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CATL unveils Freevoy Super Hybrid Battery for PHEVs and EREVs; combining Li-ion and Na-ion technologies

CATL launched Freevoy Super Hybrid Battery, the first hybrid vehicle battery to achieve a pure electric range of more than 400 kilometers and 4C superfast charging, heralding a new era for high-capacity EREV and PHEV batteries.

With EREVs (extended range electric vehicles) and PHEVs (plug-in hybrid electric vehicles) gaining prominence in the new energy vehicle market, consumers have increasingly expressed frustration over their unsatisfactory pure electric experiences with such vehicles. Short range, slow charging, and reduced low-temperature performance have emerged as critical challenges demanding immediate solutions.

Designed for hybrid vehicles of EREVs and PHEVs, CATL’s Freevoy frees drivers from the constant need to charge, a common drawback of existing hybrid vehicles, offering the convenience of one charge to power an entire week’s commute. Additionally, it delivers impressive charging speeds, providing more than 280 kilometers of range on 10 minutes of charging, effectively dispelling range anxiety for EREV and PHEV owners.

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The Freevoy incorporates a surface modification technology for the cathode material, coupled with an innovative high-voltage electrolyte formulation, to create a nano protective layer. This effectively minimizes side reactions within the active layer.

The integration of high-activity, excited-state particles into the cathode material significantly enhances transport efficiency of lithium ions within the material. Supported by the SOC full-scene high-precision model developed by CATL, and the upgrade of BMS intelligent algorithm and hardware, the SOC control accuracy of Freevoy has been increased by 40%, and the overall pure electric utilization rate has increased by more than 10%, achieving a pure electric range of more than 400km.

At the same time, CATL conducted model data analysis on the charge-discharge polarization characteristics of the battery, accurately predicted the future discharge capacity of the battery, and created a multi-level power prediction and control strategy for the battery, which improved the power performance of the hybrid vehicles by 20%.

Furthermore, CATL has successfully applied its 4C ultra-fast charging technology in the Freevoy, achieving more than 280 kilometers of range on 10 minutes of charging. Lithium ion transport is speeded through the application of cathode fast ion conductor coating technology, second-generation fast-charging graphite and novel nano-coating technologies for the anode, multi-gradient layered electrode design, and a brand-new ultra-high conductivity electrolyte formulation, allowing hybrids to deliver the ultimate charging experience equal to pure electric vehicles.

CATL’s sodium-ion battery technology is also implemented in the Freevoy, breaking the low-temperature limitations of new energy vehicles. It achieves discharge capability in extreme cold environments down to -40 degrees Celsius, charging capability down to -30 degrees Celsius, and maintains a seamless driving experience down to -20 degrees Celsius comparable to normal temperatures.

To further improve the low-temperature performance of the Freevoy, CATL has implemented three key technological innovations centered around sodium-ion battery technology.

  • Leveraging CATL’s AB battery system integration technology, the Freevoy combines sodium-ion batteries and lithium-ion batteries in a defined ratio and arrangement, with mixed, serial, and parallel connections to enhance low-temperature range by 5%.

  • CATL takes the sodium-ion battery as a SOC benchmark for monitoring of the AB battery system to assist in calibrating the lithium-ion battery’s charge level. This elevates system control precision by 30%, adding more than 10 kilometers to the pure electric range.

  • Addressing the inherent performance disparities between lithium-ion batteries and sodium-ion batteries at low temperatures, CATL has developed a full temperature range accurate BMS technology. This technology implements targeted zonal management for distinct chemical systems around the clock, effectively mitigating issues like inaccurate charge prediction or reduced power performance in harsh high and low temperature environments.

CATL has established a comprehensive reliability management and evaluation system, starting from the material selection and molecular design and encompassing multi-level protection structures, extreme manufacturing processes, comprehensive testing and validation, and big data-driven early warning mechanisms.

The Freevoy has already been used on numerous models of various brands, including Li Auto, AVATR, DEEPAL, CHANGAN NEVO, and NETA. By 2025, 30 hybrid vehicle models from brands including Geely, Chery, GAC, and VOYAH, equipped with CATL's Freevoy are scheduled to be launched and delivered.

Comments

Roger Pham

>>>>>>>>"...hybrid vehicle battery to achieve a pure electric range of more than 400 kilometers and 4C superfast charging,"
Reply: This statement completely misses the 2 biggest advantages of PHEVs over full BEVs, which is small battery pack to cut cost and weight, and able to use 120-V household socket for slow overnight charging.
O/W, if you have this much battery capacity and such a fast charging speed, why bother with a range-extender at all?

