BASF researchers have developed a process to produce methanol without any greenhouse gas emissions. If it can be successfully implemented at an industrial scale, the entire production process – from syngas production to pure methanol – will no longer release any carbon dioxide emissions. Typically, methanol is made from syngas,... Read more →
Methanotrophic bacteria remove methane from the environment and convert it into methanol. An interdisciplinary team at Northwestern University has found that the enzyme responsible for the methane-methanol conversion catalyzes this reaction at a site that contains just one copper ion. The study is published in the journal Science. Bacteria that... Read more →
Within the scope of an agreement signed in November 2017 (earlier post), Eni and FCA have developed “A20”, a new fuel with a low level of emissions due to its 15% methanol and 5% bio-ethanol alcohol content. By harnessing its low carbon content, bio component and high octane number (RON... Read more →
Carbon Recycling International has been awarded a €1.8-million (US$2.0-million) grant under the EU Horizon 2020 Research Programme to increase the scale of its CO2-to-methanol technology, marketed under the trademark Emissions-to-Liquids (ETL). The grant will allow CRI to accelerate efforts to commercialize large scale production plants, expanding the market for ETL... Read more →
Shell will join a consortium comprising Air Liquide, Nouryon (formerly AkzoNobel Specialty Chemicals), Enerkem and the Port of Rotterdam in an effort to build Europe’s first advanced waste-to-chemicals facility in Rotterdam, the Netherlands. Shell will become an equal equity partner in the proposed commercial-scale waste-to-chemicals (W2C) project, which will be... Read more →
BASF has introduced a product for the production of methanol on the basis of renewable raw materials according to the biomass balance approach. The product name is EU-REDcert-methanol. The company replaces fossil raw materials with second-generation renewable raw materials and uses waste as well as residual materials. As a result,... Read more →
Highly fuel-efficient new engine designs could significantly reduce the environmental impact of combustion-engined vehicles, especially if the engines run on renewable non-petroleum-based fuels. Ensuring these unconventional fuels are compatible with next-generation engines was the aim of a new computational study on fuel ignition behavior at KAUST. A paper on their... Read more →
Researchers from Soochow University in China and the University of Toronto have developed a new photocatalyst for the hydrogenation of CO2 to methanol with 50% selectivity under simulated solar irradiation. A paper on their work appears in the journal Joule. The solar methanol production of the defect-laden indium oxide, In2O3-x(OH)y,... Read more →
For the last 18 months, a fleet of 6 methanol-fueled versions of the Geely Emgrand 7 cars have been in Iceland. Geely is a shareholder ($45.5-million investment in 2015) in Carbon Recycling International (CRI), an Icelandic company which produces renewable methanol using recycled CO2 emissions sourced from a local thermal... Read more →
Researchers at Argonne National Laboratory, Tufts University and Oak Ridge National Laboratory have shown that mononuclear rhodium species, anchored on a zeolite or titanium dioxide support suspended in aqueous solution, can catalyze the direct conversion of methane to methanol and acetic acid using oxygen and carbon monoxide under mild conditions.... Read more →
The chief executive of Eni, Claudio Descalzi, and the chief executive of FCA, Sergio Marchionne, signed a Memorandum of Understanding for the joint development of research projects and technological applications aimed at reducing CO2 emissions from road transport vehicles. The two companies, renewing their strategic commitment to a low-carbon future... Read more →
BASF and bse Engineering have signed an exclusive joint development agreement for BASF to provide custom-made catalysts for a new chemical energy storage process. This process will enable the economically viable transformation of excess power and off-gas carbon dioxide into methanol in small-scale, decentralized production units. In addition to being... Read more →
Chemists from the US Department of Energy’s Brookhaven National Laboratory and their collaborators have definitively identified the active sites of a catalyst commonly used for making methanol from CO2. The results, published in the journal Science, resolve a longstanding debate about exactly which catalytic components take part in the chemical... Read more →
Researchers in China, along with colleagues in the US, have developed a new catalyst that shows outstanding hydrogen-production activity and stability in the low-temperature aqueous phase reforming of methanol (APRM). In a paper in the journal Nature, the team reports that platinum (Pt) atomically dispersed on α-molybdenum carbide (α-MoC) enables... Read more →
China is the global leader in methanol use and has recently expanded its methanol production capacity. Now, a study commissioned by the US Energy Information Administration (EIA) from Argus Media (a global provider of analysis on energy and commodities), finds that since the early 2000s, China’s consumption of methanol in... Read more →
At the Fuel Choices Summit in Israel this week, FCA presented the Fiat 500 M15—a retail-ready version of the Fiat 500 that runs on a blend of 85% gasoline and 15% methanol; is compliant with the Euro 6 New European Driving Cycle (NEDC); delivers a 2% CO2 reduction compared with... Read more →
A partnership comprising AkzoNobel, Van Gansewinkel, Air Liquide, AVR and Enerkem is proposing to build a waste-to-chemicals plant in Rotterdam in collaboration with the Port of Rotterdam, the City of Rotterdam, the province of South Holland and InnovationQuarter. The new chemical plant will use Enerkem’s innovative technology to convert residual... Read more →
