TUHH study compares F-T and methanol pathways for SAF production
04 March 2024
A team at Hamburg University of Technology (TUHH) has compared the Fischer-Tropsch (FT) and methanol pathways for the production of Sustainable Aviation Fuels (SAF) derived from renewable energy sources.
The results, published in an open-access paper in the journal Fuel, show a very high carbon efficiency of the FT pathway (98 to 99%) regarding the total liquid products, while the carbon efficiency regarding kerosene lies between 60 and 77%.
For the methanol pathway, a higher kerosene carbon efficiency can be achieved (60 to 90%); however, the total product efficiency (74 to 92%) is notably lower.
The energy efficiencies of both pathways behave similarly to carbon efficiency, with the methanol pathway benefiting from thermodynamic advantages, leading to higher energy efficiency at equal carbon efficiency.
Within the FT pathway, kerosene efficiency increases at high chain growth probabilities, while a high olefin-selectivity is crucial for efficient kerosene production within the methanol pathway.
Resources
Stefan Bube, Nils Bullerdiek, Steffen Voß, Martin Kaltschmitt (2024) “Kerosene production from power-based syngas – A technical comparison of the Fischer-Tropsch and methanol pathway,” Fuel, doi: 10.1016/j.fuel.2024.131269
I've been trying to get my head around biofuels as I am deeply sceptical about the aircraft industries plans for expansion when they seem to have no credible plans in place to restrict let alone decrease GHG, with the great hope being SAF, and even that they plan in a 50% only mix for the foreseeable future.
There is this study of biofuels from lignin just out:
https://newenergyandfuel.com/http:/newenergyandfuel/com/2024/02/29/research-says-biomass-pretreatment-makes-biofuel-practical/
' According to the Department of Energy, up to a billion tons per year of biomass could be made available for the manufacture of biofuels and bioproducts in the US alone, capable of displacing 30% of our petroleum consumption while also creating new domestic jobs.
Because a CELF biorefinery can more fully utilize plant matter than earlier second-generation methods, the researchers found that a heavier, denser feedstock like hardwood poplar is preferable over less carbon-dense corn stover for yielding greater economic and environmental benefits.
Using poplar in a CELF biorefinery, the researchers demonstrate that sustainable aviation fuel could be made at a break-even price as low as $3.15 per gallon of gasoline equivalent. The current average cost for a gallon of jet fuel in the U.S. is $5.96.'
Looking through the linked paper, I could not spot whether this cost is factory gate or delivered, as the output of lots of refineries would be needed to provide fuel for one major international airport.
Having said that, once you have the liquid fuel, moving that is way cheaper than lugging around the initial trees etc, so the difference is not perhaps critical, as in theory at least there is quite a bit of headroom to be economic against jet fuel.
Remaining concerns are about sensible exploitation to retain soil fertility, instead of basically strip mining regardless.
Posted by: Davemart | 04 March 2024 at 03:31 AM
@Dave, as you say, soil fertility is an issue - if you take too much, you risk wrecking the soil. I wonder is it possible to put some of the ash back into the soil as a "refertiliser"?
Posted by: mahonj | 04 March 2024 at 07:18 AM
Hi Jim:
There are others here who will know way more about biofuels than I, as in a reaction similar to that which some others on this blog have regarding fossil fuel extraction, where regardless of how it theoretically could be practise is so awful that it is tempting to dismiss it entirely, I looked at corn use, which however dubious in energy terms was a magnificent mechanismg for extracting and exploiting subsidies, and gave up.
The bottom line would appear to be that there is substantial room for production without overstepping the boundaries of what needs to be returned to the soil to retain fertility, but I have not got a handle on where those boundaries are in relation to the projected output of SAF.
Basically it seems to me to be insanity to allow long distance air travel, a luxury item to continue to grow, when there is no sort of control of emissions, so from that position it is difficult to make an even handed assessment of the best options if we are going to do that anyway.
Lignin, seaweed or some such would seem likely to have least impact on soil fertility, deprivation of the hungry to provide jet fuel and so on, but hopefully others with infinitely more knowlege of and grasp of what is going on in the use of biological resources for energy will share some of their insights, as I have not really either read up on it, or can claim to have any sort of impartial grasp as I thought what was actually going on was so yucky.