SJC

down to -40 degrees Celsius, charging capability down to -30 degrees Celsius
That is impressive because the L FP batteries don't like being charged below freezing

Nirmalkumar

This is what auto world is waiting for. What is size of sodium battery, lithium battery and other technical details will be welcome.

JamesDo88039200

So a short range fully capable EV with petrol extender for trips outside the charging network or road trips of 800+ miles per day. Love it. Texas is huge people don't realize how huge. From end to end it's 12 hours and 800 miles just to cross the State east west or north south. From DFW to just Houston is 5 hours and 350 miles at night no traffic in traffic at 2 hours more. Midland is 400+ and New Orleans is 560 miles. I drive to all three every other week on the regular. So yeah people need long-range multiple hundreds of miles per day. Having the ability to use any one of the 150,000 fuel pumps in the USA and fill a tank for 500+ miles in 3 min is a requirement not negotiable. Having the ability to use cheap grid power around the house and only needing access to pumps on long distance is the secret sauce. I also routinely go to Fort Worth a 120 mile round trip that could be all electric with a hybrid of this size pack and all my local DFW driving as well. Price one of these at 25K and it gets bought. I really want the BYD plug in that got 2.2L/100km that's 108 mpg US. Simply amazing and it sells in China for $15,000 USD would buy two tomorrow if the sold that BYD here.

yoatmon

The Mfrc's of Li-ion tech tell potential customers a lot of BS. To start off with, they state that Li is lighter than Sodium. That however is not the whole truth. Li itself does not constitute a functional cell. Considering the present SOA, you need to add Cobalt, Nickel, Manganese and Graphite to achieve a functional cell. You don't need all those additives when using Sodium. When comparing a functional Li-ion cell with a functional Sodium cell you have little to no weight advantage. That leaves a definite price advantage among others for Sodium.
It is highly advisable to adhere to the 10 - 80% recommendation for Li-ion to achieve the estimated life expectancy of the cell / battery. Even better though is to follow a 20 -80% pattern to assure an acceptable total life expectancy. That means that 40% of the battery's potential energy density is out of reach and only usable in real emergencies. So no range advantage when compared to Sodium as those restrictive measures do not apply to Sodium.
Sodium is available everywhere worldwide, is far cheaper, much easier to procure and leaves no detrimental footprint on the environment like Li does.
Additionally, Sodium has no restrictive temperature responses at low temperatures like Li does.
CATL's share of the world battery market amounts to 37,4%. They have literally dropped Li and concentrate mainly on Sodium for good reasons.

Gryf

First, let’s look at an application of this battery:
“ The Freevoy has already been used on numerous models of various brands, including Li Auto, . . .”
Check out the 2024 Li Auto L9 at https://www.liauto.com/L9#li
It has a 52.3 kWh battery with an all electric 280 km range and a 1.5l range extender that gives it a 1412 km range. These are CLTC numbers so an EPA range would be 35% less (https://insideevs.com/features/343231/heres-how-to-calculate-conflicting-ev-range-test-cycles-epa-wltp-nedc/).

If you look at the shades of gray in the picture the Sodium/Lithium battery ratio could be 50/50. So the Li Auto L9 would have a 26.15 kWh LFP battery, not much larger than a RAV4 Prime or Mitsubishi Outlander PHEV battery size (18 & 20 kWh).

If you can’t wait for the BYD or Geely EREV, maybe the Hyundai Ioniq 9 with a Range Extender will work (https://electrek.co/2024/08/28/hyundai-confirms-3-row-ioniq-9-erevs-550-mi-range-us/) and it’s made in Georgia USA.

SJC

Texas is huge you can drive all day and still be in Texas

Bernard

I like how the main objection to EVs is now "I like to drive for 600 miles straight and stop no more than three minutes for fuel!"
People must have bladders built like propane tanks, given that a suitable EV will make that trip with a 20 minute break in the middle.

Bernard

Roger,

You should know that standard US household service is 240V. Sure, you can choose to power a car via 120V, like you would for Christmas lights, but this seems like a strange cost saving, given the price of a car. It's a one-time expense to run a circuit to your garage/driveway.

Roger Pham

@James Do,
Don't get your hope up too high. The US gov will never allow such a vehicle here. PHEVs are selling in very low numbers in the US in spite of long waiting lists to buy such vehicles. Mazda is releasing a very appealing PHEV in China, but would not release it here.

@Bernard,
Level 2 charging at home is for BEV because it has no engine range extender, so you need to charge it fast in case you have to drive a lot the each day. A PHEV does not need level 2 charging at home because the engine is always there for you. Why pay for the extra level 2 charging at home when it is not needed?

SJC

A PHEV being able to charge from 110 is convenient you can always find 110 in the US

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