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New organic cathode for high performance solid-state sodium-ion battery

Solid-state sodium-ion batteries are safer than conventional lithium-ion batteries, which pose a risk of fire and explosions, but their performance has been too weak to offset the safety advantages. Researchers at the University of Houston have now developed an organic cathode that improves both stability and energy density.

The improved performance, reported in the journal Joule, is related to two key findings:

  • The resistive interface between the electrolyte and cathode that commonly forms during cycling can be reversed, extending cycle life; and

  • The flexibility of the organic cathode allowed it to maintain intimate contact at the interface with the solid electrolyte, even as the cathode expanded and contracted during cycling.

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The organic cathode demonstrated here is (electro)chemically and mechanically compatible with a sulfide electrolyte. Its moderate redox potential enables the reversible formation of a resistive active material-electrolyte interface. Credit: University of Houston.

Yan Yao, associate professor of electrical and computer engineering at the University of Houston and corresponding author of the paper, said the organic cathode—known as PTO, for pyrene-4,5,9,10-tetraone—offers unique advantages over previous inorganic cathodes. But he said the underlying principles are equally significant.

We found for the first time that the resistive interface that forms between the cathode and the electrolyte can be reversed. That can contribute to stability and longer cycle life.

—Yan Yao

Yao also is a principal investigator at the Texas Center for Superconductivity at UH. His research group focuses on green and sustainable organic materials for energy generation and storage.

Yanliang “Leonard” Liang, a research assistant professor in the UH Department of Electrical and Computer Engineering, said that reversibility of the interface is the key, allowing the solid-state battery to reach a higher energy density without sacrificing cycle life. Normally, a solid-state battery’s ability to store energy is halted when the resistive cathode?electrolyte interface forms; reversing that resistance allows energy density to remain high during cycling, he said.

Xiaowei Chi, a post-doctoral researcher in Yao’s group, said a key challenge had been to find a solid electrolyte that is as conductive as the liquid electrolytes used in lithium-ion batteries. Now that sufficiently conductive solid electrolytes are available, a remaining challenge has been the solid interfaces.

One issue raised by a solid electrolyte: the electrolyte struggles to maintain intimate contact with a traditional rigid cathode as the latter expands and contracts during battery cycling. Fang Hao, a PhD student working in Yao’s group, said the organic cathode is more pliable and thus able to remain in contact with the interface, improving cycling life. The researchers said the contact remained steady through at least 200 cycles.

In addition to Yao, authors include co-first authors Hao and Chi, Liang, Ye Zhang and Hui Dong, all of UH; Rong Xu and Kejie Zhao of Purdue University; and Hua Guo, Tanguy Terlier and Jun Lou of Rice University. The majority of this work was funded by the US Department of Energy’s Advanced Research Projects Agency-Energy (ARPA-E).

Resources

  • Hao et al. (2019) “Taming Active Material-Solid Electrolyte Interfaces with Organic Cathode for All-Solid-State Batteries” Joule doi: 10.1016/j.joule.2019.03.017

Comments

gryf

From the source:The PTO-based cells exhibit a high specific energy (587 Wh kg −1) and a record cycling stability (500 cycles).

An All Solid-state sodium-ion batteries (ASSSB) looks like something worth pursuing,
particular one like this that uses earth abundant elements.

Engineer-Poet

It only takes one serious breakthrough to change the entire landscape.  Maybe this is it; we can hope.

SJC

90-115 Wh/kg was the previous specification.
https://en.wikipedia.org/wiki/Sodium-ion_battery

gryf

@SJC
The Wikipedia references are to typical Sodium Ion batteries that have a hard graphite anode, liquid electrolyte, and a metal oxide cathode (Faradion uses a Nickel oxide and Tiamat - the startup based on RS2E research uses a Titanate cathode).
This is a Solid-State Sodium battery.

Engineer-Poet

If you look up the molecular information on pyrene, you find that it's a tetra-cyclic molecule with the formula C16H10.  Ketones like acetone have double-bonded oxygen atoms.  Where the oxygens go to make PTO a tetra-one I can't figure out easily.

Pryene is highly toxic and an environmental hazard and PTO probably is also.  This may not be the molecule we're looking for.

SJC

Yes, I understand it is solid, I wanted to compare it to previous versions.

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