Posted by: Davemart | 04 March 2024 at 07:43 AM
According to an Argonne National Laboratory study (Cradle-to-Grave Lifecycle Analysis of U.S. Light-Duty Vehicle-Fuel Pathways: A Greenhouse Gas Emission and Economic Assessment of Current (2020) and Future (2030-2035) Technologies), up to half of corn stover can sustainably be removed without causing erosion or soil quality issues (page 21).
There is actually a desperate need for a market for forest fuel removal (e.g., thinning), which could be at least partially met by using the forest wastes for fuels. At least one biorefinery is currently producing forest waste-to-fuels - https://www.redrockbio.com/ .
Posted by: Carl | 04 March 2024 at 07:55 AM
Regarding the use of forest resources as feedstock for methanol, the development of Coppice sylvicuture [felling one acre plots of trees young and regrowing them from the stumps] avoids exhausting the soil. This is due to the trees biological clocks being reset at harvest, with the root ball thriving if it carries less than 28 years of growth. The oldest such tree known is a coppice hazel near Ashford in Kent, UK, that has been regularly coppiced since it was germinated during the Roman occupation.
With no disruption of the soil by heavy machinery, by roots' extraction or even by replanting, and with routinely high biodiversity bringing nutrients to the coppice woodlands, the soils are not being degraded in well managed coppices.
Regarding the use of methanol as a feedstock for SAF, there are so many severe strikes against the latter's "sustainability" that its commercial proponents really should be indicted for greenwashing fraud. Moreover, I've yet to see any account of the final fuel costs showing methanol-based synthetic kerosene jet fuel to be cheaper than using methanol in "Methanol Reformer Fuel Cells" on planes to drive their electric motors.
Those with fleets of kerosene-burning jet planes may prefer the temporary illusion of keeping their assets' value . . . . .
Posted by: Lewis Cleverdon | 04 March 2024 at 09:28 AM
It depends on what they mean by carbon efficiency, if they mean you end up with something with carbon in it even though you have no use for it then it's part of the efficiency. As I understand it the FT process makes paraffin, then you have to refine that into something like fuels, the overall process is not that efficient.
Carl is right the consensus in agriculture is you can take half of the biomass off the land and still have plenty for the land, considering how much corn stover we have and how much wheat straw we have hundreds of millions of acres is a lot of biocarbon to put to use.
Posted by: SJC | 04 March 2024 at 09:40 AM
After looking at the term carbon efficiency it has more to do with economics than chemistry it says I can emit a lot of fossil carbon but if I do a lot of good for the economy then it's more efficient that's a completely BS metric.
Posted by: SJC | 04 March 2024 at 09:47 AM
Looks like an average of 32 tons/acre can be harvested from forest thinning - https://www.forest2market.com/blog/how-many-tons-of-wood-are-on-an-acre-of-land.
Posted by: Carl | 04 March 2024 at 09:53 AM
In this context carbon efficiency is phony accounting, it does not take into consideration the damage that fossil carbon does to the environment, droughts, floods, hail, crop failures, property damage are all unaccounted for. It may seem efficient to the GDP but they haven't considered all factors, thus it's bogus.
Posted by: SJC | 04 March 2024 at 10:35 AM
@SJC
Just so.
Fake capitalist accounting, as opposed to the genuine Adam Smith variety, treats externalised costs as 'no cost'
That is entirely untrue, and is in reality 'unaccounted for' costs.
So dumping GHG in the atmosphere costs enormous sums, it is just that those responsible for it do not pay for it, everyone else does.
Posted by: Davemart | 04 March 2024 at 11:57 AM
Just in a new analysis showing how unrealistic Direct Air Capture is using anything other than biological means:
https://techxplore.com/news/2024-03-air-carbon-capture-higher.html
' ETH researchers have developed a new method that provides a more accurate estimate of the future cost of various DAC technologies. As the technologies are scaled up, direct air capture will become significantly cheaper—though not as cheap as some stakeholders currently anticipate. Rather than the oft-cited figure of 100 to 300 U.S. dollars, the researchers suggest the costs are more likely to be between 230 and 540 dollars.'
This is quite simply complete cobblers, and a ploy to extract funds for a useless technology, useless that is apart from as a very flimsy cover story for the expansion of long distance GHG belching aircraft for instance.
DAC is not going to come to the rescue from this insanity.
Posted by: Davemart | 05 March 2024 at 03:34 AM
Davemart - well said.
To my mind the next questions are about :
- which of the biological means of Carbon Recovery are demonstrably sustainable in terms both of biodiversity and of human food security,
- and which face a minimum threat from climate impacts,
- and which are potentially both partly self-funding and socially benign.
