Topsoe and Sasol launch Zaffra JV to focus on SAF
18 March 2024
Sasol and Topsoe have launched their joint venture, Zaffra. (Earlier post.) With its headquarters based in Amsterdam, The Netherlands, Zaffra is focusing on the development and delivery of Sustainable Aviation Fuel (SAF).
Zaffra combines the extensive experience of Sasol in asset development, plant construction, and robust operating and technology expertise and Topsoe’s proven carbon emission reduction technologies.
Sasol and Topsoe have been strategic partners for more than 25 years in producing synthetic fuels. The formation of Zaffra marks Sasol’s move from being a technology provider to a producer of SAF.
Wow! Hydrogen by electrolysis, and Direct Air Capture!
Somehow I think SAF from this might be a tad expensive.
There is this now in on a new more energy efficient method of DAC:
https://techxplore.com/news/2024-03-moisture-carbon-dioxide-air.html
'Despite its promise, direct air capture has come under scrutiny since it requires more energy to perform than almost any other application of carbon capture. That is because the concentration of carbon dioxide in ambient air is extremely diluted, especially when compared to the waste gas from a point-source emitter such as a coal-fired power plant.
One of the process' most energy-intensive steps is regeneration. After capturing carbon dioxide from ambient air, conventional systems require heat and/or pressure changes to release the gas into storage so that the system can be prepared to capture more carbon. In one approach using a liquid solvent, the regeneration step requires heating the carbon capture material to temperatures ranging from 300° to 900°C.
By contrast, previous research has shown that regenerating carbon capture materials with humidity only requires adding or removing water vapor. Such an approach dramatically cuts the energy required to remove a ton of carbon dioxide, from up to 4.1 gigajoules using conventional techniques to just 0.7 gigajoules—an energy savings per ton greater than the energy used by the average U.S. household in a month.'
Having looked at the figures for DAC, and considering that this only mitigates ' One of the process' most energy-intensive steps' it seems that this may only reduce the cost from the utterly absurd to the completely unaffordable, but we will see.
Posted by: Davemart | 18 March 2024 at 01:59 AM
If you use sequestered fossil carbon and agricultural waste bio-carbon along with good renewable hydrogen made of wind and solar electricity in tubular SOECs, we can make plenty of SAF
Posted by: SJC | 18 March 2024 at 07:02 AM
@SJC:
Maybe, but I have not as yet seen substantial reports to indicate how, when, or in what volume at what cost.
What I have seen is a lot of stuff from the aerospace industry, which takes its classification as 'hard to abate' as some sort of justification for expanding anyway, and projects greatly increased GHG from the industry, whilst apparently thinking that 50% SAF and a much expanded fleet is OK.
Other hard to abate sectors such as steel, concrete, glass and fertiliser both have far more credible plans for abatement, and are way, way more essential to running a modern society than catching a plane to wherever we fancy, when we fancy, and GHG be damned.
They do not even pay the same rate of tax as other means of transport, let alone any premium for their GHG emissions.
Dead handy for multi millionaires that their private jets pay zero for their emissions, but perhaps not so great for any sensible or reasonable control of GHG emissions.
Posted by: Davemart | 18 March 2024 at 09:18 AM
@Davemart
You are correct Direct Air Capture probably will not be economic unless there is some extraordinary breakthrough, if ever.
You also said in a recent post on the 2023 DOE Billion Ton Report about sustainable biomass:
“ At my age my memory horizon stretches back to what I had for breakfast, if I am lucky, not discussions from 10 years ago!”
What about your memory from two weeks ago (3/4/24)?
In the Hamburg University of Technology (TUHH) has compared the Fischer-Tropsch (FT) and methanol pathways for the production of Sustainable Aviation Fuels (SAF) derived from renewable energy sources.
You made some very good comments about research from the University of California Riverside on Co-solvent Enhanced Lignocellulosic Fractionation pretreatment process, or CELF:
“Using poplar in a CELF biorefinery, the researchers demonstrate that sustainable aviation fuel could be made at a break-even price as low as $3.15 per gallon of gasoline equivalent. The current average cost for a gallon of jet fuel in the U.S. is $5.96.”
