A new hydrocarbon study led by researchers at Los Alamos National Laboratory contradicts conventional wisdom about how methane is trapped in rock, revealing a new strategy to access the valuable energy resource more easily. Their open-access study is published in Nature’s new Communications Earth & Environment journal.

Partners include the New Mexico Consortium, University of Maryland, and the National Institute of Standards and Technology Center for Neutron Research.

The most challenging issue facing the shale energy industry is the very low hydrocarbon recovery rates: less than 10% for oil and 20% for gas. Our study yielded new insights into the fundamental mechanisms governing hydrocarbon transport within shale nanopores. The results will ultimately help develop better pressure management strategies for enhancing unconventional hydrocarbon recovery.

—Hongwu Xu, an author from Los Alamos National Laboratory’s Earth and Environmental Sciences Division

Most of US natural gas is hidden deep within shale reservoirs. Low shale porosity and permeability make recovering natural gas in tight reservoirs challenging, especially in the late stage of well life. The pores are miniscule—typically less than five nanometers—and poorly understood.

Understanding the hydrocarbon retention mechanisms deep underground is critical to increase methane recovering efficiency. Pressure management is a cheap and effective tool available to control production efficiency that can be readily adjusted during well operation—but the study’s multi-institution research team discovered a trade-off.

This team, including the lead author, Chelsea Neil, also of Los Alamos, integrated molecular dynamics simulations with novel in situ high-pressure small-angle neutron scattering (SANS) to examine methane behavior in Marcellus shale in the Appalachian basin, the nation’s largest natural gas field, to better understand gas transport and recovery as pressure is modified to extract the gas. The investigation focused on interactions between methane and the organic content (kerogen) in rock that stores a majority of hydrocarbons.

The study’s findings indicate that while high pressures are beneficial for methane recovery from larger pores, dense gas is trapped in smaller, common shale nanopores due to kerogen deformation. For the first time, they present experimental evidence that this deformation exists and proposed a methane-releasing pressure range that significantly impacts methane recovery.

Proposed mechanism for dense methane trapping in nanopores within the kerogen matrix. At higher pressures (6000 psi), irreversible deformation of the kerogen matrix results in methane retention in pores even after pressure drawdown. Neil et al.

These insights help optimize strategies to boost natural gas production as well as better understand fluid mechanics.

Methane behavior was compared during two pressure cycles with peak pressures of 3000 psi and 6000 psi, as it was previously believed that increasing pressure from injected fluids into fractures would increase gas recovery. The team discovered that unexpected methane behavior occurrs in very small but prevalent nanopores in the kerogen: the pore uptake of methane was elastic up to the lower peak pressure, but became plastic and irreversible at 6,000 psi, trapping dense methane clusters that developed in the sub-2 nanometer pore, which encompass 90 percent of the measured shale porosity.

This work was supported by the Department of Energy’s Office of Fossil Energy, the National Energy Technology Laboratory and the Los Alamos National Laboratory Laboratory Directed Research and Development (LDRD) program.

Resources

• Chelsea W. Neil, Mohamed Mehana, Rex P. Hjelm, Marilyn E. Hawley, Erik B. Watkins, Yimin Mao, Hari Viswanathan, Qinjun Kang, and Hongwu Xu (2020) “Reduced methane recovery at high pressure due to methane trapping in shale nanopores” Communications Earth & Environment doi: 10.1038/s43247-020-00047-w