These questions are what drives my focus on biochar and methanol produced from Native Coppice Forestry. If there are better options, I would like to learn of them.
Posted by: Lewis Cleverdon | 05 March 2024 at 05:48 AM
By reusing fossil carbon you reduce the emission of fossil carbon to the atmosphere.
Posted by: SJC | 05 March 2024 at 06:37 AM
This is one of the most easy effective methods to reduce fossil carbon in the atmosphere, sequester power plant carbon, make synthetic fuels using renewable hydrogen. That will cut fossil carbon emissions into the atmosphere in half.
Posted by: SJC | 05 March 2024 at 06:45 AM
I think that biofuel production should be considered in the framework of the total human demand on the biosphere rather than simply in the narrow framework of how to preserve a "healthy" jet tourism industry with a minimum impact on the biosphere. Agriculture, cotton and other fiber crops, stock raising, lumber and paper production, are already putting large demands on the biosphere and with the human population still rising these demands could increase substantially over the next several decades unless we put a strong emphasis on lowering the per capita demand on the biosphere of the earth's most highly developed economies. Any new biofuel industry needs to be considered in this context. Coppicing may be less ecologically demanding than the cut and replant practices of the lumber and paper industries (any references?) but it still removes nutrients from the soil and it presumably has a negative impact on bio-diversity compared to natural forests.
Posted by: Roger Brown | 05 March 2024 at 07:26 AM
Roger, I'd fully agree that aviation has no special right to draw on limited green fuel supplies, and that their production has to be viewed as part of the whole resource utilization imposed on the ecosphere. For a start if, as SAF proponents intend, green fuels were used as feedstock for synthetic jet fuel, they would actually result in harmful emissions of GHG, particulates, and vapour trails. It needs saying that the better option is to use green methanol in aircrafts' Methanol Reformer Fuel Cells, but those will also need to be fuelled in road-freight vehicles, railways, farm machinery and shipping.
The merits of Native Coppice Forestry are widely known in Europe but apparently not in the USA - perhaps having been lost during colonisation. When well tended, for instance by only harvesting during winter dormancy and ensuring that the twigs holding most of the trees' trace elements are left to rot down, they can thrive on poor soils for centuries.
A particular coppice regime is commonly applied which not only raises growth-rates and so harvests, but also accommodates exceptional biodiversity - which doubtless raises the long-term soil health. As the renowned ecologist, Prof. Alastair Fitter, CBE. FRS, reported in 1994, "In-cycle coppice holds the highest biodiversity of any European ecosystem." This is due to the cyclic harvesting regime (between ~7 and 28 years) that fells plots of an acre or so scattered across the woodland, (thereby retaining as much wind-shelter as possible for new growth) and cuts another set each year until the first have fully regrown to be ready for another harvest.
This regime has remarkable effects in terms of the migration of insolation to the woodland floor, as the canopy is opened when a plot is felled and then steadily closes over during the regrowth cycle. This means that a wide range of species thriving in different light levels are supported, along with their symbionts and others, which in turn attract diverse herbivores and predators.
I should add that while I've not seen any justification for using farmland for crops to make into fuels - with the inevitable consequent pressure to clear old forest for more farmland - globally there are very large tonnages of biomass crop wastes that are wasted each year by rotting or burning. Even those which are ploughed in will rot down and outgas their CO2 inside two years or so. With the onset of Regenerative Agriculture putting a new focus on the soils' ecology, better ways of improving soil carbon content are being phased in - which means that rising volumes of biomass crop wastes will be available for methanol production. Their one downside is that they generally cannot provide a charcoal suitable for durable biochar.
Posted by: Lewis Cleverdon | 05 March 2024 at 11:10 AM
'A key solution for carbon capture and storage is under our feet. We're investigating the interactions between plants, microbes, and geological features in soil with the goal of using healthy soil ecosystems to pull carbon from the atmosphere and stash it underground for a long time, at a low cost.'
https://phys.org/news/2024-03-video-stashing-carbon-haul-healthy.html
The video is well worth a look.
These guys are doing the grunt work of sorting out how carbon storage actually happens, so it is seminal to whatever we do in future.
Posted by: Davemart | 05 March 2024 at 12:07 PM
Lewis,
Thank you for the information. Is there any reason why the paper industry could not use coppicing?
Posted by: Roger Brown | 05 March 2024 at 12:53 PM