Here are some more references on this subject:
https://news.ucr.edu/articles/2024/02/07/inexpensive-carbon-neutral-biofuels-are-finally-possible
https://www.nrel.gov/news/program/2024/biorefinery-model-points-to-a-better-method-at-producing-co-products.html
There were also good comments about Coppicing, however one in particular was not completely accurate:
“ The merits of Native Coppice Forestry are widely known in Europe but apparently not in the USA - perhaps having been lost during colonisation. ”
Coppicing and Pollarding are widely used in North America and other parts of the world. It is also called Permaculture and is important for Forest Management and reducing forest fires.
Posted by: Gryf | 18 March 2024 at 09:35 AM
At six dollars a gallon for jet fuel SAF can be very competitive whether you synthesize it using recycled fossil carbon or derive it from plant materials. These are not difficult steps to take, we don't mobilize, we keep doing the same things we've always done even though they cause problems.
Posted by: SJC | 18 March 2024 at 09:46 AM
Gryf:
My figure attests that I have my breakfast more often than once every two weeks!
Here is the discussion we are talking about:
' https://www.greencarcongress.com/2024/03/20240304-tuhh.html'
As I note there, using lignin for biofuels is potentially at least, way more efficient and perhaps available in the right quantities.
But the key word is potentially, as this is really early stage stuff, and for folk like me who can really only manage to do a bit of accountancy based on fairly established figures from the technologies the scientists and engineers have established, there is more or less nothing to grab hold of, nothing to evaluate.
But the aero industry is wishing to go full steam ahead with producing more and more planes, including the long range ones putting out most of the GHG, without any substantial, developed, let alone costed plans in place to mitigate, let alone reduce, their emissions.
Aircraft do not even pay equivalent tax, let alone any loading for GHG.
This for an industy which is in no way critical for the functioning of the economy, unlike for instance other high GHG emitters, which include the power supply industry, steel, concrete and glass, all of which have far more credible plans in place to reduce emissions,
The aircraft industry is AFAIK unique in reckoning that it is OK to vastly increase its emissions, with no more than a pious hope in place to reduce them, sometime, and certainly not now.
You think that hydrogen for aircraft won't work, and obviously have incomparably more expertise than members of the public like me to substantiate that view.
Airbus and others would disagree, but they are a very long way from proving their point, and in any case we are decades away from that being relevant to the main GHG emitters, long range aircraft, so any debate about that is irrelevant for the foreseeable future in the context of GHG emissions.
So what gets my goat is the aircraft industry's notion that increasing their emissions without any credible plan in place to contain, let alone reduce, GHG emissions, is acceptable.
Flying to Majorca for a holiday, or Davros for the movers and shakers, is not a necessity.
Containing, not expanding, GHG emissions, is.
SAF from lignin is a wonderful potential resource.
It is a bloody awful excuse for expanding the airfleet on the assumption that it, or
'Something will turn up'.
Posted by: Davemart | 18 March 2024 at 10:41 AM
“Airbus and others would disagree”
Not really.
https://www.airbus.com/en/sustainability/respecting-the-planet/decarbonisation/sustainable-aviation-fuels
Posted by: Gryf | 18 March 2024 at 11:26 AM
“ But the key word is potentially, as this is really early stage stuff,”
Potentially, until Biorefineries are built. The research is at least 10 years old.
https://www.bio.org/sites/default/files/legacy/bioorg/docs/Charles%20Wyman_0.pdf
Posted by: Gryf | 18 March 2024 at 11:28 AM
“Airbus and others would disagree”
@Gryf said:
'Not really.'
?? I was plainly referring to"
' You think that hydrogen for aircraft won't work,' not SAF
Airbus in common with Boeing and the rest of the aircraft industry is keen indeed to press on with unlimited expansion, in total disregard of any substantial, proven, let alone costed means to contain, let alone reduce GHG emissions.