Globally, the use of methanol as an alternative fuel has attracted interest because of its low production cost, renewable capacity, and good combustion-related properties (higher thermal efficiency, higher engine power, and lower regulated emissions). In China in particular, there are abundant coal resources, and the technology of using coal to... Read more →
Lawrence Livermore National Laboratory scientists have combined biology and 3-D printing to create the first reactor that can continuously produce methanol from methane at room temperature and pressure. Methane monooxygenases (MMOs), found in methanotrophic bacteria, are selective catalysts for methane activation and conversion to methanol under mild conditions; however, these... Read more →
Researchers at Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, have developed a highly efficient homogeneous Ru-based catalyst system for the production of methanol (CH3OH) from CO2 and H2 in an ethereal solvent (initial turnover frequency = 70 h−1 at 145 °C). In a paper published... Read more →
The University of North Dakota Energy & Environmental Research Center (EERC) is working with FuelCell Energy, Inc., an integrated stationary fuel cell manufacturer, to develop a durable, low-cost, and high-performance electrochemical cell to convert natural gas and other methane-rich gas into methanol, a major chemical commodity with worldwide applications in... Read more →
Researchers at Tsinghua University in China are studying the effects of Dual-Fuel Spark Ignition (DFSI) combustion fueled with different alcohols and gasoline. In one paper, published in the journal Fuel, they investigated the use of alcohols–gasoline DFSI Combustion for knock suppression and high fuel efficiency using a gasoline engine with... Read more →
Researchers at Argonne National Laboratory have identified a new material to catalyze the conversion of CO2 via hydrogenation to methanol (CH3OH): size-selected Cu4 clusters—clusters of four copper atoms each, called tetramers—supported on Al2O3 thin films. In a study published in the Journal of the American Chemical Society, the team measured... Read more →
Zhejiang Geely Holding Group (Geely Group) will invest a total of US$45.5 million in Carbon Recycling International (CRI). The investment consists of an initial investment and additional purchases of CRI equity over a 3-year period. Geely Group will become a major shareholder of CRI and will gain representation on the... Read more →
Hydrogenics Corporation will supply a 1MW electrolyzer and provide engineering expertise to a consortium of companies working on the European project MefCO2 (methanol fuel from CO2) in Germany. The application will take excess electricity from intermittent renewable energy sources, generate green hydrogen, and then create methanol using a low-carbon footprint... Read more →
A team from the University of Minnesota and Michigan State University has identified the structure of the key intermediate “Q” in the enzyme methane monooxygenase (MMO). MMO catalyzes the O2-dependent conversion of methane to methanol in methanotrophic bacteria, thereby preventing the emission into the atmosphere of approximately one billion tons... Read more →
Researchers at the UCLA Henry Samueli School of Engineering and Applied Science led by Dr. James Liao have developed a more efficient way to turn methanol into useful chemicals, such as liquid fuels, and that would also reduce carbon dioxide emissions. The UCLA team constructed a synthetic biocatalytic pathway that... Read more →
The US Environmental Protection Agency (EPA) has issued a final greenhouse gas (GHG) Prevention of Significant Deterioration (PSD) construction permit to Natgasoline LLC to construct a new motor-grade gasoline production facility in Texas that uses natural gas as feedstock (gas-to-gasoline, or GtG). Natgasoline is a new wholly owned greenfield methanol... Read more →
Maverick Synfuels (earlier post) introduced a small-scale, modular methane-to-methanol production plant that can be co-located at the methane source. The Maverick Oasis system allows producers to monetize biogas and natural gas (including associated or flare gas, and stranded gas reserves), as an alternative to producing electricity or venting greenhouse gases... Read more →
Top: Components of well-to-wheels pathway. Middle: WTW efficiency for CNGVs. Bottom: WTW efficiency for EVs. Curran et al. Click to enlarge. A well-to-wheels analysis of the use of natural gas for passenger vehicles by a team of researchers from Oak Ridge National Laboratory (ORNL) has found that, with a high... Read more →
Scanning tunneling microscope image of a cerium-oxide and copper catalyst (CeOx-Cu) used in the transformation of CO2 and H2 to methanol (CH3OH) and water. In the presence of hydrogen, the Ce4+ and Cu1+ are reduced to Ce3+ and Cu0 with a change in the structure of the catalyst surface. Source:... Read more →
Carbon dioxide recycling in the methanol economy Source: Olah et al. 2009, earlier post. Click to enlarge. A report prepared by ISIS (Institute of Studies for the Integration of Systems - Italy) together with Tecnalia (Spain) for the European Parliamentary Research Service (EPRS) discusses the technological, environmental and economic barriers... Read more →
Scientists from Stanford University, SLAC National Accelerator Laboratory and the Technical University of Denmark have identified a new nickel-gallium catalyst that converts hydrogen and carbon dioxide into methanol at ambient pressure and with fewer side-products than the conventional catalyst. The results are published in the journal Nature Chemistry. The researchers... Read more →
