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Toyota seeking partnerships to develop technology that uses boil-off gas generated while driving H2 ICE concept running on liquid hydrogen

Toyota Motor will enter the ENEOS Super Taikyu Series 2024 Empowered by BRIDGESTONE Round 7 Super Taikyu Final Fuji, to be held from 16 to 17 November, with the #32 ORC ROOKIE GR Corolla H2 Concept, a hydrogen-powered GR Corolla running on liquid hydrogen. Toyota will also be exhibiting a concept model that envisions the use of boil-off gas generated while driving as it looks for partners to take on the challenge of developing the technology together.

Boil-off gas is hydrogen that vaporizes from liquid hydrogen fuel stored in the tank due to natural heat that enters from outside.

Liquid hydrogen has a higher density than gaseous hydrogen. This allows for more hydrogen to be stored in a tank of the same capacity but presents an issue of boil-off. This is a problem for all liquid hydrogen systems, where the liquid hydrogen fuel stored in the tank evaporates due to natural heat that enters from outside. Until now, the boil-off gas (vaporized hydrogen) generated in the fuel tank while driving has been released into the atmosphere without being used.

At the Super Taikyu Final Fuji, Toyota will exhibit a new concept model that utilizes the boil-off gas. Although it is still in the concept stage, if realized, this technology is expected to improve the energy efficiency of the entire liquid hydrogen system by recovering and using boil-off gas as energy. Thus, Toyota is looking to form partnerships that will help make this technology a reality.

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Toyota is working on the development of technology to produce reusable fuel by sending boil-off gas released from liquid hydrogen in the tank to a self-pressurizer (a device that increases pressure without relying on external energy). Boil-off gas can be converted back to usable hydrogen fuel for the engine by applying pressure, but increasing the pressure sufficiently usually requires energy such as electricity. The self-pressurizer that will be exhibited at this event uses the pressure of the boil-off gas to increase pressure by two to four times and produce reusable fuel without using any additional energy.

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Self-pressurizer for increasing the pressure of boil-off gas (The meter on the left displays pressure after the increase, and the meter on the right displays pressure before the increase.)


During the pressurization process for reusing boil-off gas, a certain amount of surplus boil-off gas is still released. This is then fed into the small fuel cell package (FC stack) that Toyota has developed, and the hydrogen goes through a chemical reaction to generate electricity.

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Small FC stack that generates electricity using boil-off gas.


The electricity generated can be used to power parts such as the motor for the liquid hydrogen pump. If realized, it will be possible to supplement electricity equivalent to the amount generated by the alternator (small generator) from boil-off gas, leading to an improvement in energy efficiency.

Boil-off gas that is not used in the electricity generation process is then converted into water vapor through a catalyst as before and safely released outside the vehicle.

Comments

Bernard Harper

Green hydrogen does not exist in bulk or as a product you can buy. Currently hydrogen is a dirty gas to produce and almost all worldwide production is used to make fertilizer for food production. So its use in vehicles is disastrous and must be avoided until green hydrogen replaces its fossil fuel predecessor.

SJC

Boil off is taken into account with LNG tankers it powers the ship.

Roger Pham

@Bernard,
Good point, and the use of Hydrogen in cars is almost non-existent, due to several issues such as filling infrastructural and bulky and heavy containers taking up space and weight from payload.
However, works must continue to perfect the technology, because it will take years if possible at all to make green h2 viable, while the fossil fuel reserve is being depleted steadily. If we wait until FF fuel reserves are to be depleted before working on alternatives, it will be too late!

Roger Pham

There now exist a high-pressure-capable Liquid H2 tank that can store half of the mass of H2 in pressurized gaseous form. So, the tank can store compressed H2 for local daily commute, and can be filled with LH2 before a long trip that will consume at least 1/2 of the LH2 from the tank in 1 day. Then, the other 1/2 of the LH2 can be held inside the tank in compressed gaseous form without worrying about what to do with the boil off.

For example, a FCV having a range of 500 miles on LH2 can be driven 250 miles in one day to deplete 1/2 of the LH2 store, then the remaining LH2 can be allowed to turn into compressed H2 that can be stored on long-term basis without loss. For local commuting, then the range on compressed H2 will be only 250 miles, but that will be enough for 1 week's worth of commuting.

Roger Pham

Continued from above:
Furthermore, an insulated and pressurized H2 tank can be used to store compressed H2 chilled down to -110 degree C (cryo-compressed h2) wherein at that temperature, the H2 density will increase 50% higher than the compressed H2 at room temperature for a given pressure. So, a FCV with range of 300-mi with compressed H2 at room temperature can travel 450 miles when filled with cryo-compressed H2 at below -110 C for long trips. So, after 150 miles of driving in 1 day, the tank can be allowed to warm up to room temperature and will retain the 300-mi range for extended time. Cryo-compressed H2 is a less costly option in comparison to LH2 to extend the long-distance cruising range of FCV.

SJC

I think we could see liquid hydrogen for aircraft for trucks I think we can see MOF, you can't have high pressure tanks that are filled every day, they stretch, they need to be replaced, it's expensive and dangerous.

dursun

Rube Goldberg BS

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