Posted by: Davemart | 18 March 2024 at 11:53 AM
Research is fine, I am all in favour of it.
That is not anything like substantial costed, proven technology to produce SAF with low emissions.
Moving the global container shipping fleet to nuclear is a lot closer to being a proven technology than decarbonising long distance flight, as there are plenty of large ships powered by nuclear reactors.
I would not bet on it though, or invest money in it.
Posted by: Davemart | 18 March 2024 at 11:56 AM
“You think that hydrogen for aircraft won't work,' not SAF“
I have shown you many examples of Hydrogen working in commercial aircraft, i.e. TU-155 in 1988. Not a new thing. I know a lot about Hydrogen (Rocket engines, fuel cells, storage, etc.) since 1970.
“ in total disregard of any substantial, proven, let alone costed means to contain, let alone reduce GHG emissions.”
What does that mean?
Posted by: Gryf | 18 March 2024 at 12:02 PM
“ Moving the global container shipping fleet to nuclear is a lot closer to being a proven technology”.
Nothing new there either. The NS Savannah was launched in 1959. Good concept, just not cost effective for commercial shipping.
Nuclear powered submarines and Aircraft carriers, with the exception of the French are fueled with Highly Enriched Uranium (bomb grade stuff) and are very expensive.
Posted by: Gryf | 18 March 2024 at 12:07 PM
@Gryf:
' “You think that hydrogen for aircraft won't work,' not SAF“
I have shown you many examples of Hydrogen working in commercial aircraft, i.e. TU-155 in 1988. Not a new thing. I know a lot about Hydrogen (Rocket engines, fuel cells, storage, etc.) since 1970.'
Yeah, working, but not in any practical sense as a way forward, unless I have totally misunderstood, at least for long range:
' However, I am very hesitant to want this tank on my next long airline flight. Liquid Hydrogen is not a new thing either, it worked in 1966 on a Soviet TU-155 Aircraft.
Not practical, then or now.'
https://www.greencarcongress.com/2024/01/20240113-zeroe.html
So it seems that you have effectively ruled out hydrogen as a solution for long range aircraft, which is where the vast bulk of the emissions occur as it needs liquid hydrogen
And Airbus certainly haven't, although of course they are working on shorter haul first.
Posted by: Davemart | 18 March 2024 at 12:33 PM
@Gryf quoted and commented:
' “ in total disregard of any substantial, proven, let alone costed means to contain, let alone reduce GHG emissions.”
What does that mean?'
If I have missed substantive, costed plans to contain or reduce GHG emissions from flying long range, please give me links.
I am aware of plans to increase the aircraft fleet, and to produce some nominal amounts of SAF, at a maximum of 50% of the kerosene content, but little else.
Posted by: Davemart | 18 March 2024 at 12:44 PM
You might like to read this on the “Report of the PRESIDENTIAL COMMISSION on the Space Shuttle Challenger Accident”.
https://www.nasa.gov/history/rogersrep/v1ch3.htm
The air temperature on January 28 was predicted to be a record-low for a Space Shuttle launch. Morton Thiokol engineers were concerned over the effect the record-cold temperatures would have on the seal provided by the Solid Rocket Booster O-rings for the launch.
From the report:
“The black color and dense composition of the smoke puffs suggest that the grease, joint insulation and rubber O-rings in the joint seal were being burned and eroded by the hot propellant gases.”
At 73.124 seconds:
“Within milliseconds there was massive, almost explosive, burning of the hydrogen streaming from the failed tank bottom and the liquid oxygen breach in the area of the intertank.”
Flying 8 hours in a commercial aircraft with those “plastic” GTL liquid hydrogen tanks and jet fuel in the wings, nothing could go wrong.
Posted by: Gryf | 18 March 2024 at 12:56 PM
“I am aware of plans to increase the aircraft fleet, and to produce some nominal amounts of SAF, at a maximum of 50% of the kerosene content, but little else.”
That is for today. SAF is still expensive with current technology.
