An international research group has improved graphene’s ability to catalyze the hydrogen evolution reaction, which releases hydrogen as a result of passing an electronic current through water. They designed a mathematically-predicted graphene electrocatalyst, and confirmed its performance using high resolution electrochemical microscopy and computational modelling. The findings were published in an open access paper in the journal Advanced Science.

Akichika Kumatani of Tohoku University’s Advanced Institute for Materials Research (AIMR), Tatsuhiko Ohto of Osaka University, Yoshikazu Ito of Tsukuba University and colleagues in Japan and Germany found that adding nitrogen and phosphorus dopants around the well-defined edges of graphene holes enhanced its ability to electrocatalyze the hydrogen evolution reaction.

Graphene-based catalysts have an advantage over metal-based ones in that they are stable and controllable, making them suitable for use in fuel cells, energy storage and conversion devices, and in water electrolysis. Their properties can be improved by making multiple simultaneous changes to their structures. However, scientists need to be able to see these changes at the nanoscale in order to understand how they work together to promote catalysis.

Kumatani and his colleagues used the recently developed scanning electrochemical cell microscopy (SECCM) for direct, sub-microscale observation of the electrochemical reactions that happen when current is passed through water during electrolysis. It also allowed them to analyze how structural changes in graphene electrocatalysts affect their electrochemical activities. This type of observation is not possible using conventional approaches.

The team synthesized an electrocatalyst made from a graphene sheet full of mathematically predicted holes with well-defined edges. The edges around the holes increase the number of active sites available for chemical reactions to occur. They doped the graphene sheet by adding nitrogen and phosphorus atoms around hole edges. The graphene-based electrocatalyst was then used to enhance the release of hydrogen during electrolysis.

Using SECCM, the team found that their graphene electrocatalyst significantly improved the formation of a current in response to energy release during electrolysis. Their computational calculations suggest that adding nitrogen and phosphorus dopants enhances the contrast of positive and negative charges on the atoms surrounding hole edges, boosting their ability to transport an electric current.

Nitrogen- and phosphorus-doped holey graphene electrocatalysts worked better than those doped with only one of the two chemical elements.

These findings pave a path for atomic-level engineering of the edge structure of graphene in graphene-based electrocatalysts through the local visualization of electrochemical activities.

—Kumatani et al.

Resources

• A. Kumatani, C. Miura, H. Kuramochi, T. Ohto, M. Wakisaka, Y. Nagata, H. Ida, Y. Takahashi, K. Hu, S. Jeong, J.-i. Fujita, T. Matsue, Y. Ito (2019) “Chemical Dopants on Edge of Holey Graphene Accelerate Electrochemical Hydrogen Evolution Reaction” Advanced Science doi: 10.1002/advs.201900119