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Researchers find possible new source of rare earth elements: phosphogypsum

Researchers have found a possible new source of rare earth elements—phosphate rock waste—and an environmentally friendly way to extract them, according to a study published in The Journal of Chemical Thermodynamics.

Rare earth elements such as neodymium and dysprosium are essential for technologies such as solar and wind energy and advanced vehicles, along with modern electronics like smartphones. China produces roughly 90% of all such elements.

Recovering them from phosphogypsum—waste from phosphoric acid production—is a potential solution, according to researchers at Rutgers University–New Brunswick and other members of the Critical Materials Institute, a US Department of Energy effort aimed at bolstering US supply chains for materials important to clean energy.

Each year, an estimated 250 million tons of phosphate rock are mined to produce phosphoric acid for fertilizers. The US mined approximately 28 million metric tons in 2017. Rare earth elements generally amount to less than 0.1% in phosphate rock. But worldwide, about 100,000 tons of these elements per year end up in phosphogypsum waste. That’s almost as much as the approximately 126,000 tons of rare earth oxides produced worldwide each year.

Conventional methods to extract rare earth elements from ores generate millions of tons of toxic and acidic pollutants. But instead of using harsh chemicals to extract the elements, another method might use organic acids produced by bacteria, said Paul J. Antonick and Zhichao Hu, co-lead authors of the study.

They are members of the thermodynamics team led by senior author Richard E. Riman, a Distinguished Professor in the Department of Materials Science and Engineering in Rutgers’ School of Engineering.

The research team explored using mineral and organic acids, including a bio-acid mixture, to extract six rare earth elements (yttrium, cerium, neodymium, samarium, europium and ytterbium) from synthetic phosphogypsum. Scientists led by David Reed at Idaho National Laboratory produced the bio-acid mixture—consisting primarily of gluconic acid, found naturally in fruits and honey—by growing the bacteria Gluconobacter oxydans on glucose.

The results suggest that the bio-acid did a better job extracting rare earth elements than pure gluconic acid at the same pH (2.1). The mineral acids (sulfuric and phosphoric) failed to extract any rare earth elements in that scenario. When the four acids were tested at the same concentration, only sulfuric acid was more effective than the bio-acid.

A next step would be to test bio-acid on industrial phosphogypsum and other wastes generated during phosphoric acid production that also contain rare earth elements. For their initial study, the researchers evaluated phosphogypsum made in the lab, so they could easily control its composition. Industrial samples are more complex.

Aside from Riman, Antonick and Hu, the Rutgers team included co-author Paul Kim. Also contributing to the study besides Idaho National Laboratory were researchers at OLI Systems Inc. in Cedar Knolls, New Jersey; University of California, Davis; and Lawrence Livermore National Laboratory.

Resources

  • Paul J. Antonick, Zhichao Hu, Yoshiko Fujita, David W. Reed, Gaurav Das, Lili Wu, Radha Shivaramaiah, Paul Kim, Ali Eslamimanesh, Malgorzata M. Lencka, Yongqin Jiao, Andrzej Anderko, Alexandra Navrotsky, Richard E. Riman (2019) “Bio- and mineral acid leaching of rare earth elements from synthetic phosphogypsum,” The Journal of Chemical Thermodynamics, Volume 132, Pages 491-496 doi: 10.1016/j.jct.2018.12.034

Comments

Engineer-Poet

Rare earths aren't the only byproduct of phosphate mining.  Phosphogypsum emits radon, which is the direct decay product of radium.  All of this comes from decay of the original uranium.  It appears likely to me that the rare earths are also associated with thorium.

Phosphogypsum has been mined for uranium, and processing to recover rare earths without also extracting the uranium seems wasteful to me.  The USA gets most of its uranium from places like Kazakhstan and more domestic resources would be welcome.  (Of course, switching to a breeder reactor economy would allow the use of the massive inventory of depleted uranium currently sitting around being useless and could power the country for the next several centuries without importing or mining another gram.)

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