Of course, how many air aft are flying with Hydrogen?
Posted by: Gryf | 18 March 2024 at 01:01 PM
How many aircraft are flying with Hydrogen and have flown across the Atlantic.
https://www.bp.com/en_us/united-states/home/news/features-and-highlights/saf-transatlantic-flight.html#
Posted by: Gryf | 18 March 2024 at 01:04 PM
Gryf:
I have no wish for an adversarial discussion, and I enjoy interacting with you.
But I do not follow your argument.
At no stage have I said or claimed that hydrogen is remotely ready to power long distance transatlantic flight. Nor have Airbus indicated any such plans.
However, they have indicated that they are looking at liquid hydrogen for aircraft, which would plainly allow at some stage longer distances than gaseous, which you appear to rule out.
I have no idea why you repeatedly contrast SAF to hydrogen, as at no stage have I claimed that hydrogen is ready to replace SAF.
Why you should refer to something going wrong with the use of hydrogen in a Shuttle in 1986 is just as confusing.
How many sucessful flights were there in 1986 using SAF?
I have simply argued that SAF is currently not really in the works to substantially reduce GHG, which has nothing at all to do with how hydrogen is doing, so why you seek repeatedly to confound the two is not clear.
I repeat, there is no obligation for critics of what is being realistically planned for SAF to have an alternative such as hydrogen ready to power the vast expansion aircraft manufacturers want and project.
We can simply fly less, without causing the world economy to grind to a halt.
Posted by: Davemart | 18 March 2024 at 02:00 PM
There is no “vast expansion aircraft manufacturers want and project.”
Current Aircraft deliveries have been on the books for years.
What are Airbus plans for Hydrogen other than research?
“Why you should refer to something going wrong with the use of hydrogen in a Shuttle in 1986 is just as confusing.” This is part of Hydrogen fuel tank research which you brought up, i.e. GTL
How many sucessful flights were there in 1986 using SAF?
SAF is a drop in fuel and a recent development. However, the TU-155 flew with Liquid hydrogen in 1988.
So how many since then?
Aircraft travel is a small contributor to GHG. Less than 4% and 80% of that is on long flights. So Hydrogen will help for at most 1% of GHG. For short flights take an electric train.
Posted by: Gryf | 18 March 2024 at 02:56 PM
Gryf
I give up.
It does not matter how many times I say that hydrogen is not a present competitor to SAF you simply do not listen.
'Aircraft travel is a small contributor to GHG. Less than 4% and 80% of that is on long flights'
Yeah, projected to rise massively by 2050 as they are ploughing right ahead producing more aircraft whilst paying lipservice to decarbonisation with 50% SAF at some unspecified time by unspecified means at unspecified cost the cover story.
No point in saying again that the alternative I support is to fly less, such as France's measure to stop short flights, I suppose, as you will simply claim that pm some obscure way I am claiming that hydrogen is the competitor for flights I don't think should happen.
Posted by: Davemart | 18 March 2024 at 03:30 PM
https://www.eesi.org/papers/view/fact-sheet-the-growth-in-greenhouse-gas-emissions-from-commercial-aviation
' By 2050, commercial aircraft emissions could triple given the projected growth of passenger air travel and freight.'
Fly less is my answer, but no doubt that will be turned into some argument for hydrogen against SAF
Posted by: Davemart | 18 March 2024 at 03:37 PM
Gryf sought to argue:
' “Why you should refer to something going wrong with the use of hydrogen in a Shuttle in 1986 is just as confusing.” This is part of Hydrogen fuel tank research which you brought up, i.e. GTL'
Wow. So you want to argue that the state of the tech in 1986 is relevant to what we can do today?
Bang go electric cars then, as they might have been a touch impractical using 1986 tech,
GTL if building demo dewar tanks for hydrogen right now, using present tech, not that of 1986
No point in saying again that that is wholly irrelevant to what will happen in long distance air transport for the next 25 years though, as that will be ignored.
Posted by: Davemart | 18 March 2024 at 03:44 PM