Cambridge researchers develop standalone device that makes formic acid from sunlight, CO2 and water
24 August 2020
Researchers at the University of Cambridge, with colleagues at the University of Tokyo, have developed a standalone device that converts sunlight, carbon dioxide and water into formic acid, a carbon-neutral fuel, without requiring any additional components or electricity.
The device is a significant step toward achieving artificial photosynthesis—a process mimicking the ability of plants to convert sunlight into energy. The device is based on an advanced ‘photosheet’ technology and converts sunlight, carbon dioxide and water into oxygen and formic acid—a storable fuel that can be either be used directly or be converted into hydrogen.
The results, reported in the journal Nature Energy, represent a new method for the conversion of carbon dioxide into clean fuels. The wireless device could be scaled up and used on energy farms similar to solar farms, producing clean fuel using sunlight and water.
Harvesting solar energy to convert carbon dioxide into fuel is a promising way to reduce carbon emissions and transition away from fossil fuels. However, it is challenging to produce these clean fuels without unwanted by-products.
It’s been difficult to achieve artificial photosynthesis with a high degree of selectivity, so that you’re converting as much of the sunlight as possible into the fuel you want, rather than be left with a lot of waste.—first author Dr Qian Wang from Cambridge’s Department of Chemistry
In addition, storage of gaseous fuels and separation of by-products can be complicated—we want to get to the point where we can cleanly produce a liquid fuel that can also be easily stored and transported.—senior author Professor Erwin Reisner
In 2019, researchers from Reisner’s group developed a solar reactor based on an artificial leaf design, which also uses sunlight, carbon dioxide and water to produce a fuel, known as syngas. The new technology looks and behaves quite similarly to the artificial leaf but works in a different way and produces formic acid.
While the artificial leaf used components from solar cells, the new device doesn’t require these components and relies solely on photocatalysts embedded on a sheet to produce a so-called photocatalyst sheet. The sheets are made up of semiconductor powders, which can be prepared in large quantities easily and cost-effectively.
In addition, this new technology is more robust and produces clean fuel that is easier to store and shows potential for producing fuel products at scale. The test unit is 20 square centimeters in size, but the researchers say that it should be relatively straightforward to scale it up to several square meters. In addition, the formic acid can be accumulated in solution, and be chemically converted into different types of fuel.
We were surprised how well it worked in terms of its selectivity—it produced almost no by-products. Sometimes things don’t work as well as you expected, but this was a rare case where it actually worked better.—Dr Wang
The carbon-dioxide converting cobalt-based catalyst is easy to make and relatively stable. While this technology will be easier to scale up than the artificial leaf, the efficiencies still need to be improved before any commercial deployment can be considered. The researchers are experimenting with a range of different catalysts to improve both stability and efficiency.
The current results were obtained in collaboration with the team of Professor Kazunari Domen from the University of Tokyo, a co-author of the study.
The researchers are now working to further optimise the system and improve efficiency. Additionally, they are exploring other catalysts for using on the device to get different solar fuels.
Qian Wang et al. (2020) “Molecularly engineered photocatalyst sheet for scalable solar formate production from carbon dioxide and water.” Nature Energy doi: 10.1038/s41560-020-0678-6
From the abstract linked for the paper:
' The monolithic device provides a solar-to-formate conversion efficiency of 0.08 ± 0.01% with a selectivity for formate of 97 ± 3%'
That efficiency rate sounds like a goer to me, as the land is cheapest with most solar incidence in remote locations, and formic acid is way easier to transport than electricity, which is expensive to transmit, and even than hydrogen, which is ten times cheaper to pipeline over 1000 km.
Posted by: Davemart | 25 August 2020 at 01:25 AM