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Cornell team develops aluminum-anode batteries with up to 10,000 cycles

Cornell researchers led by Lynden Archer, the Joseph Silbert Dean of Engineering and the James A. Friend Family Distinguished Professor of Engineering, have been exploring the use of low-cost materials to create rechargeable batteries that will make energy storage more affordable. These materials could also provide a safer and more environmentally friendly alternative to lithium-ion batteries.

The group previously demonstrated the potential of zinc-anode batteries. Now, they have employed a different approach for incorporating aluminum, resulting in rechargeable batteries that offer up to 10,000 error-free cycles. A paper on the work is published in Nature Energy.

0405_aluminum2

This magnified image shows aluminum deposited on carbon fibers in a battery electrode. The chemical bond makes the electrode thicker and its kinetics faster, resulting in a rechargeable battery that is safer, less expensive and more sustainable than lithium-ion batteries.


A very interesting feature of this battery is that only two elements are used for the anode and the cathode—aluminum and carbon—both of which are inexpensive and environmentally friendly. They also have a very long cycle life. When we calculate the cost of energy storage, we need to amortize it over the overall energy throughput, meaning that the battery is rechargeable, so we can use it many, many times. So if we have a longer service life, then this cost will be further reduced.

—lead author Jingxu (Kent) Zheng, currently a postdoc at MIT

Among the advantages of aluminum is that it is abundant in the earth’s crust, it is trivalent and light, and it therefore has a high capacity to store more energy than many other metals. However, aluminum can be tricky to integrate into a battery’s electrodes. It reacts chemically with the glass fiber separator, which physically divides the anode and the cathode, causing the battery to short circuit and fail.

The researchers’ solution was to design a substrate of interwoven carbon fibers that forms an even stronger chemical bond with aluminum. When the battery is charged, the aluminum is deposited into the carbon structure via covalent bonding, i.e., the sharing of electron pairs between aluminum and carbon atoms.

While electrodes in conventional rechargeable batteries are only two dimensional, this technique uses a three-dimensional—or nonplanar—architecture and creates a deeper, more consistent layering of aluminum that can be finely controlled.

Basically we use a chemical driving force to promote a uniform deposition of aluminum into the pores of the architecture. The electrode is much thicker and it has much faster kinetics.

—Jingxu Zheng

The aluminum-anode batteries can be reversibly charged and discharged one or more orders of magnitude more times than other aluminum rechargeable batteries under practical conditions.

Although superficially different from our earlier innovations for stabilizing zinc and lithium metal electrodes in batteries, the principle is the same— substrates that provide a large thermodynamic driving force that promotes nucleation; and runaway, unsafe growth of the metal electrode is prevented by forces such as surface tension that can be massive at small scales.

—Lynden Archer, senior author

The research was supported by the US Department of Energy Basic Energy Sciences Program through the Center for Mesoscale Transport Properties, an Energy Frontiers Research Center, hosted at Stony Brook University. The researchers made use of the Cornell Center for Materials Research, which is supported by the National Science Foundation’s Materials Research Science and Engineering Center program.

Resources

  • Zheng, J., Bock, D.C., Tang, T. et al. (2021) “Regulating electrodeposition morphology in high-capacity aluminium and zinc battery anodes using interfacial metal–substrate bonding.” Nat Energy doi: 10.1038/s41560-021-00797-7

Comments

mahonj

A few more numbers would be nice, but maybe it is too soon for that.
10,000 cycles is very impressive. You could get a daily charge cycle for 27 years.

Davemart

@mahonj

I could not find the assumed depth of discharge etc, so I don't really know how to evaluate it.

SJC

only two elements are used for the anode and the cathode—aluminum and carbon...

gryf

Basically, an Aluminum Ion battery. Many researchers including ORNL, Stanford (Hongjie Dai), Cornell, Nebraska (article:"Ultra-fast charging in aluminum-ion batteries: electric double layers on active anode",https://doi.org/10.1038/s41467-021-21108-4).
The theoretical energy density potential for aluminum-ion batteries is 1060 Wh/kg in comparison to lithium-ion's 406 Wh/kg limit. (reference: Wikipedia).

SJC

design a substrate of interwoven carbon fibers...
When the battery is charged, the aluminum is deposited into the carbon structure...
brilliant!

SJC

Al-ion battery retains 92% capacity after 250,000 charge cycles
https://www.elektormagazine.com/news/al-ion-battery-with-92-capacity-after-250-000-charge-cycles

mahonj

Lets hope something comes of it.
How many other obstacles have they got to overcome until they have a workable battery?
I am not being cynical, but every few months we see a new battery or battery breakthrough, and meanwhile batteries are improving at something like 10% / annum, which is rather pedestrian.
[ If someone has a better figure than 10%/annum, I will accept it. ]

SJC

250,000 charge cycles is projected, it would take 30 years to test.

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