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New superionic conductor could result in highest energy density solid-state batteries to date

Scientists from Tohoku University and the High Energy Accelerator Research Organization have developed a new complex hydride lithium superionic conductor that could result in all-solid-state batteries with the highest energy density to date. An open-access paper on the work is published in Nature Communications.

The researchers say the new material, achieved by designing structures of hydrogen clusters (complex anions), shows markedly high stability against lithium metal, which would make it the ultimate anode material for all-solid-state batteries.

Research_30190322_image1

High-energy-density all-solid-state lithium metal battery employing complex hydrides. Credit: Sangryun Kim and Shin-ichi Orimo.

All-solid-state batteries incorporating lithium metal anode have the potential to address the energy density issues of conventional lithium-ion batteries that use flammable organic liquid electrolytes and low-capacity carbonaceous anodes. However, they suffer from high lithium ion transfer resistance, mainly due to the instability of the solid electrolytes against lithium metal, limiting their use in practical cells.

Here, we report a complex hydride lithium superionic conductor, 0.7Li(CB9H10)–0.3Li(CB11H12), with excellent stability against lithium metal and a high conductivity of 6.7 × 10−3 S cm−1 at 25 °C. This complex hydride exhibits stable lithium plating/stripping reaction with negligible interfacial resistance (<1 Ω cm2) at 0.2 mA cm−2, enabling all-solid-state lithium-sulfur batteries with high energy density (>2500 Wh kg−1) at a high current density of 5016 mA g−1.

—Kim et al.

All−solid−state batteries are promising candidates for resolving the intrinsic drawbacks of current lithium−ion batteries, such as electrolyte leakage, flammability and limited energy density.

Lithium metal is widely believed to be the ultimate anode material for all−solid−state batteries because it has the highest theoretical capacity (3860 mAh g−1) and the lowest potential (−3.04 V vs. standard hydrogen electrode) among known anode materials.

Lithium-ion-conducting solid electrolytes are a key component of all-solid-state batteries because the ionic conductivity and stability of the solid electrolyte determine battery performance.

The problem has been that most existing solid electrolytes have chemical/electrochemical instability and/or poor physical contact against lithium metal, inevitably causing unwanted side reactions at the interface. These side reactions result in an increase in interfacial resistance, greatly degrading battery performance during repeated cycling.

As revealed by previous studies, which proposed strategies such as alloying the lithium metal and interface modification, this degradation process is very difficult to address because its origin is the high thermodynamic reactivity of the lithium metal anode with the electrolyte.

The main challenges to using the lithium metal anode are high stability and high lithium ion conductivity of the solid electrolyte.

Complex hydrides have received a lot of attention in addressing the problems associated with the lithium metal anode because of their outstanding chemical and electrochemical stability against the lithium metal anode. But because of their low ionic conductivity, using complex hydrides with the lithium metal anode have never been attempted in practical batteries. So we were very motivated to see if developing complex hydride that exhibit lithium superionic conductivity at room temperature can enable the use of lithium metal anode. And it worked.

—Sangryun Kim, lead and co-corresponding author

The Tohoku University research team was led by Sangryun Kim from the Institute of Material Research (IMR) and Shin-ichi Orimo from the Advanced Institute for Materials Research (AIMR). Members included Dorai Arunkumar, Naoaki Kuwata and Junichi Kawamura from the university’s Institute of Multidisciplinary Research for Advanced Materials (IMRAM), as well as Toshiya Otomo from the High Energy Accelerator Research Organization.

Resources

  • Sangryun Kim, Hiroyuki Oguchi, Naoki Toyama, Toyoto Sato, Shigeyuki Takagi, Toshiya Otomo, Dorai Arunkumar, Naoaki Kuwata, Junichi Kawamura, and Shin-ichi Orimo (2019) “A complex hydride lithium superionic conductor for high−energy−density all−solid−state lithium metal batteries” Nature Communications doi: 10.1038/s41467-019-09061-9

Comments

yoatmon

".....enabling all-solid-state lithium-sulfur batteries with high energy density (>2500 Wh kg−1)".
That would be 2.5 kWh / kg or a battery with a weight of 100 kg = 100kg x 2.5kWh = 250 kWh. Now, if that could be had for a reasonable price, say $100.00 / kwh? My only remaining question would be, how soon can all that be ramped up for mass production? I'll have it!

Centurion

Colosal, una batería de ¡¡¡2,5kwh/kg!!!. Con esta batería el paradigma mundial cambiaría para siempre se podría utilizar en todos los medios: Transporte terrestre, aereo y maritimo todo a la vez........Demasiado epico para poder verlo algún día, hay demasiados intereses ocultos para que jamas llegue a comercializarse pero me emocina ver que hay tecnología que puede hacerla posible.......

avada

@yoatmon
That part's surely a pipe-dream. Using a sulfur cathode is a whole different beast altogether. Which is also unsolved, and might remain as such, since their main problem is that sulfur doesn't conduct electricity.

Kind of silly of them to mix it in with this about solid electrolytes.

yoatmon

Well, I could imagine that bucky balls mixed with that sulphur would really get those horses galloping; and they are an excellent conductor.

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