Ozone pollution near Earth’s surface is one of the main ingredients of summertime smog. It is also not directly measurable from space due to the abundance of ozone higher in the atmosphere, which obscures measurements of surface ozone. New NASA-funded research has devised a way to use satellite measurements of the precursor gases that contribute to ozone formation to differentiate among three different sets of conditions that lead to its production.
These observations may also assist air quality managers in assessing the most effective approaches to emission reduction programs that will improve air quality. A study describing the research is published in Journal of Geophysical Research: Atmospheres, a publication of the American Geophysical Union.
Determining effective strategies for mitigating surface ozone (O3 ) pollution requires knowledge of the relative ambient concentrations of its precursors, NOx, and VOCs. The space-based tropospheric column ratio of formaldehyde to NO2 (FNR) has been used as an indicator to identify NOx-limited versus NOx-saturated O3 formation regimes. Quantitative use of this indicator ratio is subject to three major uncertainties: (1) the split between NOx-limited and NOx-saturated conditions may shift in space and time, (2) the ratio of the vertically integrated column may not represent the near-surface environment, and (3) satellite products contain errors. We use the GEOS-Chem global chemical transport model to evaluate the quantitative utility of FNR observed from the Ozone Monitoring Instrument over three northern midlatitude source regions.—Jin et al.
Unlike its presence at high altitude where ozone acts as Earth’s sunscreen from harmful ultraviolet radiation, at low altitudes, ozone is a health hazard contributing to respiratory problems such as asthma and bronchitis. It is formed through complex chemical reactions initiated by sunlight and involving two types of gases, volatile organic compounds (VOC) and nitrogen oxides (NOx). Both are represented in the study by a major gas of each type, the VOC formaldehyde and NO2, that are measureable from space by the Dutch-Finnish Ozone Monitoring Instrument aboard NASA’s Aura satellite, launched in 2004.
With a combination of computer models and space-based observations, Xiaomeng Jin at the Lamont-Doherty Earth Observatory at Columbia University and her colleagues used the concentrations of ozone’s precursor molecules to infer whether ozone production increases more in the presence of nix, VOCs, or a mix of the two, for a given location.
Their study regions focused on North America, Europe and East Asia during the summer months, when abundant sunlight triggers the highest rates of ozone formation. To understand their impact on ozone formation, Jin and her team investigated whether VOC or NOx was the ingredient that most limited ozone formation. If emissions of that molecule are reduced, then ozone formation will be reduced—critical information for air quality managers.
The findings show that cities in North America, Europe and East Asia, are more often VOC-limited or in a transitional state between VOC and NOx-limited. In addition, the 12-year data record of satellite observations show that a location’s circumstances can change.
For example, in 2005 New York City’s ozone production during the warm season was limited by VOCs, but by 2015 it had transitioned to a nox-limited system due to reduced NOx emissions resulting from controls put into place at both regional and national levels. This transition means that future NOx reductions will likely further decrease ozone production, said Jin.
Volatile organic compounds occur in high volume naturally, given off by some plants, including certain tree species. They can also arise from paint fumes, cleaning products, and pesticides, and are a by-product of burning fossil fuels in factories and automobiles. Nitrogen oxides are a byproduct of burning fossil fuels and are abundant in cities, produced by power plants, factories, and cars. Because VOCs have a large natural source during summer over the eastern United States, for example, emission reduction plans over the last two decades in this region have focused on NOx, which is overwhelmingly produced by human activities.
Space-based methods for monitoring ozone chemistry complement surface-based measurements made by air quality management agencies. The view from space offers consistent coverage of broad areas, and provides data for regions that may not have ground stations.
This work was a collaboration of researchers at Lamont-Doherty with those at University of Rochester in New York; the Royal Netherlands Meteorological Institute in De Bilt, Netherlands; Wageningen University in Wageningen, Netherlands; Belgian Institute for Space Aeronomy in Brussels, Belgium; Harvard-Smithsonian Center for Astrophysics in Cambridge, Massachusetts; the U.S. Environmental Protection Agency Office of Research and Development in Research Triangle Park in North Carolina and its Region 8 Office in Denver Colorado; and NASA's Goddard Space Flight Center in Greenbelt, Maryland.
Jin, X., Fiore, A. M., Murray, L. T., Valin, L. C., Lamsal, L. N., Duncan, B., … Tonnesen, G. S. (2017). “Evaluating a space-based indicator of surface ozone-NOx-VOC sensitivity over midlatitude source regions and application to decadal trends.” Journal of Geophysical Research: Atmospheres, 122, 10,439–10,461. doi: 10.1002/2017JD026720