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Researchers in Korea propose graphene/Ni foam as Li metal storage medium for advanced batteries

Researchers in Korea have developed three-dimensional monolithic corrugated graphene on nickel foam electrode as a Li metal storage framework in carbonate electrolytes. Electrochemical tests reported in their paper in the Journal of Power Sources illustrate the effectiveness of this material design concept, which provides a new route to the development of a Li metal electrode for use in highly reactive electrolytes.

To expedite the commercialization of Li metal anodes by combining them with Li transition metal oxides to achieve a high operating voltage, a carbonate-based electrolyte should be used, which is unstable at low potentials. Therefore, hybrid engineering to prevent dendritic Li growth and increase the coulombic efficiency in highly reactive electrolytes is essential.

—Kang et al.

The researchers fabricated the electrode using a simple acid-catalyzed hydrothermal method involving separation of few-layer graphene sheets and formation of corrugated graphene sheets on porous Ni foam.

During the initial Li deposition, Li ions are inserted into the vertical edge plane boundaries between graphene sheets. Li metal deposits then nucleate and grow further underneath the graphene sheets.

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The corrugated graphene sheets unfold and function as an artificial solid electrolyte interphase layer that separates the Li deposits from the reactive electrolyte. Consequently, the dendritic Li growth is effectively prevented, and the coulombic efficiency is significantly improved. Li can be stably cycled for 1,000 cycles even in carbonate electrolytes.

Resources

  • Hee-Kook Kang, Sang-Gil Woo, Jae-Hun Kim, Seong-Rae Lee, Dong-Geon Lee, Ji-Sang Yu (2019) “Three-dimensional monolithic corrugated graphene/Ni foam for highly stable and efficient Li metal electrode,” Journal of Power Sources Volume 413, Pages 467-475 doi: 10.1016/j.jpowsour.2018.12.075

Comments

Engineer-Poet

We just saw the article on recycling old Li-ion carbon anodes into graphene.  Looks like this fits into the Ni-graphene scheme as a materials source.

Of course, to get graphene this way you have to make more carbon-electrode batteries and cycle them to separate the graphene layers.  Details, details.

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