singh
The research received funding from the National Science Foundation.
Lamuel David, Romil Bhandavat, Uriel Barrera & Gurpreet Singh (2016) “Silicon oxycarbide glass-graphene composite paper electrode for long-cycle lithium-ion batteries” Nature Communications 7, Article number: 10998 doi: 10.1038/ncomms10998
What would be the comparative performance at the cell level against current top of the line?
Posted by: HarveyD | 11 April 2016 at 08:13 AM
"..charge capacity of ~588 mAh g−1electrode (~393 mAh cm−3electrode) at the 1,020th cycle and shows no evidence of mechanical failure."
- sounds several-fold like than present commercial electrodes - right?
Posted by: kelly | 11 April 2016 at 12:28 PM
Kelly, not really. The "active" part of the cell is often only about 30-35% of the total cell by weight. But then you have to multiply the mAh by the Voltage which usually runs 2.5-2.7V depending on the chemistry for Lithium batteries.
Plus, to answer Harvey's question, you'd have to know which cathode it would be paired with and the cathode is usually the weak link in terms of energy density compared to the anode.
So there's not really enough info to answer the question, but depending on what assumptions you want to make I could see it being between 400-600Wh/kg. And of course, all of that assumes there's no hidden "gotcha" in this thing with regard to cost, operating temp range (both hot and cold), what electrolyte it uses, yada, yada, yada, yada.
Posted by: DaveD | 12 April 2016 at 01:25 PM