The US DOE is soliciting (DE-FOA-0001051) projects for up to $10 million in awards to target technological advancements to lower the cost of producing hydrogen and/or high-hydrogen syngas from coal for use in 90% carbon capture power generation and/or gasification-based liquid (transportation) fuel production: methanol or diesel. Liquid fuel production... Read more →
A team at the University of Idaho has demonstrated that glycerol, a byproduct from biodiesel production, could be used as a substrate for producing drop-in gasoline-range biofuel. In a paper published in the ACS journal Energy & Fuels, Guanqun Luo and Armando G. McDonald describe their study of converting methanol... Read more →
New fuel booster valve for ME-LGI engine showing the main constituent parts. Click to enlarge. On 1 July MAN Diesel & Turbo announced the development of a new ME-LGI dual fuel engine. The new engine expands the company’s dual-fuel portfolio, enabling the use of more sustainable fuels such as methanol... Read more →
Summary of levelized production cost estimates of fuel (LCOF) for the examined plant designs. The horizontal red lines show the comparable price of gasoline (before tax, refining margin 0.3 $/gal, exchange rate: 1 € = 1.326 $) with crude oil prices 100 $/bbl and 150 $/bbl. Source: VTT. A study... Read more →
Researchers at the University of Erlangen-Nürnberg (Germany) report in the journal Angewandte Chemie their development of an enhanced platinum catalyst for the steam reforming of methanol to release hydrogen. A central problem of renewable energy technology lies in the great variation of energy generated (i.e., intermittency). One proposed solution is... Read more →
Schematic diagram of the Primus STG+ process. Click to enlarge. Primus Green Energy Inc., developer of a proprietary process to produce gasoline and other fuels from biomass and/or natural gas (earlier post), will provide financial support to engineers at Princeton University for general research on synthetic fuels, which will include... Read more →
Cartoon of the process. Click to enlarge. Researchers at Columbia University have developed a biological process utilizing autotrophic ammonia-oxidizing bacteria (AOB) for the conversion of methane (CH4) to methanol (CH3OH). A paper on their work is published in the ACS journal Environmental Science & Technology. In fed-batch reactors using mixed... Read more →
Researchers from the US and China have determined that a duckweed biorefinery producing a range of gasoline, diesel and kerosene products can be economically competitive with petroleum-based processes, even in some cases without environmental legislation that penalizes greenhouse gas emissions. A paper describing their analysis of four different scenarios for... Read more →
(a) Schematic pathway for a homogeneously catalyzed methanol reforming process via three discrete dehydrogenation steps. (b) Best performing catalysts. Nielsen et al. Click to enlarge. Researchers from Germany and Italy have developed an efficient low-temperature catalytic process to produce hydrogen from methanol. Hydrogen generation by this method proceeds at 65–95... Read more →
Researchers at the Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, have developed a new catalyst based on nickel oxide on magnesium oxide (NiO/MgO) that is effective for the bi-reforming with steam and CO2 (combined steam and dry reforming) of methane as well as natural gas... Read more →
The ExxonMobil MTG process flow diagram. Source: EMRE. Click to enlarge. Sundrop Fuels, Inc., a gasification-based drop-in advanced biofuels company, finalized a licensing agreement to use ExxonMobil Research and Engineering Company’s methanol-to-gasoline (MTG) technology to be incorporated into a “green gasoline” production facility. Located near Alexandria, Louisiana, Sundrop Fuels plans... Read more →
Cascade catalysis for the lower temperature conversion of CO2 to methanol. Credit: ACS, Huff and Sanford. Click to enlarge. Researchers at the University of Michigan have demonstrated the viability of cascade catalysis—i.e., the use of a series of different homogeneous catalysts operating in a single vessel—for the reduction of CO2... Read more →
Celanese Corporation, developer of a hydrocarbons-to-ethanol production process derived from its acetyl technology (earlier post) announced plans in June to enter the industrial ethanol market in China by revamping the market entry strategy to allow the company to enter 6-12 months sooner than originally planned. (Earlier post.) In a recent... Read more →
Overview of the process. Click to enlarge. Researchers at the University of California, Santa Barbara (UCSB) have developed a one-pot process for the catalytic conversions of wood and cellulosic solids to liquid and gaseous products in a reactor operating at 300–320 °C and 160-220 bar. Little or no char is... Read more →
Anthropogenic chemical carbon cycle. Click to enlarge. In a Perspective published in the Journal of the American Chemical Society, researchers from the Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California describe their work on developing the feasible anthropogenic recycling of carbon dioxide. Under their scheme, carbon... Read more →
Binding pocket representation of P450 enzyme with activator (perfluoro chain in green) and docking poses of a methane cluster (carbon atoms in black and hydrogen atoms in white) hovering above Fe=O (red) in the porphyrin ring. Zilly et al. Click to enlarge. Researchers at the Max Planck Institute for Carbon... Read more →
The US Department of Energy’s National Renewable Energy Laboratory (NREL) is collaborating with Oorja Protonics, a developer and manufacturer of direct methanol fuel cell technology (earlier post) on a two-year project to deploy and demonstrate methanol fuel cells for power pallet jacks in four commercial wholesale distribution centers. The total... Read more →